The Synthesis and Characterization of Thiophene Derivative Polymers

2011 ◽  
Vol 284-286 ◽  
pp. 1846-1849 ◽  
Author(s):  
Wei Xing Chen ◽  
Su Yan Zhang ◽  
Ai Jie Ma ◽  
Qi Guan Wang
Keyword(s):  
Absorption Band ◽  
Chemical Oxidation ◽  
Electrochemical Activity ◽  
Strong Absorption ◽  
Synthesis And Characterization ◽  
Thiophene Derivative ◽  
The Media ◽  
Ft Ir ◽  
Important Kind

Thiophene derivative polymer is an important kind of conductive polymers. They often have good electrochemical activity, environment stability and ease of processing. Here, 3-bromothiophene and 3-thiophenezoic acid as monomers, using chemical oxidation approach, the poly (3-thiophenezoic acid) (PTPA), the copolymer of 3-bromine thiophene (BTP) and 3-thiophenezoic acid (TPA) are synthesized in the media of chloroform or methanol. The structures of both polymers are characterized with FT IR, NMR and UV-vis. The results showed that the reactivity of TPA can be improved after alkalizing. The copolymer has strong absorption in the UV region. Its absorption band and intensity are higher than that of PTPA.

Synthesis and Characterization of Fibular PANI/Nano-CeO2 Composites

2010 ◽  
Vol 148-149 ◽  
pp. 1021-1025
Author(s):  
Hui Xu ◽  
Yong Chen ◽  
Xing Wei Shi ◽  
Xiao Yu Liu ◽  
Guo Jun Gou
Keyword(s):  
Acid Concentration ◽  
Chemical Oxidation ◽  
Synthesis And Characterization ◽  
Chemical Bonds ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ft Ir ◽  
Two Phases ◽  
Ceo2 Particle

The fibular PANI/ nano-CeO2 composites were synthesized via chemical oxidation of aniline using nano-CeO2 as an oxidant, and nano-CeO2 was prepared by hydrothermal treatment. Sphere-like morphology and fibers of PANI/ nano-CeO2 composites were obtained. The resulting composites were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), Fourier transform infrared (FT-IR). The results showed that chemical bonds existed between two phases. The acid concentration and nano-CeO2 particles affected the crystallinity of PANI fibers. The morphology of PANI was formed from the ball gradually developing into the fibular with rising of acid concentration. The regular crystalline structure of fibular was easy to form with a reducing CeO2 particle size.

Chemical Synthesis and Characterization of Conducting Poly(2-Aminothiazole)

2016 ◽  
Vol 867 ◽  
pp. 111-115 ◽  
Author(s):  
Peng Fei Lv ◽  
Xia Wang ◽  
Hua Zou
Keyword(s):  
Copper Chloride ◽  
Chemical Oxidation ◽  
Deionized Water ◽  
Molar Ratio ◽  
Synthesis And Characterization ◽  
Polymerization Temperature ◽  
Oxidation Method ◽  
Ft Ir ◽  
Scanning Electron

In this work, poly(2-aminothiazole) (P2AT) was synthesized by chemical oxidation method using 2-aminothiazole as the monomer. The polymerization was initiated using three different oxidants, CuCl2, FeCl3 and (NH4)2S2O8. The results suggested that the monomer was easily polymerized and higher yields were achieved when CuCl2 was used as the oxidant. The effects of reaction time and polymerization temperature on the yield of polymerization using CuCl2 were investigated. The polymerization yield of the P2ATs was 25.2 % at oxidant/monomer molar ratio of 0.1 for 24 h in the copper chloride /deionized water. The P2ATs were characterized by FT-IR, UV-vis, thermogravimetric analysis (TGA) and scanning electron microscopy (SEM).

One Step Synthesis and Characterization of Zirconia-Graphene Composites

2012 ◽  
Vol 600 ◽  
pp. 174-177 ◽  
Author(s):  
Jian Fei Xia ◽  
Zong Hua Wang ◽  
Yan Zhi Xia ◽  
Fei Fei Zhang ◽  
Fu Qiang Zhu ◽  
...  
Keyword(s):  
Synthesis And Characterization ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Graphene Composite ◽  
Transmission Electron ◽  
One Step ◽  
Ft Ir ◽  
Xrd Techniques

Zirconia-graphene composite (ZrO2-G) has been successfully synthesized via decomposition of ZrOCl2•6H2O in a water-isopropanol system with dispersed graphene oxide (GO) utilizing Na2S as a precursor could enable the occurrence of the deposition of Zr4+ and the deoxygenation of GO at the same time. Transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) techniques were used to characterize the samples. It was found that graphene were fully coated with ZrO2, and the ZrO2 existing in tetragonal phase, which resulted in the formation of two-dimensional composite.

Electrochemically Synthesis and Characterization of Copolymers Based on 1, 4-Diethoxybenzene and 3, 4-Ethylenedioxythiophene

2011 ◽  
Vol 335-336 ◽  
pp. 989-993
Author(s):  
Mi Ouyang ◽  
Zhen Wei Yu ◽  
Yi Xu ◽  
Yu Jian Zhang ◽  
Cheng Zhang
Keyword(s):  
Cyclic Voltammetry ◽  
Ir Spectroscopy ◽  
Feed Ratio ◽  
Synthesis And Characterization ◽  
Monomer Mixture ◽  
Long Wavelength ◽  
H Nmr ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

Copolymers based on 1, 4-diethoxybenzene (DEB) and 3, 4-ethylenedioxythiophene (EDOT) were electrochemically synthesized and characterized. The structures of the copolymers were established by 1H NMR and FT-IR spectroscopy. The results indicated the final product was a copolymer instead of a blend or a composite. The physical properties were systematically investigated by cyclic voltammetry, UV-vis absorption and fluorescence. The PL maximum of copolymers presented obviously red-shift to long wavelength as the feed ratio of EDOT in monomer mixture increased.

scholarly journals Synthesis and Characterization of Some Novel Oxazine, Thiazine and Pyrazol Derivatives

2016 ◽  
Vol 13 (2) ◽  
pp. 244-252
Author(s):  
Baghdad Science Journal
Keyword(s):  
Acetic Acid ◽  
Ir Spectra ◽  
Glacial Acetic Acid ◽  
Basic Medium ◽  
Synthesis And Characterization ◽  
Pyrazole Derivatives ◽  
Phenyl Hydrazine ◽  
H Nmr ◽  
Ft Ir

In this paper, some chalcone derivatives (C1, C2) were synthesized based on the reaction of equal amount of substituted acetophenone and substituted banzaldehyde in basic medium. Oxazine and thiazine derivatives were prepared from the reaction of chalcones (C1-C2) with urea and thiourea respectively in a basic medium. Pyrazole derivatives were prepared based on the reaction of chalcones with hydrazine mono hydrate or phenyl hydrazine in the presence of glacial acetic acid as a catalyst. The new synthesized compounds were identified using various physical techniques like1 H-NMR and FT-IR spectra.

scholarly journals Synthesis and Characterization of some New 1,3,4-Oxadiazole derivatives based on 4-amino benzoic acid

2016 ◽  
Vol 13 (4) ◽  
pp. 762-769
Author(s):  
Baghdad Science Journal
Keyword(s):  
Schiff Base ◽  
Benzoic Acid ◽  
Spectral Data ◽  
1H Nmr ◽  
Synthesis And Characterization ◽  
Oxadiazole Derivatives ◽  
Ft Ir ◽  
Amino Benzoic Acid

Various of 2,5- disubstituted 1,3,4-oxadiazole (Schiff base, ?- lactam and azo) were synthesized from 2,5-di (4,4?-amino-1,3,4-oxadiazole which usequently synth-esized from mixture of 4- amino benzoic acid and hydrazine arch of polyphosphorus acid. The synthesized compounds were cherecterized by using some spectral data (UV, FT-IR , and 1H-NMR)

Synthesis and Characterization of an Alendronate-Chitosan Conjugate

2011 ◽  
Vol 140 ◽  
pp. 53-57 ◽  
Author(s):  
Xiao Hong Shao ◽  
Ji Qing Xu ◽  
Yan Peng Jiao ◽  
Chang Ren Zhou
Keyword(s):  
Drug Delivery ◽  
Drug Delivery System ◽  
Synthesis And Characterization ◽  
Hydroxyl Groups ◽  
Amino Groups ◽  
H Nmr ◽  
Ft Ir ◽  
Novel Drug Delivery System ◽  
Novel Drug

The biomineral-binding alendronate-chitosan conjugate (Scheme 1) was developed as a novel drug delivery system. Alendronate was conjugated to the hydroxyl groups of chitosan, thereby maintaining the amino groups of chitosan intact. By means of FT-IR and 1H NMR, the characterization was conducted to confirm the successful synthesis of alendronate-chitosan conjugate.

scholarly journals Synthesis and Characterization of 2-Pyrazoline Derivatives and their in silico and in vitro Studies on Antimicrobial and Anticancer Activities

2019 ◽  
Vol 31 (10) ◽  
pp. 2191-2196 ◽  
Author(s):  
S. Rathinamanivannan ◽  
K. Megha ◽  
Raja Chinnamanayakar ◽  
Ashok Kumar ◽  
M.R. Ezhilarasi
Keyword(s):  
Breast Cancer ◽  
Synthesis And Characterization ◽  
Anticancer Activities ◽  
1H And 13C Nmr ◽  
Chemical Structures ◽  
Ft Ir ◽  
Affinity Score ◽  
High Binding Affinity

The new series of 1-(4,5-dihydro-5-phenyl-3-diphenylpyrazol-1-yl)butan-1-one derivatives were synthesized by cyclization method using biphenyl chalcone with n-butyric acid and hydrazine hydrate. The synthesized 1-(4,5-dihydro-5-phenyl-3-diphenylpyrazol-1-yl)butan-1-one derivatives chemical structures were confirmed from spectral data such as FT-IR, 1H and 13C NMR. 2-Pyrazoline derivatives were docked with bacterial (1UAG) and breast cancer (1OQA) protein. Based on high binding affinity score, the best compound was subjected to in vitro anticancer activity by MTT assay. Also, antimicrobial activity were studied for synthesized 2-pyrazoline derivatives.

Preparation and Electrical Characterization of Poly(Aniline) NanoClay Composites

2015 ◽  
Vol 34 (4) ◽  
Author(s):  
Esma Ahlatcioǧlu ◽  
Bahire Filiz şenkal ◽  
Mustafa Okutan
Keyword(s):  
Electrical Characterization ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
Inorganic Hybrid ◽  
X Ray ◽  
Ft Ir ◽  
Doped Polyaniline ◽  
Poly Aniline ◽  
Scanning Electron

AbstractIn this work, synthesis and characterization of composite materials based on NanoClay(NC) and boric acid doped PolyAniline (PANI) is studied. PANI was successfully incorporated into NC to form PANI-NC composites. The resulting organic-inorganic hybrid material, PANI-NC was characterized by various physicochemical techniques. Formation of PANI inside the clay tactoid has been confirmed by X-ray diffraction studies (XRD), scanning electron microscope (SEM) and FT-IR. Also, conductivity and physical properties of the PANI-NC composites were investigated.

Sign in / Sign up

Export Citation Format

Share Document