The Influence of Technical Factor and Ingredient Design on Crystallization Behavior of MgO-SiO2-Al2O3-B2O3-KF Glass-Ceramics

2012 ◽  
Vol 446-449 ◽  
pp. 1054-1058
Author(s):  
Xiao Li Zhang ◽  
Ji Wei Fan ◽  
Ping Fan

In this paper, the the micro crystallization behavior of MgO-SiO2-Al2O3-B2O3-KF glass-ceramics which was prepared by sintering and water quenching method was discussed. The study indicated that the compacts shrinkage of MgO-SiO2-Al2O3-B2O3-KF glass-ceramics were related to its vitrification and its component crystallization degree; about the density of sintered compacts, the higher the crystallization degree, the higher the dense it owns. The conclusion reached above is significant in dimension control to the produce process. In the samples when the proportion of ingredient was closer to the atomic ratio of mica crystal, the higher the micro crystallization degree of the glass-ceramics will be. When sintering temperatuer is 1000oC,the MgO-SiO2-Al2O3-B2O3-KF glass-ceramics begain to present the crystallization; when it achieves to 1050°C, the crystallization degree is highest; continue to increase the sintering temperature, the micro crystallization will be melted again.

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Nur Fatin Syamimi ◽  
Khamirul Amin Matori ◽  
Way Foong Lim ◽  
Sidek Abdul Aziz ◽  
Mohd Hafiz Mohd Zaid

Willemite- (Zn2SiO4-) based glass ceramics doped with various amounts of europium oxide (Eu2O3) were prepared by solid state melting and quenching method. Effect of sintering temperature (600–1000°C) on structural and morphological properties of the doped samples was investigated. Phase composition, phase evolution, functional groups, and microstructure analysis were, respectively, characterized using X-ray diffractometer (XRD), fourier transform infrared spectroscopy, field emission scanning electron microscopy (FE-SEM), and energy-dispersive X-ray. XRD analysis detected the presence of rhombohedral crystalline phase in the doped samples sintered at different temperatures. FE-SEM and bulk density results confirmed that doping of the willemite with Eu2O3effectively enhanced densification. The microstructural analysis of the doped samples showed that the average grain size increased with the increase of sintering temperature.


2015 ◽  
Vol 31 (11) ◽  
pp. 1158-1160 ◽  
Author(s):  
Shuming Wang ◽  
Fenghua Kuang ◽  
Dazhan Zhang ◽  
Xu Zhou ◽  
Minghui Tang

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