The Pressure Differential Analysis of LiCl Solution Absorption Process

2013 ◽  
Vol 732-733 ◽  
pp. 541-547
Author(s):  
Chun Li Tang ◽  
Qian Wang

To improve indoor air quality, mass transfer is an important part in air handling process, which is helpful for the control of humidity of air. This paper presents mass transfer dynamic analysis of isothermal and opposite flow process theoretically. The pressure difference analysis is used to show the changing of pressures of two phases in dehumidification process. It calculates the partial pressure of water vapor in wet air and the vapor pressure of LiCl solution. Also it gives the curves of pressure change in dehumidification of isothermal and opposite flow by lithium chloride. Results from this paper can be used as theoretical foundation for the experimental design of dehumidification of air by LiCl solution.

2011 ◽  
Vol 19 (03) ◽  
pp. 167-175 ◽  
Author(s):  
ZAN-SHE WANG ◽  
ZHAO-LIN GU ◽  
GUO-ZHENG WANG ◽  
FENG CUI ◽  
SHI-YU FENG

A novel membrane heat exchanger was proposed and analyzed. It was expected that the novel heat exchanger could be applied to the lithium bromide absorption chiller. Polyvinylidene fluoride hollow fiber module was adopted as the solution heat exchanger. The hot feed solution from the generator flowed into the lumen side of the membranes while the cold feed solution from the absorber flowed away from the shell side. Heat transfer and mass transfer occurred simultaneously in the membrane module, and only water vapor could diffuse across the membrane pore due to the water vapor pressure difference between the inside and outside of the membrane. Mathematical equations of the heat and mass transfer processes in the membrane heat exchanger were built, and the parallel flow process and the counter flow process were compared by numerical simulation. The simulation results show that the counter flow process was the better flow mode because the mean temperature difference was larger and the mass transfer was more steadily from the lumen side to the shell side. The heat caused by water vapor mass transfer may account for one-third of the total heat transfer. As a result, the membrane heat exchanger not only reinforced the heat recovery but also enlarged the deflation range and reduced the circulation rate and the heat loads of the generator and absorber. Eventually, the coefficient of performance of the heat exchanger was increased.


Author(s):  
L. Y. Zhang ◽  
Y. Li ◽  
Y. Wang ◽  
L. X. Cao ◽  
X. Z. Meng

Absorber is an important component in absorption refrigerating system. Its performance plays a significant role on the overall efficiency of absorption refrigerating system. The nanofluids which can enhance the heat and mass transfer will be utilized to absorber for enhancing the water vapor absorption process and improving the absorber efficiency. The software CFD-FLUENT is used to analyze the falling film absorption process of the nanofluids, which consists of H2O/LiBr solution with Fe3O4 nanoparticles in this paper. The results indicate that the enhancing heat and mass transfer of nanofluids is related to the nanoparticle concentration and size. The stronger the nanoparticle concentration, the greater enhancement of heat and mass transfer of falling film; while the smaller the nanoparticle size, the greater enhancement of heat and mass transfer of falling film. It is also found that the enhancement ratio of heat and mass transfer flux reach 1.48 and 1.37, respectively, as the Fe3O4 nanoparticles mass concentration of 0.01wt% and the size of 50nm.


Author(s):  
E. D. Rogdakis ◽  
V. D. Papaefthimiou

One of the most important components of an absorption air-conditioning/heat pump system is the absorber, where the refrigerant water vapour is absorbed into the liquid solution. While absorption systems have been in use for several years, the complex transport phenomena occurring in the absorber are not fully elucidated yet. Thus, an attempt is made to model the absorption process of water vapour in aqueous solutions of lithium bromide considering a falling-film, vertical-tube absorber. The proposed analysis is based on the formulation of four differential equations describing the spatial variation (parallel to the tube-axis) of solution mass, temperature, mass fraction and coolant temperature. The system of ordinary differential equations is numerically solved using a non-stiff numerical method. Thermophysical properties and especially, heat and mass transfer coefficients are calculated using widely-accepted and reliable relationships, which are extracted from the literature using recently published information on wavy-laminar flows. In the present study, the questionable assumption of treating the water vapour as an ideal gas is heavily modified utilizing. Consequently, the hypothesis of saturated water vapour at the steam-solution interaction surface is revised by introducing an energy difference between the superheated steam and the liquid water within the binary solution. The last correction encouraged us to compare theoretical results for solution temperature, mass fraction and mass flow rate, which were obtained using both assumptions. It was proved that the initial treatment causes an underestimation of the absorbed steam mass and correspondingly, an underestimation of solution temperature and mass fraction at the mass exchange interface. An attempt is made also to identify the effect of mass transfer coefficient on the effectiveness of the absorption process and on the energy differences between the superheated steam and the liquid water either as pure substance or as component of the binary mixture. It was shown that the increase of mass transfer coefficient leads to an increase of steam mass transfer rate and to a corresponding decrease of solution temperature slope at the entrance of a tube. Correspondingly, the increase of mass transfer coefficient results in an increase of heat of absorption and heat of dilution at the same variation range of the solution mass fraction.


Author(s):  
Ya-Ping Chen ◽  
Chen-Jie Shi ◽  
Ming-Heng Shi ◽  
Chen-Min Ling

Film-inversion is an effective way recently developed to enhance heat and mass transfer in absorbers. However, only one-side of round or rectangular tube i.e. half of the total heat transfer area is used to form film-inverting configuration in the published literature. The paper presents a double-side film-inverting scheme, which consists of two plate bundles and a set of comb shaped conjunction guiders between them for leading solution film from both-sides of each couple of the upper plate bundle to the opposite sides of the bottom ones. A two-scale crosswise corrugation plate bundle, which has vertical large corrugations and horizontal small ones, is suggested instead of the plane plate bundle. The horizontal small corrugation can make the film turbulent and film distribution uniform before and after inversion with surface tension effect, thus increasing the heat and mass transfer coefficients of the absorption process. A mathematic model for heat and mass transfer in absorption process with aqueous Li-Br solution falling film-inverting on two sequential vertical plane plates was established and solved numerically. The distributions of dimensionless velocity, temperature and concentration of liquid film profile before and after film-inverting were obtained. The influence of the number of inversion on heat and mass transfer characteristics was analyzed. The calculation results show that the heat and mass transfer coefficients of the once-film-inverting scheme have about 58% and 73% increment respectively over these of the none film-inverting scheme.


Author(s):  
Hualing Zhang ◽  
Liu Chao

The model of two phases of liquid and vapor flow and vapor condensation under the condition of exerted force was established in parallel nanochannel. Fluid was water molecular and the solid walls are composed of Pt atoms. The process of vapor condensation in nanochannel wall was simulated by molecular dynamic simulation. The different flow patterns of the condensation process of superheated water vapor, which mainly were annular flow, injection flow, slug flow, bubble flow and shrinking bubble flow, were observed under different conditions. For low pressure of water vapor, a new flow pattern which was named as fluctuation flow appeared during condensation process. The simulation results agreed very well with the experimental results provided by references.


2019 ◽  
Vol 7 ◽  
pp. 954-959 ◽  
Author(s):  
Detelin Ganchev Markov ◽  
Sergey Mijorski ◽  
Peter Stankov ◽  
Iskra Simova ◽  
Radositna A. Angelova ◽  
...  

: People are one of the sources for deterioration of the indoor air quality. They worsen indoor air quality by their presence (respiration, bio-effluents), activities and habits. Through respiration, people decrease the oxygen concentration in the air of the occupied space and increase carbon dioxide and water vapor concentration in the indoor air as well as its temperature. The goal of the AIRMEN project is to find out if the rate of consumption of oxygen and emission of carbon dioxide (and water vapor) by people depends on the indoor air temperature as well as carbon dioxide concentration in the inhaled air. In order to achieve this goal a small climate chamber must be designed and constructed which allows for controlling and measuring both inflow and exposure parameters as well as for measuring outflow parameters. The principal goal of this paper is to present some important details, obtained by CFD simulations, from the design process of the climate chamber which precondition the air distribution in the chamber and hence the exposure parameters.


2008 ◽  
Vol 273-276 ◽  
pp. 782-788 ◽  
Author(s):  
C.R. Ruivo ◽  
J.J. Costa ◽  
A.R. Figueiredo

In this paper the numerical modelling of the behaviour of a channel of a hygroscopic compact matrix is presented. The heat and mass transfer phenomena occurring in the porous medium and within the airflow are strongly coupled, and some properties of the airflow and of the desiccant medium exhibit important changes during the sorption/desorption processes. The adopted physical modelling takes into account the gas side and solid side resistances to heat and mass transfer, as well as the simultaneous heat and mass transfer together with the water adsorption/desorption process in the wall domain. Two phases co-exist in equilibrium inside the desiccant porous medium, the equilibrium being characterized by sorption isotherms. The airflow is treated as a bulk flow, the interaction with the wall being evaluated by using appropriated convective coefficients. The model is used to perform simulations considering two distinct values of the channel wall thickness and different lengths of the channel. The results of the modelling lead to a good understanding of the relationship between the characteristics of the sorption processes and the behaviour of hygroscopic matrices, and provide guidelines for the wheel optimization, namely of the duration of the adsorption and desorption periods occurring in each hygroscopic channel.


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