Membrane cleaning in membrane distillation of reverse osmosis concentrate generated in landfill leachate treatment

As a thermally induced membrane separation process, membrane distillation (MD) has drawn more and more attention for the advantages of treating hypersaline wastewaters, especially the concentrate from reverse osmosis (RO) process. One of the major obstacles in widespread MD application is the membrane fouling. We investigated the feasibility of direct contact membrane distillation (DCMD) for landfill leachate reverse osmosis concentrate (LFLRO) brine treatment and systematically assessed the efficiency of chemical cleaning for DCMD after processing LFLRO brine. The results showed that 80% water recovery rate was achieved when processing the LFLRO brine by DCMD, but the membrane fouling occurred during the DCMD process, and manifested as the decreasing of permeate flux and the increasing of permeate conductivity. Analysis revealed that the serious flux reduction was primarily caused by the fouling layer that consist of organic matters and inorganic salts. Five cleaning methods were investigated for membrane cleaning, including hydrogen chloride (HCl)-sodium hydroxide (NaOH), ethylene diamine tetraacetic acid (EDTA)-NaOH, critic acid, sodium hypochlorite (NaClO) and sodium dodecyl sulphate (SDS) cleaning. Among the chemical cleaning methods investigated, the 3 wt.% SDS cleaning showed the best efficiency at recovering the performance of fouled membranes.

The Use of NaOH Solutions for Fouling Control in a Membrane Bioreactor: A Feasibility Study

Nowadays, the microbial production of 1,3-propanediol (1,3-PD) is recognized as preferable to the chemical synthesis. However, finding a technological approach allowing the production of 1,3-PD in the membrane bioreactor (MBR) is a great challenge. In the present study, a ceramic ultrafiltration (UF) membrane (8 kDa) for treatment of 1,3-PD broths was used. It has been demonstrated that the membrane used provides the stable permeate flux that is necessary to ensure the stability of the fermentation process in MBR technology. It was noticed that the broth pH has a significant impact on both the final 1,3-PD concentration and permeate flux. Moreover, the feasibility of using NaOH for fouling control in the MBR was evaluated. It has been shown that 1% NaOH solution is effective in restoring the initial membrane performance. To the best of our knowledge, this study is the first to shed light onto the possibility of reducing the amount of the alkaline solutions generated during the MBR operation. Indeed, it has been found that 1% NaOH solution can be successfully used several times for both membrane cleaning and to stabilize the broth pH. Finally, based on the results obtained, the technological conceptions of the MBR technology were designed.

Sequencing Batch Integrated Fixed-Film Activated Sludge Membrane Process for Treatment of Tapioca Processing Wastewater

Tapioca processing industries are very popular in the rural community to produce a variety of foods as the end products. Due to their small scales and scattered locations, they require robust modular systems to operate at low capacity with minimum supervision. This study explores the application of a novel sequencing batch-integrated fixed-film activated sludge membrane (SB-IFASM) process to treat tapioca processing wastewater for reuse purposes. The SB-IFASM employed a gravity-driven system and utilizes biofilm to enhance biodegradation without requiring membrane cleaning. The SB-IFASM utilizes the biofilm as a secondary biodegradation stage to enhance the permeate quality applicable for reuse. A lab-scale SB-IFASM was developed, preliminarily assessed, and used to treat synthetic tapioca processing industry wastewater. The results of short-term filtration tests showed the significant impact of hydrostatic pressure on membrane compaction and instant cake layer formation. Increasing the pressure from 2.2 to 10 kPa lowered the permeability of clean water and activated sludge from 720 to 425 and from 110 to 50 L/m2·h bar, respectively. The unsteady-state operation of the SB-IFASM showed the prominent role of the bio-cake in removing the organics reaching the permeate quality suitable for reuse. High COD removals of 63–98% demonstrated the prominence contribution of the biofilm in enhancing biological performance and ultimate COD removals of >93% make it very attractive for application in small-scale tapioca processing industries. However, the biological ecosystem was unstable, as shown by foaming that deteriorated permeability and was detrimental to the organic removal. Further developments are still required, particularly to address the biological stability and low permeability.

Assessment of Forward Osmosis in PRO Mode during Desalination of a Local Oil Refinery Effluent

In this study, the performance of a forward osmosis system was assessed over a 30-h period during desalination of a local oil refinery effluent using NaCl as the draw solute. The study was conducted with the active layer of the membrane facing the draw solution. Assessment was done based on the water flux, salt rejection (SO42− and CO32−), membrane fouling and fouling reversal after membrane cleaning. Critical to this study was the performance of manual scrubbing of the membrane after each run and the application of chemically enhanced osmotic backwash. Scanning electron microscope (SEM) analysis of the cellulose triacetate (CTA) membrane was conducted before and after cleaning to ascertain the degree of fouling and fouling reversal after membrane cleaning. The results showed an average water flux of 3.78 ± 0.13 L/m2 h, reverse solute flux (RSF) of 1.56 ± 0.11 g/m2·h, SO42− rejection of 100%, CO32− rejection of 95.66 ± 0.32% and flux recovery of 95% after membrane cleaning. This study identifies that intermittent manual scrubbing of the membrane plays a major role in overall membrane performance. It also provides a practical basis for further research and decision making in the use of FO and CTA membranes for oil refinery effluent desalination.