Recovery Copper from a Low Grade and Ultra-Fine-Grained Dissemination Mixed Copper Ore by Flotation

2013 ◽  
Vol 734-737 ◽  
pp. 962-966
Author(s):  
Yong Jun Xian ◽  
Shu Ming Wen ◽  
Hai Ying Shen ◽  
Qi Nie

The present study aims to characterize the copper ore from east area of Yunnan province. The results indicate that the ores is a representative low grade and and ultra-fine-grained ore. As a result, a suitable flotation flow i.e. “ultrafine grinding- sulphidizing and dispersing - bulk flotation with low dosage collector” was presented for processing of eligible copper concentrate with high recovery and the main factors i.e. grinding fineness, regulators types and dosage and collector dosage affecting the indexes of roughing concentration was investigated. As a result, a close-circuit flotation test scheme was proceeded, which obtained a high quality copper concentrate with Cu grade of 25.12%, copper recovery of 87.63%. This index is successful in the aim of recovery copper for such mixed copper ore.

2013 ◽  
Vol 734-737 ◽  
pp. 929-934
Author(s):  
Qi Nie ◽  
Xiao Si Zhou ◽  
Fen Lan Peng ◽  
Xu Shen ◽  
Zhi Zhang Li

Based on the analysis of the properties of the copper ore from Jinggu area in Yunnan province, a suitable technical route was presented for processing of eligible copper concentrate and the main factors i.e. grinding fineness, Na2S dosage and collector dosage, affecting the quality of roughing concentration was investigated. On this basis, a close-circuit flotation test scheme was preceded, which obtained a high quality copper concentrate with Cu grade of 16.08%, copper recovery of 58.52%. The recovery of copper concentrate is much lower than the Cu recovery of roughing concentrate from the condition experiments. This may be contributed to the fact that fine slime carried by middling worsens the separation of copper minerals and gangues. The Mo was enriched in concentrate, which is significantly considered to recovery in further work.


2014 ◽  
Vol 1010-1012 ◽  
pp. 1630-1635
Author(s):  
Jian Gang Ku ◽  
Hui Huang Chen ◽  
Wen Yuan Liu

The copper ore, which has fine-grained nature and differences in the degree of mineral dissemination, is a kind of low grade sulfide minerals. Tests indicate that not only the grinding fineness but also the combination mode of depressants is one of the most important factors to improve the concentrate grade index. Additionally, according to tests conducted with dosage of lime, the rougher flotation should be operated at a pH of 11. Furthermore, all the depressants used were effective to increase the concentrate grade. By the closed-circuit micro-flotation experiment, satisfied grade index (18.7%Cu with 81% recovery) of the final concentrate was achieved, which could provide reference in industrial applications.


2013 ◽  
Vol 734-737 ◽  
pp. 1104-1109
Author(s):  
Yong Jun Xian ◽  
Qi Nie ◽  
Ping Lu

Based on the analysis of the properties of the copper-molybdenum ore from Yunnan province, a suitable technical route was presented for processing of eligible molybdenum and copper concentrate with a high recovery. Moreover, the main factors i.e. grinding fineness and collector dosage, affecting the quality of roughing concentration was investigated. The optimum condition of bulk flotatuon were obtained.


2009 ◽  
Vol 71-73 ◽  
pp. 409-412
Author(s):  
Wen Qing Qin ◽  
Yan Sheng Zhang ◽  
Shi Jie Zhen ◽  
Jun Wang ◽  
Jian Wen Zhang ◽  
...  

The effects of several variables on the column bioleaching of copper sulphide ore have been investigated. The copper ore contained chalcopyrite as the main sulfide minerals and bornite and chalcocite as the minor minerals. The experiment was carried out using bench-scale column leach reactors designed in Key Lab of Biometallurgy of Ministry of Education, which were inoculated with the pure mesophile bacteria (Acidithiobacillus ferrooxidans) and thermophile bacteria (Sulfobacillus), respectively, and the mixed bacteria which contain both iron- and sulfur-oxidizing bacteria. The results show that the mixed cultures were more efficient than the pure cultures alone and the maximum copper recovery 53.64% was achieved using the mixed cultures after 85 days. The leaching rate of chalcopyrite tended to increase with the increased dissolved ferric iron concentration. The effect of particle size on the rate of the copper leaching was also investigated, and it was shown that the copper bioleaching rate decreases as the amount of fines increase, which limits the permeability, thus decreases leaching rate. Jarosite and elemental sulphur formed in the column were characterized by the X-ray and EDS.


2012 ◽  
Vol 524-527 ◽  
pp. 1047-1053 ◽  
Author(s):  
Dian Wen Liu ◽  
Jian Jun Fang ◽  
Xiao Lin Zhang ◽  
Shao Jun Bai ◽  
Zhi Cong Wei ◽  
...  

Tangdan copper oxide ore deposit, located in the northeast Yunnan province of China, is the largest independent copper oxide deposit in China. The ore from the deposit is characterized by low grade, high oxidation ratio and fine-grained dissemination, which results in the poor flotation recovery. The analysis of plant flotation data reveals that the loss of copper minerals into tailings is mainly with coarse size fraction, due to its insufficient liberation and finer size, especially for the size fraction below 10 microns, which are very difficult to be floated with conventional flotation methods. In order to improve the flotation performance of the ore, laboratory tests include Hallimond flotation and vacuum flotation were respectively conducted with pure malachite, the dominant copper oxide mineral in the deposit; and the results indicate that a finer grinding fineness up to -325 mesh even -400 mesh is required to decrease the copper loss in the coarse size fraction, and vacuum flotation provides a promising way for the recovery of ultrafine malachites.


2017 ◽  
Vol 64 (1) ◽  
pp. 3-14 ◽  
Author(s):  
Baisui HAN ◽  
Batnasan ALTANSUKH ◽  
Kazutoshi HAGA ◽  
Yasushi TAKASAKI ◽  
Atsushi SHIBAYAMA

2017 ◽  
Vol 262 ◽  
pp. 202-206 ◽  
Author(s):  
Víctor J. Zepeda ◽  
Ivan Nancucheo ◽  
Milton Guillen ◽  
Enrique Becerra ◽  
Camila Escuti ◽  
...  

Flotation tailings are hazardous due to physical and chemical instability and are currently considered one of the main pollution concerns of mining industry. Most of these tailings are fine-grained residues with low copper content (0.1-0.8%) and include toxic compounds, such as heavy metals, arsenic, and flotation reagents, among others. Another hazard is the generation of acid mine drainage (AMD) due to biological oxidation of tailings. On the other hand, low-grade ore is challenging the mining industry to commercially produce copper.The main objective of this work was to assess the use of flotation tailings and low-grade ore to produce a biologically-produced copper sulfide, as a product for further pyrometallurgical or fine chemistry processing. Low-grade ore and flotation tailings were first agglomerated at different proportions and leaching tests were performed in 1m columns, using either industrial or synthetic raffinate solution. Then, the PLS solution obtained from the column tests was subjected to selective precipitation of copper by using biogenic hydrogen sulfide (H2S) generated by a mixed culture of neutrophilic sulfate reducing bacteria (SRB), enriched from sediments of Caracarani river (located at 4,600 m over sea level in northern Chile).Over 91% of the copper soluble present in the PLS was recovered as copper sulfide in 28 days, while ferrous iron, other metals and arsenic remained in solution. Analysis performed by XRD confirmed the presence of copper in the precipitate (58% as covellite). This work demonstrates the possibility to apply bioleaching and bio-precipitation technologies to treat tailings and low-grade copper ore to produce a high quality copper sulfide.


2013 ◽  
Vol 868 ◽  
pp. 403-407
Author(s):  
Ci Yun Chen ◽  
Shu Ming Wen ◽  
He Fei Zhao ◽  
Chao Lv ◽  
Yi Jie Wang

Through earliest experimental study to tailings of Yangla copper ore known that under the best conditions of the flotation process can be obtained a copper concentrate which copper grade of 1.43% and recovery was 29.71%. Due to copper minerals embedded in this materials at a very fine particle size, and closely symbiosis with iron content and quartz, lead to it difficult to enrichment through ore dressing methods. And copper minerals mainly exist in the form of sulfide copper mineral, it can not by leaching method for processing directly, thus put forward a process to deal with this materials of enriched concentrate conduct to sulfuric roasting-leaching, which on the premise of guaranteed cost is not high, ultimately achieve the goal of recycling all kinds of valuable elements. Through the test of low temperature sulphation roasting - leaching to the flotation of copper concentrate shows that under the conditions of temperature of 450 °C for copper concentrate roasting 135 minutes, and after the calcine cooling, then with concentration of 4% sulfuric acid and Liquid-solid ratio of 3:1 leaching of 80 minutes, ultimately available to the test targets of copper leaching rate of around 81%.


2014 ◽  
Vol 556-562 ◽  
pp. 193-196
Author(s):  
Zhi Guo Zhang ◽  
Quan Jun Liu ◽  
Jin Cheng Ran

For the characteristic of the high oxidation ratio and the high intergrowth ratio,the copper ore belongs to a kind of refractory ore.It could not get qualified concentrate and high recovery with the traditional flowsheet and general reagent system.In the case of stable grade of copper concentrate,the recovery of copper using composite reagent system could have a reasonably improve,which could reach to 84.49% at the copper concentrate grade of Cu 20.91%.


2012 ◽  
Vol 616-618 ◽  
pp. 649-654
Author(s):  
Qin Bo Cao ◽  
Shu Ming Wen ◽  
Dan Liu ◽  
Hai Ying Shen ◽  
Jiu Shuai Deng ◽  
...  

Improving the recovery of molybdenum is a research hotspot in the bulk flotation of Mo-copper sulphide ore. In this paper, the optimum flotation parameters for a kind of molybdenite ore obtained form Yunnan province, involving the grinding fineness, pulp concentration, dosages of kerosene and butyl xanthate, were determined in order to improve the recovery of Mo in the bulk Mo-copper flotation. In addition, a close-circuit flotation test was also conducted to simulate the practical process. A Mo-copper concentrate with Mo grade of 3.02% and recovery of 93.46% was obtained through the close-circuit flotation test, which satisfy the requirement for the bulk flotation of Mo-copper ore.


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