Preparation and Electrochemical Properties of LiMn2O4 Nanofibers via Electrospinning for Lithium Ion Batteries

2012 ◽  
Vol 562-564 ◽  
pp. 799-802 ◽  
Author(s):  
Shuai Liu ◽  
Yun Ze Long ◽  
Hong Di Zhang ◽  
Bin Sun ◽  
Cheng Chun Tang ◽  
...  

LiMn2O4 nanofibers were prepared via electrospinning and followed by calcination. The surface morphology of as-spun and pure LiMn2O4 nanofibers was characterized by a scanning electron microscope (SEM) with an average diameter of 180 nm. After calcination at 800 °C in air for 5 h, charge/discharge capacity of pure LiMn2O4 nanofibers was measured in the potential range of 3.0 to 4.3 V. Battery testing showed that LiMn2O4 have a high discharge capacity of 80 mAh/g and 85% of the initial charge capacity was maintained for 5 cycles.

2021 ◽  
Author(s):  
Jinkwang Hwang ◽  
Rika Hagiwara ◽  
Hiroshi Shinokubo ◽  
Ji-Young Shin

Dual-ion sodium-organic secondary batteries were provided with antiaromatic porphyrinoid, NiNc as an active electrode material, which implemented inherent charge-discharge behaviors with high discharge capacity, high stability, high Coulombic efficiency with...


2020 ◽  
Vol 4 (4) ◽  
pp. 1704-1711
Author(s):  
Zige Tai ◽  
Ming Shi ◽  
Wei Zhu ◽  
Xin Dai ◽  
Yanfei Xin ◽  
...  

We prepared carbon-coated β-MnO2 for the cathode of a lithium-ion battery with high discharge capacity.


2016 ◽  
Vol 4 (19) ◽  
pp. 7289-7296 ◽  
Author(s):  
T. Kimijima ◽  
N. Zettsu ◽  
K. Yubuta ◽  
K. Hirata ◽  
K. Kami ◽  
...  

Highly dispersed primary Li(Ni1/3Co1/3Mn1/3)O2 crystals, which showed high discharge capacity at a high C-rate, were grown from a Li2MoO4 flux.


2007 ◽  
Vol 280-283 ◽  
pp. 671-676 ◽  
Author(s):  
Hong Wei Chan ◽  
Jenq Gong Duh ◽  
Shyang Roeng Sheen

Surface modification on the electrode has a vital impact on lithium-ion batteries, and it is essential to probe the mechanism of the modified film on the surface of the electrode. In this study, a Li2O-2B2O3 film was coated on the surface of the cathode material by solution method. The cathode powders derived from co-precipitation method were calcined with various weight percent of the surface modified glass to form fine powder of single spinel phase with different particle size, size distribution and morphology. The thermogravimetry/differential thermal analysis was used to evaluate the appropriate heat treatment temperature. The structure was confirmed by the X-ray diffractometer along with the composition measured by the electron probe microanalyzer. From the field emission scanning electron microscope image and Laser Scattering measurements, the average particle size was in the range of 7-8µm. The electrochemical behavior of the cathode powder was examined by using two-electrode test cells consisted of a cathode, metallic lithium anode, and an electrolyte of 1M LiPF6. Cyclic charge/discharge testing of the coin cells, fabricated by both coated and un-coated cathode material, provided high discharge capacity. Furthermore, the coated cathode powder showed better cyclability than the un-coated one after the cyclic test. The introduction of the glass-coated cathode material revealed high discharge capacity and appreciably decreased the decay rate after cyclic test.


2011 ◽  
Vol 347-353 ◽  
pp. 3506-3509
Author(s):  
Xu Ma ◽  
Yu Ling Liu ◽  
Ling Long Kong ◽  
Yan Hong Ding ◽  
Jie Zhao ◽  
...  

Si/C composites were synthesized by using graphite and glucose as carbon source. The samples were characterized by X-ray diffractometer (XRD) and field emission scanning electron microscope(SEM). The electrochemical charge/discharge test was used to evaluate capacity and cycling stability of the composites. The first discharge and charge capacity of SGC composite using graphite and glucose as carbon source were 1661mAh/g and 1259.1 mAh/g, and the first coulombic efficiency was 75.8%. After 20 cycles, the capacity of SGC composite was 380 mAh/g and the coulombic efficiency remained over 98%.


2015 ◽  
Vol 3 (42) ◽  
pp. 21290-21297 ◽  
Author(s):  
Bing Li ◽  
Chao Li ◽  
Jijun Cai ◽  
Jinbao Zhao

Lithium-rich manganese-based layered oxides with a composition of xLi2MnO3·(1 − x)LiMO2 (M = Mn, Co, Ni, etc.) are attractive, due to their high discharge capacity.


2008 ◽  
Vol 20 (22) ◽  
pp. 4269-4273 ◽  
Author(s):  
Jung-wook Seo ◽  
Jung-tak Jang ◽  
Seung-won Park ◽  
Chunjoong Kim ◽  
Byungwoo Park ◽  
...  

1999 ◽  
Vol 575 ◽  
Author(s):  
S. Fujitani ◽  
H. Fujimoto ◽  
T. Nohma ◽  
K. Nishio

ABSTRACTLiNi1−xCoxO2(x=0.2, 0.3, 0.4) was synthesized through a sintering process from two different types of source materials of nickel and cobalt, namely each respective hydroxide and oxide, and composite hydroxide. Influence of the difference on charge-discharge characteristics, crystal structure and distribution of the metal elements was investigated.The composite hydroxides formulated in Ni1−xCox(OH)2 as the source material brought better homogenized composite lithiated nickel based metal oxides exhibiting the larger specific discharge capacity. Further modification of LiNi0.6Co0.4)2 by manganese through sintering from the composite hydroxide including manganese brought a good charge-discharge cycle performance as well as a high discharge capacity of 160mAh/g level.A cylindrical test cell of 18mm in diameter and 65mm in height using the LiNi0.6Co0.3Mn0.1O2 exhibited discharge capacity of 1700mAh which is larger than that using LiCoO2, and also exhibited a competitive charge-discharge cycle performance to commercialized lithium ion batteries.


2006 ◽  
Vol 510-511 ◽  
pp. 1078-1081
Author(s):  
Wen Jie Jin ◽  
Taek Rae Kim ◽  
Seung Hwan Moon ◽  
Yun Soo Lim ◽  
Myung Soo Kim

Carbon nanofibers and nano-size metal particles were incorporated into the surface of graphite particles. The carbon nanofibers prepared from the decomposition of ethylene over nickelcopper catalyst and the micro-size silicon particles were directly introduced into the graphite particles by mixing. Nano-size tin particles were also incorporated into the graphite particles by impregnation. The three different graphite composites were tested as anode base materials for lithium ion secondary battery. The incorporation of a certain amount of carbon nanofibers into the graphite electrode improved the cyclic performance as well as the initial charge/discharge capacity. With the introduction of silicon, the initial charge/discharge capacity increased but exhibited the bad cyclic characteristics. With the modification with tin, an improved electrochemical performance was observed in both initial charge/discharge capacity and cyclic characteristics.


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