Topologically Close-Packed Phase Precipitation in Ni-Based Superalloys

2011 ◽  
Vol 320 ◽  
pp. 26-32 ◽  
Author(s):  
Fei Sun ◽  
Jian Xin Zhang

The addition of refractory elements is effective in improving the comprehensive performance of Ni-based superalloys, and meanwhile, the precipitation trend of TCP phases increases with the elements content due to the segregation of refractory elements during high temperature service. The precipitation of TCP phases obviously decreased the creep properties and creep rupture life of superalloys. The toughness and plastic of superalloys also dramatically deteriorated. The addition of Ruthenium (Ru) is shown to suppress the formation of TCP phases in Ni-based superalloys, resulting in much improved the creep resistance and the microstructural stability. The studies on TCP phases in Ni-based superalloys including crystallography and precipitation of TCP phases and the effect of alloy composition on TCP phases are reviewed.

2011 ◽  
Vol 306-307 ◽  
pp. 562-571 ◽  
Author(s):  
Fei Sun ◽  
Jian Xin Zhang

Addition of Ru in Ni-base single crystal superalloys had been used to improve the elevated temperature strength and other multiple properties. Significant decreases in stacking fault energy of the γ phase and the volume fraction of γ′ phase are observed with the addition of Ru. As well as serving as an effective solid-solution strengthening element in high refractory content Ni-base single crystal superalloys, Ru additions are able to effectively strengthen both the γ and γ′ phases and suppress the formation of TCP phases. Due to the changes in the partitioning behavior of elements and the slight decrease in the supersaturation of refractory elements in γ phase associated with Ru additions, high temperature creep resistance and the microstructural stability of the alloy are improved remarkable. The influence of Ru on the microstructure of Ni-base single crystal superalloys is reviewed.


2005 ◽  
Vol 475-479 ◽  
pp. 655-660 ◽  
Author(s):  
Q. Feng ◽  
L.J. Rowland ◽  
T.M. Pollock

Three unusual Ru-rich phases have been identified in a multicomponent Ni-base single crystal superalloy, including a L21 Ru2AlTa Heusler phase, a B2 RuAl phase and a hcp Re(Ru)-rich δ phase. These phases have their own preferential precipitation location within the dendritic structure. No conventional topologically-close-packed (TCP) phases have been observed with thermal exposure at 950oC for 1500 hours.


2022 ◽  
pp. 131656
Author(s):  
Jinbin Chen ◽  
Jingyang Chen ◽  
Qinjia Wang ◽  
Yidong Wu ◽  
Qing Li ◽  
...  

2015 ◽  
Vol 622 ◽  
pp. 204-211 ◽  
Author(s):  
S.S. Wang ◽  
L. Chang ◽  
L. Wang ◽  
T. Wang ◽  
Y.D. Wu ◽  
...  

2006 ◽  
Vol 258-260 ◽  
pp. 231-236 ◽  
Author(s):  
Yoshinori Murata ◽  
Tomonori Kunieda ◽  
Kouji Yamashita ◽  
Toshiyuki Koyama ◽  
Effendi ◽  
...  

The diffusivity of refractory elements in heat resistant steels is crucial for the basic understanding of the microstructural stability during creep. The purposes of this study are to estimate the diffusivity in Fe-Cr alloys as a base alloy for the bcc matrix phase in high Cr ferritic steels and also to investigate the alloying effect of Re on the W diffusivity in them. Fe-15Cr and Fe-20Cr binary alloys, Fe-15Cr-5Re, Fe-15Cr-5W, Fe-20Cr-5Re ternary alloys [mol%] were used in this study. On the basis of the modified ternary Boltzmann-Matano method, the interdiffusion coefficients were obtained in Fe-Cr-Re ternary system. The apparent interdiffusion coefficient for the Re-doped Fe-Cr-W alloy was about one fifth of that for the Re-free alloy. It is concluded that the existence of Re retarded significantly the W diffusion in Fe-15mol%Cr based alloy. This is probably the main reason why a small amount of Re addition suppress the microstructural evolution of W containing high Cr ferritic steels.


Author(s):  
Kotur S. Raghavan

Modern day gas turbines are very complex in construction and consist of a very large number of smaller parts and subassemblies. Hence the most vital parts of the entire assembly are the mechanical devices which are deployed to connect and keep them together. In gas turbines two approaches are normally used in the assembly process. They are the threaded fasteners such as bolt and nut and shrunk-fit or interference-fit assemblies. In the high temperature regions of the gas turbines the effect of creep on the integrity of such fastening arrangements needs to be assessed at the design stage. A problem commonly faced pertains to lack of creep data which would facilitate detailed nonlinear analysis. The available data invariably exhibit scatter. In this paper parametric studies are undertaken. Creep curves are chosen so that both primary and secondary stages are accounted for. The coefficients are chosen to meet the design needs. The performance of bolted joints and shrunk-fit assemblies get affected over time due to stress relaxation leading to loss of bolt pretension or the effective interference. The bolt preload as well as the interference is to be optimally chosen. Higher the preload or the interference the more effective is the joint. At the same time the stress levels are higher and hence the stresses will relax to a greater extent. For a design stage assessment of the behavior of assemblies there is need for correlation among the various operating parameters such as stress, temperature and time. For individual components one normally uses empirical correlations such as Larson-Miller to predict rupture life and also creep growth. For assemblies in which relaxation is the main design issue, such parameters are usually not available. There is need to carry out detailed nonlinear analysis. Typical bolted flange and shrink-fit assemblies are chosen for study. Parametric studies are carried out. Using creep properties as described earlier, nonlinear structural responses are studied. The purpose is to correlate the creep properties, in terms of creep strain with respect to time, stress and temperature, with the joint behavior. The key joint behavior indices are the bolt tensile stress in the case of threaded fastening and the compressive force of “effective interference” in the case of shrunk-fit assemblies. The studies have established the need for rigorous creep analysis of components having interference fits or threaded fasteners. Once the operational requirements are known, the approach presented helps in material selection.


2007 ◽  
Vol 353-358 ◽  
pp. 2912-2915 ◽  
Author(s):  
Ke Ke Zhang ◽  
Yao Li Wang ◽  
Yan Li Fan ◽  
Jie Yiang ◽  
Yan Fu Yan ◽  
...  

Creep property of solder alloys is one of the important factors to effect the reliability of surface mount technology (SMT) soldered joints. The creep behavior and its rupture life of Sn2.5Ag0.7CuXRE lead-free soldered joints were separately investigated and predicted under constant temperature by a single shear lap creep specimen with a 1mm2 cross sectional area and finite element method (FEM) in this paper. Results show that the creep property of Sn2.5Ag0.7Cu0.1RE is superior to that of the commercial employed lead-free solder Sn3.8Ag0.7Cu and the creep rupture life of its soldered joints is 8.4 times more than that of Sn2.5Ag0.7Cu solder. The creep rupture life of Sn2.5Ag0.7CuXRE lead-free soldered joints indirectly predicted by FEM is better in accord with that of actual testing results, which are important to design the reliability of lead-free soldered joints for SMT.


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