Lithium-Ion Battery Anode Electrochemical Properties of Si/C Composites Using Graphite and Glucose as Carbon Source

2011 ◽  
Vol 347-353 ◽  
pp. 3506-3509
Author(s):  
Xu Ma ◽  
Yu Ling Liu ◽  
Ling Long Kong ◽  
Yan Hong Ding ◽  
Jie Zhao ◽  
...  
Keyword(s):  
Electron Microscope ◽  
Carbon Source ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
Charge Capacity ◽  
X Ray ◽  
Battery Anode ◽  
Charge Discharge ◽  
Scanning Electron ◽  
Discharge Test

Si/C composites were synthesized by using graphite and glucose as carbon source. The samples were characterized by X-ray diffractometer (XRD) and field emission scanning electron microscope(SEM). The electrochemical charge/discharge test was used to evaluate capacity and cycling stability of the composites. The first discharge and charge capacity of SGC composite using graphite and glucose as carbon source were 1661mAh/g and 1259.1 mAh/g, and the first coulombic efficiency was 75.8%. After 20 cycles, the capacity of SGC composite was 380 mAh/g and the coulombic efficiency remained over 98%.

Comparison of Lini0.5Mn1.5O4 and LiMn2O4 for Lithium-Ion Battery

2013 ◽  
Vol 860-863 ◽  
pp. 956-959
Author(s):  
Xing Hua Liang ◽  
Lin Shi ◽  
Yu Si Liu ◽  
Tian Jiao Liu ◽  
Chao Chao Ye ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Particle Size ◽  
Electron Microscope ◽  
Solid State ◽  
Scanning Electron Microscope ◽  
Retention Rate ◽  
Lithium Ion ◽  
X Ray ◽  
Charge Discharge ◽  
Scanning Electron

The High Potential Material Lini0.5Mn1.5O4 was Synthesized via Solid-State Reaction.The Surface Morphology and Particle Size of the Sample were Observed by Scanning Electron Microscope(SEM).The Crystal Structure of the Sample was Collected and Analyzed through X-Ray Diffractometry(XRD).The Sample was Charaterized by Charge-Discharge Tests.Results Indicated that the Cycling Retention Rate was about 80%,after being Charge-Diacharged at a Rate of 0.1C in a Voltage of 3.45-4.77V for 10 Times.Compared with Limn2O4,LiNi0.5Mn1.5O4 has good cycle performance.Both of LiNi0.5Mn1.5O4 structure were space group of Fd3m.

Hydrothermal Synthesis and Electrochemical Performance of LiFePO4/Graphene Composites for Lithium-Ion Batteries

2014 ◽  
Vol 900 ◽  
pp. 242-246 ◽  
Author(s):  
Xing Ling Lei ◽  
Hai Yan Zhang ◽  
Yi Ming Chen ◽  
Wen Guang Wang ◽  
Zi Dong Huang ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Lithium Ion Batteries ◽  
Electrochemical Impedance ◽  
Lithium Ion ◽  
X Ray Diffraction ◽  
Galvanostatic Charge ◽  
X Ray ◽  
Charge Discharge ◽  
Scanning Electron ◽  
Discharge Test

LiFePO4/graphene composites were prepared via a simple hydrothermal method. The as-prepared LiFePO4/graphene composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), galvanostatic charge-discharge test, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) tests. The lithium-ion batteries using LiFePO4/graphene composites as cathode material exhibited a discharge capacity of 165 mAh/g, which was 97% of the theoretical capacity of 170 mAh/g.

Preparation and Performance of Si/Al/C Composites Anode Material Prepared by Glucose-Modified

2012 ◽  
Vol 164 ◽  
pp. 268-271
Author(s):  
Xu Ma ◽  
Ling Long Kong ◽  
Yu Ling Liu ◽  
Yan Hong Ding ◽  
Jie Zhao ◽  
...  
Keyword(s):  
Anode Material ◽  
Coulombic Efficiency ◽  
Test System ◽  
Cycling Stability ◽  
Charge Capacity ◽  
And Performance ◽  
Charge Discharge ◽  
Discharge Test

Si/Al/C composites were synthesized by the method of doping aluminum and glucose-modified. The samples were characterized by XRD, SEM, and the capacity and cycling stability of the composites were tested by electrochemical charge/discharge test system. After glucose was pyrolyzed, the first discharge and charge capacity of Si/Al/C composites were 1312 and 956.7mAh/g, and the first coulombic efficiency was 72.9%. After 50 cycles, the capacity of Si/Al/C composites was 440mAh /g and the coulombic efficiency remained over 98.1%

Effects of Mg2+ Doping on the Properties of LiFePO4 Synthesized via Hydrothermal Route

2009 ◽  
Vol 610-613 ◽  
pp. 498-501
Author(s):  
Guang Chuan Liang ◽  
Xiao Ke Zhi ◽  
Xiu Qin Ou ◽  
Li Wang
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Hydrothermal Synthesis ◽  
Cell Volume ◽  
X Ray Diffraction ◽  
Hydrothermal Route ◽  
X Ray ◽  
Charge Discharge ◽  
Scanning Electron ◽  
Discharge Test

Mg2+ doped LiFePO4 was synthesized from Li3PO4, FeSO4 and MgSO4 by a hydrothermal synthesis at 150 °C（Li1-xMgxPO4, x=0.00, 0.01,0.02,0.04,0.06）. The samples were characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM) and charge-discharge test. The results showed that Mg2+ dissolved in the LiFePO4 lattice. When the content is in the range of 0 to 6 mol%, Mg2+ caused the shrinkage of LiFePO4 cell volume. The capacity of doped and undoped samples at low discharging rate was similar, about 145mAhg-1 for 0.2C. But the sample doped with 2-4 mol% Mg2+ has higher capacity and longer cycle lifetime than the undoped one at 5C.

Synthesis of Lithium-Ion Battery Cathode Material LiFe0.95Mn0.05PO4/C Using FeCl3 Etching Waste as Iron Source

2013 ◽  
Vol 457-458 ◽  
pp. 191-196
Author(s):  
Guang Hui Guo ◽  
Shan Chen ◽  
Fang Fang Liu ◽  
Li Yu Zhang
Keyword(s):  
Electron Microscopy ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Morphological Properties ◽  
Electrochemical Performances ◽  
X Ray ◽  
Material Life ◽  
Iron Source ◽  
Scanning Electron ◽  
Discharge Test

In this paper, LiFe0.95Mn0.05PO4/C was prepared by using simulated FeCl3 etching waste as iron source for lithium-ion battery cathode materials. The structural and morphological properties of the samples were characterized by X-ray powder diffraction (XRD) and Scanning electron microscopy (SEM). The electrochemical performances of the sample were also investigated with charge and discharge test. The achieved results indicate that product obtained was confirmed to be LiFe0.95Mn0.05PO4 and has the advantage of high purity, small size and good electrochemical performance.

Synthesis and Electrochemical Performance of K-Doped Li4Ti5O12 as Anode Material for Lithium-Ion Batteries

2014 ◽  
Vol 633-634 ◽  
pp. 495-498
Author(s):  
Xiao Bing Huang ◽  
Hong Hui Chen ◽  
Shi Biao Zhou ◽  
Yuan Dao Chen ◽  
Bei Ping Liu ◽  
...  
Keyword(s):  
Lithium Ion ◽  
Rate Performance ◽  
X Ray Diffraction ◽  
Solid State Method ◽  
X Ray ◽  
State Method ◽  
Traditional Solid State Method ◽  
Initial Capacity ◽  
Charge Discharge ◽  
Discharge Test

Spinel Li4-xKxTi5O12(x=0, 0.03) were successfully synthesized by a traditional solid-state method and systematically investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and the charge-discharge test, respectively. The results demonstrated that Li3.97K0.03Ti5O12exhibited much better rate performance in comparsion with Li4Ti5O12. At 0.2 C and 10 C, it delivered a discharge capacity of 173 mAh g-1and 124 mAh g-1respectively, and after 100 cycles at 10 C, 96.1% of its initial capacity was retained.

scholarly journals Rapid Microwave Synthesis of β-SnWO4 Nanoparticles: An Efficient Anode Material for Lithium-Ion Batteries

2020 ◽  
Author(s):  
Sumedha N ◽  
Mabkhoot Alsaiari ◽  
Mohammed Jalalah ◽  
Shashank M ◽  
Fahad Alharthi ◽  
...  
Keyword(s):  
Electron Microscope ◽  
Transmission Electron Microscope ◽  
Structural Parameters ◽  
Lithium Ion ◽  
High Specific Capacitance ◽  
Stoichiometric Ratio ◽  
X Ray ◽  
Transmission Electron ◽  
Adsorption Desorption ◽  
Charge Discharge

Abstract Here, we report a facile synthesis of β-SnWO4 nanoparticles via microwave heat treatment using SnCl2 and H2WO4, in the presence of tamarind seed powder. X-ray diffraction analysis confirmed the crystalline nature, revealing a cubic structure of β-SnWO4 nanoparticles. Morphological features were visualized using a scanning electron microscope which exhibited homogenously distributed clusters of nanoparticles which were further confirmed using transmission electron microscope. The micrographs also displayed some porosity. Energy dispersive X-ray spectroscopy confirmed the elemental contents such as tin, oxygen and tungsten in the same stoichiometric ratio as expected by the respective empirical formula. High-resolution transmission electron microscope was used to find the d-spacing which was ultimately used to analyze the structural parameters. The spectrum obtained using Fourier transform infrared spectroscopy illuminates different stretching vibrations. Additionally, Barrett-Joyner-Halenda analysis was carried out to investigate N2 adsorption-desorption isotherm as well as to govern the pore size distribution. Cyclic voltammetry measurements were implemented to analyze the ongoing electrode reactions throughout the charge/discharge for β-SnWO4 nanostructures. The galvanometric charge/discharge curves for β-SnWO4 have also been discussed. A high specific capacitance (600 mAhg-1 at 0.1 C) and excellent columbic efficiency (~100%) was achieved.

scholarly journals Rapid Microwave Synthesis of β-SnWO4 Nanoparticles: An Efficient Anode Material for Lithium Ion Batteries

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 334
Author(s):  
H. N. Sumedha ◽  
Mabkhoot A. Alsaiari ◽  
Mohammed S. Jalalah ◽  
M. Shashank ◽  
Fahad A. Alharthi ◽  
...  
Keyword(s):  
Electron Microscope ◽  
Transmission Electron Microscope ◽  
Structural Parameters ◽  
Lithium Ion ◽  
High Specific Capacitance ◽  
Stoichiometric Ratio ◽  
X Ray ◽  
Transmission Electron ◽  
Adsorption Desorption ◽  
Charge Discharge

We report a facile synthesis of β-SnWO4 nanoparticles via a microwave heat treatment using SnCl2 and H2WO4 in the presence of tamarind seed powder. An X-ray diffraction analysis confirmed a crystalline nature revealing a cubic structure of β-SnWO4 nanoparticles. The morphological features were visualized using a scanning electron microscope that exhibited homogenously distributed clusters of nanoparticles, which were further confirmed using a transmission electron microscope. The micrographs also displayed some porosity. Energy dispersive X-ray spectroscopy confirmed the elemental contents such as tin, oxygen and tungsten in the same stoichiometric ratio as expected by the respective empirical formula. A high-resolution transmission electron microscope was used to find the d-spacing, which was ultimately used to analyze the structural parameters. The spectrum obtained using Fourier transform infrared spectroscopy illuminated different stretching vibrations. Additionally, a Barrett–Joyner–Halenda analysis was carried out to investigate the N2 adsorption-desorption isotherm as well as to govern the pore size distribution. Cyclic voltammetry measurements were implemented to analyze the ongoing electrode reactions throughout the charge/discharge for the β-SnWO4 nanostructures. The galvanometric charge/discharge curves for β-SnWO4 are also discussed. A high specific capacitance (600 mAhg–1 at 0.1 C) and excellent columbic efficiency (~100%) were achieved.

Preparation and Electrochemical Properties of LiMn2O4 Nanofibers via Electrospinning for Lithium Ion Batteries

2012 ◽  
Vol 562-564 ◽  
pp. 799-802 ◽  
Author(s):  
Shuai Liu ◽  
Yun Ze Long ◽  
Hong Di Zhang ◽  
Bin Sun ◽  
Cheng Chun Tang ◽  
...  
Keyword(s):  
Discharge Capacity ◽  
Lithium Ion ◽  
Average Diameter ◽  
Potential Range ◽  
Charge Capacity ◽  
High Discharge ◽  
High Discharge Capacity ◽  
Initial Charge ◽  
Charge Discharge ◽  
Scanning Electron

LiMn2O4 nanofibers were prepared via electrospinning and followed by calcination. The surface morphology of as-spun and pure LiMn2O4 nanofibers was characterized by a scanning electron microscope (SEM) with an average diameter of 180 nm. After calcination at 800 °C in air for 5 h, charge/discharge capacity of pure LiMn2O4 nanofibers was measured in the potential range of 3.0 to 4.3 V. Battery testing showed that LiMn2O4 have a high discharge capacity of 80 mAh/g and 85% of the initial charge capacity was maintained for 5 cycles.

Synthesis of MoS2/C Submicrosphere by PVP-Assisted Hydrothermal Method for Lithium Ion Battery

2012 ◽  
Vol 531 ◽  
pp. 471-477 ◽  
Author(s):  
Hao Luo ◽  
Ling Zhi Zhang ◽  
Lu Yue
Keyword(s):  
Hydrothermal Reaction ◽  
Specific Capacity ◽  
Sodium Molybdate ◽  
Lithium Ion ◽  
Charge Capacity ◽  
X Ray ◽  
Structure And Morphology ◽  
Transmission Electron ◽  
Scanning Electron ◽  
Better Than

Molybdenum disulfide/carbon (MoS2/C) submicrosphere was synthesized through a PVP-assisted hydrothermal reaction of sodium molybdate and thiourea (CS(NH2)2), The structure and morphology of MoS2 composites were characterized by X-ray powder diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscopy (TEM). The lithium intercalation/de-intercalation behavior of as-prepared MoS2 submicrosphere electrode was also investigated. It was found that the MoS2 submicrosphere electrode exhibited the best electrochemical performance, retaining a specific capacity of 575mAh/g after 100 cycles, with higher first charge capacity (1037 mAh/g), which was better than those of the MoS2 prepared without PVP

Sign in / Sign up

Export Citation Format

Share Document