Comparison between Green Liquor Pretreatment-Kraft Pulping and Conventional Kraft Pulping

2013 ◽  
Vol 781-784 ◽  
pp. 2650-2653
Author(s):  
Zhang Hong Xie ◽  
Jing Hui Zhou ◽  
Hai Ming Li ◽  
Guang Wei Sun

This paper studied the differences of pulping performances, beating characteristics and strength properties between green liquor pretreatment-Kraft pulping and conventional Kraft pulping based on previous optimized pulping conditions. The green liquor pretreatment-Kraft pulping has higher yield, lower Kappa number, reduced residual effective alkali and decreased viscosity. Green liquor pretreatment improves pulp strength properties although green liquor pretreatment-Kraft pulp has beating characteristics similar to conventional Kraft pulp.

2018 ◽  
Vol 33 (2) ◽  
pp. 175-185 ◽  
Author(s):  
Gustavo B. de Souza ◽  
Jorge Luiz Colodette ◽  
Fernando José Borges Gomes ◽  
Danila Morais de Carvalho

AbstractThe improvement caused by eucalypt chip impregnation on kraft pulping performance was assessed for terminating the cook at kappa in the range of 15–27 and at controlled residual effective alkali (REA) of 6–8 g/L NaOH. Extended impregnation cooking of eucalypt chips (EIC) increased about 1 %lignin- and HexA-freescreen yield gains in relation to conventional cooking (CC), regardless of kappa number in the range of 15–27. The EIC technology allows for cooking eucalypt wood to kappa number up to 27, without rejects production, but without significant improvement inlignin- and HexA-freescreen yield and with larger chlorine dioxide (ClO2) consume during bleaching. The optimum kappa number for both CC and EIC cooking was about 19 with similar refinability and strength properties for both technologies, CC and EIC. It was concluded that extended impregnation cooking is an attractive technique for enhancing bleached eucalypt Kraft pulp yield.


TAPPI Journal ◽  
2020 ◽  
Vol 19 (3) ◽  
pp. 139-148
Author(s):  
MARYAM SADEGH MOUSAVI ◽  
NIKOLAI DEMARTINI

The accumulation of nonprocess elements in the recovery cycle is a common problem for kraft pulp mills trying to reduce their water closure or to utilize biofuels in their lime kiln. Nonprocess elements such as magne-sium (Mg), manganese (Mn), silicon (Si), aluminum (Al), and phosphorus (P) enter the recovery cycle via wood, make-up chemicals, lime rock, biofuels, and process water. The main purge point for these elements is green liquor dregs and lime mud. If not purged, these elements can cause operational problems for the mill. Phosphorus reacts with calcium oxide (CaO) in the lime during slaking; as a result, part of the lime is unavailable for slaking reactions. The first part of this project, through laboratory work, identified rhenanite (NaCa(PO4)) as the form of P in the lime cycle and showed the negative effect of P on the availability of the lime. The second part of this project involved field studies and performing a mass balance for P at a Canadian kraft pulp mill.


2013 ◽  
Vol 750-752 ◽  
pp. 1520-1523
Author(s):  
Hong Xia Gao ◽  
Wen Hua He ◽  
Xiu Qiong Guan ◽  
Chun Liu ◽  
Bo Yuan

The effect of chelating agents Diethylene Triamine Penta Methylene Phosphonic Acid in bamboo kraft cooking was studied. The results show that the bamboo pulp yield was 49.52% when DTPMPA dosage is 0.4%, at the same time the Kappa number was lower. With the increasing of DTPMPA dosage in bamboo kraft pulping, the bamboo pulp strength was increased.


2012 ◽  
Vol 36 (6) ◽  
pp. 1163-1172 ◽  
Author(s):  
María Graciela Aguayo ◽  
Regis Teixeira Mendonça ◽  
Paulina Martínez ◽  
Jaime Rodríguez ◽  
Miguel Pereira

Tension (TW) and opposite wood (OW) of Eucalyptus globulus trees were analyzed for its chemical characteristics and Kraft pulp production. Lignin content was 16% lower and contained 32% more syringyl units in TW than in OW. The increase in syringyl units favoured the formation of β-O-4 bonds that was also higher in TW than in OW (84% vs. 64%, respectively). The effect of these wood features was evaluated in the production of Kraft pulps from both types of wood. At kappa number 16, Kraft pulps obtained from TW demanded less active alkali in delignification and presented slightly higher or similar pulp yield than pulps made with OW. Fiber length, coarseness and intrinsic viscosity were also higher in tension than in opposite pulps. When pulps where refined to 30°SR, TW pulps needed 18% more revolutions in the PFI mill to achieve the same beating degree than OW pulps. Strength properties (tensile, tear and burst indexes) were slightly higher or similar in tension as compared with opposite wood pulps. After an OD0(EO)D1 bleaching sequence, both pulps achieved up to 89% ISO brightness. Bleached pulps from TW presented higher viscosity and low amount of hexenuronic acids than pulps from OW. Results showed that TW presented high xylans and low lignin content that caused a decrease in alkali consumption, increase pulp strength properties and similar bleaching performance as compared with pulps from OW.


1973 ◽  
Vol 3 (3) ◽  
pp. 359-366 ◽  
Author(s):  
I. E. Bella ◽  
K. Hunt

The unscreened kraft pulp yields at permanganate No. 14 for 7-, 13-, and 22-year-old trembling aspen (Populustremuloides Michx.) trees from Manitoba for effective alkali applications of 14% were 56.2, 55.7, and 54.8% (o.d. wood), respectively. Specific gravity data for green and ovendry wood are presented, but no relationship with tree height could be established. Pulp strength values from the 7-, 13-, and 22-year-old aspen were, respectively, 60, 67, and 65 for tear factor; 67, 71, and 72 for burst factor; and 10.1, 10.4, and 10.7 (km) for breaking length, respectively. These data indicate that trees of any of the three ages will make a kraft pulp comparable in yield and strength to commercial hardwood–softwood pulp.


2013 ◽  
Vol 724-725 ◽  
pp. 399-404
Author(s):  
Jun Ying Zhang ◽  
Jing Hui Zhou ◽  
Hai Ming Li ◽  
Ying Han ◽  
Jun Feng Shi

Green liquor, a process liquor of alkali recovery in pulp and papermaking industry, pretreatment used in poplar kraft pulping process and the influences of pretreatment conditions on pentosan extraction have been studied. The results show that the influence of green liquor dosage on pentosan extraction is the most remarkable, with temperature taking the second place and time the third. Under the conditions of liquor ratio 1:4, green liquor dosage 1.5 L/kg (based on oven dried material), temperature 100 °C, time 90 min, higher pentosan extraction ratio of 13.81% (based on the pentosan content of raw material) is achieved. The wood was pulped under normal KP conditions after pretreated by the optimal pentosan extraction conditions. Comparing two kinds of pulp with and without pretreatment at similar stock yield level, the results show that the former has a little lower viscosity, significantly decreased Kappa number and excellent paper physical properties.


2005 ◽  
Vol 29 (3) ◽  
pp. 489-494 ◽  
Author(s):  
Leonel F. Torres ◽  
Roberto Melo ◽  
Jorge Luiz Colodette

The use of 12-year-old Pinus tecunumanii (Eguiluz e Perry) grown in Colombia was evaluated for bleached kraft pulp production. Kraft pulps of kappa number 30 ± 1 were produced, and oxygen delignified and bleached to 90% ISO with ECF processes. The bleached pulps produced under optimum conditions were evaluated with regard to their strength properties. Pinus tecunumanii wood required low effective alkali charge to reach the desired kappa number and the unbleached pulp showed high oxygen delignification efficiency and bleachability when a OD(EO)DED sequence was used. The bleached pulps presented good physical-mechanical properties, which are comparable to those obtained with more traditional pines such as Pinus taeda and Pinus radiata. The results demonstrate that this tropical pine species is a suitable raw material for bleached kraft pulp production


2021 ◽  
Vol 55 (3-4) ◽  
pp. 255-262
Author(s):  
ARVIND SHARMA ◽  
GUNJAN DHIMAN ◽  
PRITI S. LAL ◽  
RAVI D. GODIYAL ◽  
BIPIN P. THAPLIYAL

"Moringa oleifera (drumstick) wood was evaluated in terms of its chemical composition, morphological features, Kraft pulping behavior, ECF bleaching and mechanical strength properties – important parameters for pulp and paper making – in comparison with Acacia mangium. Moringa oleifera was found to have the following composition: holocellulose 65.5%, lignin 20.5%, pentosan 11.6%, -cellulose 40.5% and extractives content of 5.15%, which made it comparable with the Acacia mangium wood sample. The alkali prehydrolysis of Moringa oleifera was carried out using 2% NaOH at 150 °C. The prehydrolysis liquor (PHL) was found to contain 50.9 mg/kg of calcium, 5140 mg/kg of potassium and 312 mg/kg of iron content. The prehydrolysis step was followed by Kraft pulping in order to obtain chemical grade pulp of kappa number 15-16 under optimized conditions. The Moringa oleifera pulp was bleached using the DEpD bleaching sequence to reach 85% brightness (ISO). The bleached pulp had an average fiber length of 1.21 mm, which was higher than that of Acacia mangium – 0.782 mm. The mechanical strength properties of the unbleached and bleached pulps, such as tear, tensile and burst indices, were also determined to show their suitability for pulp and paper production."


2016 ◽  
Vol 12 (1) ◽  
pp. 29-36
Author(s):  
R. Vargas ◽  
J. R. Sanjuán D. ◽  
J. A. Silva G. ◽  
J. Rivera P. ◽  
F. J. Fuentes T. ◽  
...  

Chips of avocado wood (Persea americana Mill.) were pulped by means of conventional Soda and Kraft pulping processes. The pulps were bleached with an elemental-chlorine-free sequence OD1-Eop-D2, pre-setting reaction conditions for the first chlorine dioxide stage (D1) . The results show that during the chemical pulping process, avocado wood is easier to cook than other hardwoods such as eucalyptus. The avocado pulp also showed a very good bleachability, reaching brightness levels of up to 92% ISO compared to 84% for eucalyptus after the ECF bleaching sequence. The avocado Kraft pulps required more chemical input in the bleaching sequence than the Soda pulps. On the other hand, the physico-mechanical properties of the pulp were not notably reduced by the bleaching process, the Kraft pulp being stronger than the soda pulp. Strength properties of avocado are similar to those of eucalyptus; therefore this raw material constitutes a worthwhile choice for cellulosic fiber supply.


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