Arc-Spraying Composite Coatings on Mild Steel for Long-Term High-Temperature Oxidation Protection

2013 ◽  
Vol 690-693 ◽  
pp. 2039-2045
Author(s):  
Zhong Li Zhang ◽  
Qi Shen Wang ◽  
Peng Rao Wei ◽  
Xue Gong
Keyword(s):  
High Temperature ◽  
High Temperature Oxidation ◽  
Protective Coatings ◽  
Steel Substrate ◽  
Composite Coatings ◽  
Arc Spraying ◽  
Al Alloy ◽  
Temperature Oxidation ◽  
Oxidation Protection

An arc-spraying composite coating system for high-temperature oxidation protection is composed of an inner Fe-Cr-Al alloy layer and an Al-Si alloy outer layer. The high-temperature oxidation behavior of the composite coatings on steel substrate was studied during isothermal exposures in air at 900°C. Experiments show that the coatings on steel substrate are not deteriorated and the substrate is protected well, being exposed to high temperatures up to 900°C. Inter diffusion of alloying elements within the protective coatings occur, while the elements, Cr and Al, are also diffusing to the core of the base metal. As test time proceeds, a large number of chromium oxides are generated in situ within the protective coatings, especially close to the coating/substrate interface. The oxides generated increase the bond strength of the coating to the steel substrate, and together with the surface alumina they provide a long-term effective anti-oxidant protection to steel substrate. The results on titanium sponge production site show that the protective coatings on the reactor have provided an effective protection and prolong the lifetime at least forty percent for the reactors.

High-Temperature Oxidation Resistance of Electroless Ni-P-ZrO2 Composite Coatings

2011 ◽  
Vol 686 ◽  
pp. 569-573 ◽  
Author(s):  
Ming Feng Tan ◽  
Wan Chang Sun ◽  
Lei Zhang ◽  
Quan Zhou ◽  
Jin Ding
Keyword(s):  
High Temperature ◽  
Carbon Steel ◽  
Oxidation Resistance ◽  
High Temperature Oxidation ◽  
Steel Substrate ◽  
Composite Coatings ◽  
Low Carbon ◽  
Temperature Oxidation ◽  
P Matrix ◽  
Electroless Ni

Electroless Ni-P coating containing ZrO2particles was successfully co-deposited on low carbon steel substrate. The surface and cross-sectional micrographs of the composite coatings were observed with scanning electron microscopy (SEM). And the chemical composition of the coating was analyzed with energy dispersive spectroscopy (EDS). The oxidation resistance was evaluated by weight gains during high temperature oxidation test. The results showed that the embedded ZrO2particles with irregular shape uniformly distributed in the entire Ni-P matrix, and the coating showed a good adhesion to the substrate. The weight gain curves of Ni-P-ZrO2composite coatings and Ni-P coating at 923K oxidation experiments were in accordance with . The ZrO2particles in Ni-P matrix could significantly enhance the high temperature oxidation resistance of the carbon steel substrate as compared to pure Ni-P coating.

High Temperature Oxidation Behavior of Arc-sprayed FeCrBAlMo Coating

2016 ◽  
Vol 19 (1) ◽  
Author(s):  
Xin Zhang ◽  
Zehua Wang ◽  
Jinran Lin
Keyword(s):  
High Temperature ◽  
High Temperature Oxidation ◽  
Oxidation Behavior ◽  
Steel Substrate ◽  
Arc Spraying ◽  
X Ray Diffraction ◽  
Temperature Oxidation ◽  
X Ray ◽  
High Velocity Arc Spraying ◽  
High Temperature Oxidation Behavior

AbstractFeCrBAlMo coating was deposited on an AISI 20 steel substrate by high velocity arc spraying (HVAS). Compared with FeCrBSiMo coating and pristine AISI 20 steel, the microstructure and high temperature oxidation behavior of FeCrBAlMo coating were investigated by optical microscopy, scanning electron microscopy, energy-dispersive spectroscopy and X-ray diffraction. Meanwhile, the bonding strength of the coatings was also measured. The results indicated that both coatings were composed of α(Fe,Cr) and Fe

High Temperature Oxidation Behaviors of Ni-Cr Based Thermal Sprayed Coatings

2009 ◽  
Vol 79-82 ◽  
pp. 691-694
Author(s):  
Liu Ying Wang ◽  
Gu Liu ◽  
Yong Fa Wu ◽  
Shao Chun Hua ◽  
Jian Xun Yao
Keyword(s):  
High Temperature ◽  
Carbon Steel ◽  
High Temperature Oxidation ◽  
Steel Substrate ◽  
Medium Carbon Steel ◽  
Arc Spraying ◽  
Gravimetric Analysis ◽  
Temperature Oxidation ◽  
Cr Coating ◽  
Oxidation Behaviors

Ni-Cr coating and Ni-Cr/ZrO2 gradated coating were deposited on C45 carbon steel by high velocity arc spraying and micro-plasma spraying to solve the high temperature oxidation problem of medium carbon steel components. The oxidations of Ni-Cr coating, Ni-Cr/ZrO2 gradated coating and C45 carbon steel substrate were carried out for up to 108 hours in air atmosphere at 1100°C. The oxidation behaviors were investigated after detailed examinations by thermal gravimetric analysis (TGA), x-ray diffraction (XRD) and scanning electron microscopy (SEM). Ni-Cr coating and Ni-Cr/ZrO2 gradated coating show similar and low dynamics curve near to the logarithms function. Surface observations with SEM and XRD reveal that the oxidizing surface of the C45 carbon steel substrate is mainly a loose spherical structure consisted of mainly Fe2O3 and Fe3O4. The surface structures of Ni-Cr coating and Ni-Cr/ZrO2 gradated coating after 108 hours oxidization are rather denser than that of C45 carbon steel, which can effectively improve the properties of the oxidation resistance of C45 carbon steel substrate.

The Structures and High Temperature Properties of FeMnCrNiAl/Cr3C2 Composite Coatings by High Velocity Arc Spraying

2011 ◽  
Vol 130-134 ◽  
pp. 1532-1538
Author(s):  
Yong Jun Chao ◽  
Jun Jie Weng ◽  
Shao Guang Liu ◽  
Jian Li ◽  
Jin Peng Sang
Keyword(s):  
High Temperature ◽  
High Velocity ◽  
Steel Substrate ◽  
Composite Coatings ◽  
Arc Spraying ◽  
Micro Hardness ◽  
Temperature Oxidation ◽  
High Temperature Properties ◽  
Binding Strength ◽  
High Velocity Arc Spraying

The FeMnCrNi/Cr3C2 inter metallic composite coatings are prepared by high velocity arc spraying (HVAS) technology on 20G steel. The properties, such as the microstructure, micro hardness, binding strength, high temperature oxidation, thermal shock resistance, and erosion in high temperature, are studied based on methods such as analysis of optical microscope, micro hardness, field emission scanning electron microscope (FESEM), and spectrum analysis. The result shows that FeMnCrNiAl/Cr3 C2 coatings, compared with 20G steel substrate, present higher micro hardness, binding strength and more excellent high temperature properties, which will be improved if added with rare-earth Alloy.

scholarly journals High-Temperature Oxidation Properties and Microstructural Evolution of Nanostructure Fe-Cr-Al ODS Alloys

Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 526
Author(s):  
Zhengyuan Li ◽  
Lijia Chen ◽  
Haoyu Zhang ◽  
Siyu Liu
Keyword(s):  
High Temperature ◽  
Oxide Layer ◽  
Microstructural Evolution ◽  
High Temperature Oxidation ◽  
Oxide Dispersion Strengthened ◽  
Al Alloy ◽  
Temperature Oxidation ◽  
X Ray ◽  
Plasma Sintering ◽  
Ods Alloys

The oxidation behavior and microstructural evolution of the nanostructure of Fe-Cr-Al oxide dispersion strengthened (ODS) alloys prepared by spark plasma sintering were investigated by high-temperature oxidation experiments in air at 1200 °C for 100 h. The formation of Al2O3 scale was observed by X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS) line scans. The oxidation rate of Fe-Cr-Al ODS alloys is lower than that of conventional Fe-Cr-Al alloys, and the oxide layer formed on the Fe-Cr-Al alloy appeared loose and cracked, whereas the oxide layer formed on the Fe-Cr-Al ODS alloys was adherent and flat. This is due to the high density of dispersed nano-oxides hindering the diffusion of Al element and the formation of vacancies caused by them. In addition, the nano-oxides could also adhere to the oxide layer. Besides, the microstructure of the Fe-Cr-Al ODS alloy had excellent stability during high-temperature oxidation.

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