Effect of pH Value on Nitrogen and Phosphorus Removal in Biochemical Reactor

2013 ◽  
Vol 777 ◽  
pp. 263-267
Author(s):  
Hong Wei Rong ◽  
Meng Xiang Lin ◽  
Ke Fang Zhang ◽  
Chao Sheng Zhang ◽  
Heng Ning Xue ◽  
...  

pH value is one of the most important factors which affect the nitrogen and phosphorus removal in the wastewater treatment process. The influences of potential of hydrogen on nitrogen and phosphorus removal of wastewater were studied in this study. The results revealed that: (1) faintly acidic environment was conducive to biological phosphorus removal in biochemical reactors with FeCl3, PFS and PAS but not with Al2(SO4)3.On the other hand, synergistic effect between the microorganism and coagulants ( FeCl3, PFS, Al2(SO4)3 and PAS) was confirmed in this study. (2) faintly acidic environment was favorable to the nitrogen removal in biochemical reactors with PFS and PAS while the faintly alkaline environment was conducive to the nitrogen removal with FeCl3 and Al2(SO4)3. And there was no synergistic effect between the microorganism and coagulants.

2004 ◽  
Vol 50 (10) ◽  
pp. 163-170 ◽  
Author(s):  
R.J. Zeng ◽  
R. Lemaire ◽  
Z. Yuan ◽  
J. Keller

Simultaneous nitrification and denitrification (SND) via the nitrite pathway and anaerobic–anoxic enhanced biological phosphorus removal (EBPR) are two processes that can significantly reduce the COD demand for nitrogen and phosphorus removal. The combination of these two processes has the potential of achieving simultaneous nitrogen and phosphorus removal with a minimal requirement for COD. A lab-scale sequencing batch reactor (SBR) was operated in alternating anaerobic–aerobic mode with a low dissolved oxygen concentration (DO, 0.5 mg/L) during the aerobic period, and was demonstrated to accomplish nitrification, denitrification and phosphorus removal. Under anaerobic conditions, COD was taken up and converted to polyhydroxyalkanoates (PHA), accompanied with phosphorus release. In the subsequent aerobic stage, PHA was oxidized and phosphorus was taken up to less than 0.5 mg/L at the end of the cycle. Ammonia was also oxidised during the aerobic period, but without accumulation of nitrite or nitrate in the system, indicating the occurrence of simultaneous nitrification and denitrification. However, off-gas analysis found that the final denitrification product was mainly nitrous oxide (N2O) not N2. Further experimental results demonstrated that nitrogen removal was via nitrite, not nitrate. These experiments also showed that denitrifying glycogen-accumulating organisms rather than denitrifying polyphosphate-accumulating organisms were responsible for the denitrification activity.


2007 ◽  
Vol 56 (6) ◽  
pp. 115-124 ◽  
Author(s):  
U. Bracklow ◽  
L. Manigas ◽  
A. Drews ◽  
M. Vocks ◽  
M. Barjenbruch ◽  
...  

For membrane bioreactors (MBR) with enhanced nutrients removal, rather complex recirculation schemes based on the biological requirements are commonly recommended. The aim of this work was to evaluate other recirculation options. For a laboratory scale MBR, four different recirculation schemes were tested. The MBR was operated with COD degradation, nitrification, post-denitrification without carbon dosing and biological phosphorus removal. For all configurations, efficient COD, nitrogen and phosphorus removal could be achieved. There were no big differences in elimination efficiency between the configurations (COD elimination: 96.6–97.9%, nitrogen removal: 89.7–92.1% and phosphorus removal: 97.4–99.4%). Changes in the degradation, release and uptake rates were levelled out by the changes in contact time and biomass distribution. With relatively constant outflow concentrations, different configurations are still interesting with regard to oxygen consumption, simplicity of plant operation or support of certain degradation pathways such as biological phosphorus removal or denitrification.


RSC Advances ◽  
2015 ◽  
Vol 5 (73) ◽  
pp. 59326-59334 ◽  
Author(s):  
A. Chen ◽  
Y. Chen ◽  
C. Ding ◽  
H. Liang ◽  
B. Yang

The presence of 2 and 5 mg L−1of tetracycline decreased total nitrogen removal. Tetracycline induced EPS release and decreased its protective role on cells. Denitrifiers instead of nitrifiers were negatively affected by tetracycline.


1983 ◽  
Vol 15 (3-4) ◽  
pp. 1-13 ◽  
Author(s):  
James L Barnard

This paper briefly summarizes the early work on phosphorus removal in activated sludge plants in the U.S.A. and observed that such removals only occurred in low SRT plants of the plug flow type and in the Phostrip plants, neither designed for full nitrification. The discovery of simultaneous nitrogen and phosphorus removal, as well as full-scale experiments are discussed. The Phoredox process was proposed utilizing internal recycling for the removal of nitrates and an anaerobic first stage in which the incoming feed is used to obtain the necessary anaerobic conditions, essential as a conditioning step for the uptake of phosphorus. Proposed mechanisms are discussed.


2006 ◽  
Vol 53 (3) ◽  
pp. 53-60 ◽  
Author(s):  
Y. Annaka ◽  
Y. Hamamoto ◽  
M. Akatsu ◽  
K. Maruyama ◽  
S. Oota ◽  
...  

To reduce MBR O&M costs, a new MBR process that conducts efficient simultaneous biological nitrogen and phosphorus removal (BNR) was developed. In the development of this process, various approaches were taken, including reduction of power demand, chemical consumption and sludge disposal costs. To address power demand reductions, air supply requirements for membrane cleaning were reduced. The process adopted an improved membrane that requires less air for cleaning than conventional membranes. It also introduced cyclic aeration, which alternately supplies washing air to the two series of membrane units. Adoption of biological phosphorus removal eliminated chemical costs for phosphorus removal and contributed to the reduction of sludge disposal costs. By combining these technologies, compared to conventional MBR processes, an approximately 27% reduction in O&M costs was achieved.


2013 ◽  
Vol 401-403 ◽  
pp. 2084-2087
Author(s):  
Ming Fen Niu ◽  
Si Li ◽  
Hong Jing Jiao ◽  
Jian Wei ◽  
Yuan Yang Sun ◽  
...  

Denitrifying phosphorus removal can be achieved with the same matrix simultaneous nitrogen and phosphorus removal,is a hot topic of abroad study biological wastewater treatment,This is discussed the Influence factors of anoxic tank NO3- load, dissolved oxygen and the volume ratio of aerobic tank and anoxic tank, pH value of wastewater, sludge retention time (SRT), hydraulic retention time (HRT), mixed liquor suspended solids (MLSS) and temperature on denitrifying phosphorus removal, for denitrifying phosphorus removal process simulation, experimental research and practical application provides a reference and basis.


2012 ◽  
Vol 588-589 ◽  
pp. 55-58
Author(s):  
Yong Feng Li ◽  
Jian Yu Yang ◽  
Guo Cai Zhang

Simulate sewage were used in an anaerobic-anoxic-aerobic biological nutrient removal system(A2O process), by observing the pHs in different compartments and its reflected changes in nitrogen and phosphorus removal, studied on the effects of different pHs on the removal of pollutants. The experiments indicates that the anaerobic phosphorus release showed the main performance of the decline of pH, denitrification in anoxic zone caused the rise of pH, uptake of phosphate in the aerobic zone mainly caused the continuous rise of pH. There is no evidently changes in COD removal, ammonia nitrogen get the highest removal as the pH value was between 8.0-8.5, when pH was at 6.5-7.5, the TN have the maximum removal rate, TP can keep in a high level when the pH was above 6.0.


2006 ◽  
Vol 53 (9) ◽  
pp. 169-175 ◽  
Author(s):  
K. Hamada ◽  
T. Kuba ◽  
V. Torrico ◽  
M. Okazaki ◽  
T. Kusuda

A shortage of organic substances (COD) may cause problems for biological nutrient removal, that is, lower influent COD concentration leads to lower nutrient removal rates. Biological phosphorus removal and denitrification are reactions in which COD is indispensable. As for biological simultaneous nitrogen and phosphorus removal systems, a competition problem of COD utilisation between polyphosphate accumulating organisms (PAOs) and non-polyphosphate-accumulating denitrifiers is not avoided. From the viewpoint of effective utilisation of limited influent COD, denitrifying phosphorus-removing organisms (DN-PAOs) can be effective. In this study, DN-PAOs activities in modified UCT (pre-denitrification process) and DEPHANOX (post-denitrification ptocess) wastewater treatments were compared. In conclusion, the post-denitrification systems can use influent COD more effectively and have higher nutrient removal efficiencies than the conventional pre-denitrification systems.


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