The Application of Corrosion and Scale Inhibitor to Circulating Water

2012 ◽  
Vol 610-613 ◽  
pp. 2591-2594
Author(s):  
Jia Guo Ren ◽  
Qian Qian Wu

According to the requirements of the circulating water treatment, a corrosion and scale inhibitor which compounded several single corrosion inhibitor and scale inhibitor was prepared, resulting in simplifying the process of operation, improving the concentration ratio of circulating water from 2.2 to 2.8, reducing the sewage volume, and decreasing the corrosion rate and cohesion rate. Therefore, the economic efficiency of the power plant gets greatly improved.

Author(s):  
Ruizhu Hu ◽  
Tinglin Huang ◽  
Tianwei Wang ◽  
Huixin Wang ◽  
Xiao Long

The circulating pellet fluidized bed (CPFB) softening method is a highly efficient and environmentally friendly softening technology that can be used to reduce water hardness during the pretreatment process of circulating water in thermal power plants. The performance of chemical crystallization CPFB reactors was tested for increasing the concentration ratio and softening the circulating water in a thermal power plant in Dingzhou, Hebei. The results show that usage of CPFB reactors removed water hardness and Ca2+ ions with efficiencies exceeding 60% and 90%, respectively. The size of the particles discharged from the reactors was approximately 1–3 mm, and the content of CaO in these particles was found to be greater than 50%. All the discharged particles were reused in the desulfurization system in the power plant. The operational cost of the CPFB system is US$0.074 per cubic meter of water. After adopting the proposed CPFB softening method in the Dingzhou Power Plant, the concentration ratio of the circulation cooling water was increased from 4.5 to more than 9. In addition, the amount of replenished water and sewage discharge were both reduced by 150 m3/h, and the amount of scale inhibitor used in the system was reduced by more than 30%. These improvements contribute to approximately US$200,000 in annual savings in the power plant. In summary, the CPFB softening method demonstrated a high hardness removal rate, strong economic benefits, and remarkable environmental and social benefits. Therefore, this method seems ideal for softening replenished circulating cooling water, increasing the concentration ratio of the water and achieving zero liquid discharge (ZLD) in thermal power plants.


2012 ◽  
Vol 40 (4) ◽  
pp. 1025-1037
Author(s):  
Mahmoud Bady ◽  
Hassanien Manaa ◽  
Adel M. Kamal El- Dean ◽  
A. M Hussein

2001 ◽  
Vol 1 (3) ◽  
pp. 91-96 ◽  
Author(s):  
L.J. Hem ◽  
E.A. Vik ◽  
A. Bjørnson-Langen

In 1995 the new Skullerud water treatment plant was put into operation. The new water treatment includes colour removal and corrosion control with an increase of pH, alkalinity and calcium concentration in addition to the old treatment, which included straining and chlorination only. Comparative measurements of internal corrosion were conducted before and after the installation of the new treatment plant. The effect of the new water treatment on the internal corrosion was approximately a 20% reduction in iron corrosion and a 70% reduction in copper corrosion. The heavy metals content in standing water was reduced by approximately 90%. A separate internal corrosion monitoring programme was conducted, studying the effects of other water qualities on the internal corrosion rate. Corrosion coupons were exposed to the different water qualities for nine months. The results showed that the best protection of iron was achieved with water supersaturated with calcium carbonate. Neither a high content of free carbon dioxide or the use of the corrosion inhibitor sodium silicate significantly reduced the iron corrosion rate compared to the present treated water quality. The copper corrosion rate was mainly related to the pH in the water.


2021 ◽  
Author(s):  
Zhao Xionghu ◽  
Saviour Bassey Egwu ◽  
Deng Jingen ◽  
Miao Liujie

Abstract The effect of corrosion inhibitor Benzotriazole on synthetic-based mud system was studied. Rheological performance of the benzotriazole enhanced synthetic-based fluid system was studied and compared against the base mud. To study its effect on dynamic wellbore conditions, different drilling fluid compositions were placed in a hot rolling oven for 16 hours at temperatures 150 °C and 170°C and the effect of temperature on mud properties were studied. Tests carried out include rheological test (before and after hot rolling), filtrate pH, lubricity test, and fluid loss test. The corrosion penetration rate was studied using the weight loss method. Based on experiment results, the synthetic-based mud system which comprised of benzotriazole displayed a reduction in coefficient of friction up to 95.93%. At ambient condition, optimal ratio of mineral oil:benzotriazole (M:B) which gives best lubricity performance on synthetic-based mud system is 80:20. This leads to improved corrosion inhibition and lubricity of the synthetic-based fluid by reducing the coefficient of friction up to 90.13%. Increased temperature led to further decrease in coefficient of friction with a % torque reduction of 95.93 displayed by the 80:20 ratio M:B mud composition at 170 °C. Significant alterations of the mud composition rheological and fluid loss parameters before and after exposure to high temperature in hot rolling oven were not observed. pH values were maintained ≥7 at the dynamic conditions highlighting solubility of the formulated fluid composition and absence of contaminants which can pose significant threats to the rates of corrosion in drill pipes. Increasing the concentration of Benzotriazole led to a reduction in corrosion rate. However, as the temperature effect increased, the corrosion rate elevated. Based on results from this investigation, it was concluded that Benzotriazole can be applied as a corrosion inhibitor in a synthetic-based drilling fluid system as an alternative corrosion inhibitor without significant alteration of the base mud properties. Benefits of this will be the optimization of extended reach well drilling operations due to excellent lubricity performance, corrosion rate reduction, compatibility with HPHT wellbore condition and fluid loss control.


2021 ◽  
Author(s):  
Bagus Muliadi Nasution ◽  
Andrew Yonathan ◽  
Muthi Abdillah ◽  
Wang Zhen

Abstract Organic acid has been widely applied for inorganic scale treatment in oil and gas industry including well stimulation and scale inhibitor. Thanks to its low corrosivity and slower reaction rate with rock, organic acid is considered to offer better performance comparing to strong acid - Hydrochloric Acid (HCl). Yet, proper treatment requires vigorous analysis and experiment in order to meet foremost expectations. Besides, mistreatment of scale could result in formation damage including clay precipitation. Pre-treatment experiments were performed on Zelda field at South East Sumatera block, that has faced with scale problem for ages. Water sample was taken from flowing Zelda A-08 well to be analyzed for mineral's saturation level. Scale was extracted from three sources including tubing, sand bailer, and Electrical Submersible Pump (ESP) of Zelda A-08. Those scale were treated in X-Ray Powder Diffraction (XRD) for mineral composition, and solubility test that utilized two types of acid system - formic acid (HCOOH) and hydrochloric acid (HCl) for comparison. Anti-swelling test and corrosion test were performed to examine the effectiveness of clay stabilizer and corrosion inhibitor. As for carbonate analysis, both formic acid 9% and HCl 15% have comparable solubility (98.17% vs 98% for tubing's scale, 91.86% vs 82.79% for ESP's scale, and 70.30% vs 68.07% for sand bailer's scale). Yet, longer reaction is carried out by formic acid 9% (1 hour) comparing to HCl 15% (18 minutes). For silicate analysis, HF-formic acid provided the higher solubility than HF-HCl (8.34% vs 5.67% for ESP's scale and 30.48% vs 25.68% for sand bailer's scale). On anti-swelling test, by reducing swelling tendency up to 62.6%, it proves that examined clay stabilizer works perfectly against swelling potential of clay, despite of high swelling tendency of sand bailer's scale (25.8%). On corrosion test, adding on corrosion inhibitor (pyridine-based) into solution results in regular HCl 15% has corrosion rate 26.279 g/m2.h which is much higher (300%) than HF-HCl (7.977 g/m2.h) and HF-formic acid (8.229 g/m2.h). Based on pre-treatment test, formic acid 9% together with examined corrosion inhibitor and clay stabilizer, can be used as an alternative to regular HCl 15% for stimulation purpose where more areas will be covered that previously left unreachable by regular acid 15%. In addition, potentially more effective squeezed scale inhibitor using organic acid can also be achieved by performing further experiments. The method presented in this paper for pre-treatment experimental studies of organic acid can provide engineers with intensive guide to meet the best result of organic acid treatment.


2011 ◽  
Vol 99-100 ◽  
pp. 350-353
Author(s):  
Xiao Bing Sun ◽  
Xu Bin Qiao

As the largest unit capacity of nuclear power plant at present, the flow conduit of circulating water pump in EPR1750 nuclear power plant is a volute conduit, which is a cast-in-situ conceret structure with complexly gradual change cavity. Therefore, the hydraulic efficiency of circulating water pump is not only related with the design of pump leaves, but also closely related to the design of volute and the complicated spatial type of intake and outtake conduits. With the pump leaves and the intake and outtake conduits of conceret volute as the research model, based on computational fluid dynamics (CFD)and the three dimensional Reynolds averaged Navier-Stokes equations, an analytic model suitable for computation is established to simulate the three-dimensional steady flow in the whole pumping system under different operating modes. By use of the commercial fluid-computation softer ANSYS, the distribution of basic physic quantities in the fluid field inside the pump and the conduits is obtained. The analysis and prediction of the performance of pump system are made, and the spatial type design of intake and outtake conduits is evaluated. The calculation results can be referenced to improve the design of pump systems in the similar projects.


2018 ◽  
Vol 159 ◽  
pp. 02027 ◽  
Author(s):  
Abdul Hamid ◽  
Sri Nugroho ◽  
Gunawan Dwi Haryadi ◽  
Khaeroman

Pump shafts are generally exposed to the liquid being pumped either on a continual basis or at certain locations along the length of the shaft. The shaft material is austenitic stainless steel, description ASTM AU 79 TY 316. The purpose of this study is to determine the failure of the water pump shaft used in the power plant. Metallography is the study of structure metal shaft can used as a means for CWP metal pelleting (Circulating Water Pump), for the purpose of damaged or deeply degraded areas. SEM test is used to know the beginning of the crack (crack initiation). EDS test is used to chemical composition and Vikers hardness test is also used to know the hardness material. These three tests to support in analyzing the failure of the pump shaft. The conclusion of this failure analysis is the shaft material has porosity. Fatigue cracking comes from the outer surface area.


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