Effect of Epoxidized Palm Oil Loading on the Swelling and Mechanical Properties of SBR Vulcanizates

2013 ◽  
Vol 812 ◽  
pp. 236-240
Author(s):  
Mohd Zaki Nurul Ayunie ◽  
Ahmad Zafir Romli ◽  
M.A. Wahab ◽  
Mohd Hanafiah Abidin
Keyword(s):  
Tensile Strength ◽  
Carbon Black ◽  
Palm Oil ◽  
Crosslink Density ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Epoxidized Palm Oil ◽  
Opposite Trend ◽  
Styrene Butadiene

The effects of epoxidized palm oil (EPO) content in carbon black filled styrene butadiene rubber (SBR) on tensile strength, elongation at break and crosslink density were investigated. Five different loadings of EPO in parts per hundred rubbers (phr) were used to test the tensile strength of the carbon black filled SBR which showed a decreasing trend as the content of EPO in the vulcanizates increased. In contrast, elongation at break showed the opposite trend where the elongation at break increased as the content of the EPO increased. The SBR vulcanizates with the highest content of EPO gave the highest value of elongation at break which is 2393.56%. In the case of swelling index, it was found to increase as the amount of EPO increased.

Effect of Epoxidized Palm Oil (EPO) on Tensile Properties and Density of Rubber Compounding

2013 ◽  
Vol 812 ◽  
pp. 216-220 ◽  
Author(s):  
Mohd Nasir Anis Nazurah ◽  
Ahmad Zafir Romli ◽  
M.A. Wahab ◽  
Mohd Hanafiah Abidin
Keyword(s):  
Tensile Strength ◽  
Palm Oil ◽  
Abrasion Resistance ◽  
Renewable Resource ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Synthetic Rubber ◽  
Epoxidized Palm Oil ◽  
Styrene Butadiene

Epoxidized palm oil (EPO) can act as processing oil has the potential of non toxic, degradable, renewable resource and as the alternative safe process oils in rubber compounding. Epoxidized palm oil is used as some of additives in rubber compounding to provide function of softener or stabiliser thus, improve properties of rubber compounding performance. Rubber that is used in this study is styrene butadiene rubber (SBR); a synthetic rubber copolymer consisting of styrene and butadiene. SBR also has good abrasion resistance and good aging stability when protected by additives. Compared to natural rubber, SBR has better processability, heat aging and abrasion resistance but inferior elongation, hot tear strength, hysteresis, resilience and tensile strength. This study is focusing on the effect of EPO without the addition of carbon black into the compound via tensile and density test. This is very important as to study the physical and mechanical interaction between SBR and EPO without the influence of other fillers. Different loading of oil were used at 25 pphr, 30 pphr. 35 pphr, 40 pphr and 45 pphr in the compounding process as processing aid. EPO35 which contain 35 pphr of EPO shows the highest value of tensile strength which is 2.2 MPa. The vulcanizate that contain 30 pphr of EPO shows the highest value for Youngs modulus which is 0.22 MPa while the elongation at break increased as the oil loading increased. The highest value for density is 0.979 g/cm3 for the vulcanizate contain 25 pphr of EPO. The results indicates that EPO is potential to replace other processing oils as renewable resource and safe to human.

scholarly journals Effects of alkanolamide addition on cure characteristics, crosslink density and tensile properties of carbon-black-filled styrene-butadiene rubber compounds

2018 ◽  
Vol 197 ◽  
pp. 12006 ◽  
Author(s):  
Indra Surya ◽  
Hanafi Ismail
Keyword(s):  
Tensile Strength ◽  
Carbon Black ◽  
Tensile Properties ◽  
Crosslink Density ◽  
Density Measurement ◽  
Tensile Modulus ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Cure Characteristics ◽  
Styrene Butadiene

By using a semi-efficient sulphur vulcanisation system, the effects of alkanolamide (ALK) addition on cure characteristics, crosslink density and tensile properties of carbon black (CB)-filled styrene-butadiene rubber (SBR) compounds were investigated. The ALK was prepared from Refined Bleached Deodorized Palm Stearin and diethanolamine and added into the CB-filled SBR compounds. The ALK loadings were 1.0, 3.0, 5.0 and 7.0 phr. It was found that ALK decreased the scorch and cure times of the CB-filled SBR compounds. ALK also improved the tensile modulus and tensile strength; especially up to a 5.0 phr of loading. The crosslink density measurement proved that the 5.0 phr of ALK exhibited the highest degree of crosslink density which caused the highest in tensile modulus and tensile strength. Due to its plasticity effect, ALK increased the elongation at break of the CB-filled SBR vulcanisates.

Influence of Novel Electron Beam Modified Surface Treated Dual Phase Filler on Rheometric and Mechanical Properties of Styrene Butadiene Rubber Vulcanizates

2003 ◽  
Vol 76 (2) ◽  
pp. 299-317 ◽  
Author(s):  
A. M. Shanmugharaj ◽  
Anil K. Bhowmick
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Electron Beam ◽  
Styrene Butadiene Rubber ◽  
Dual Phase ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Polymer Filler ◽  
Modified Surface ◽  
Styrene Butadiene

Abstract Rheometric and mechanical properties, hysteresis and swelling behavior of the Styrene-Butadiene Rubber vulcanizates (SBR) filled with unmodified and novel electron beam modified surface treated dual phase fillers were investigated. Scorch time increases for these modified filler loaded vulcanizates due to introduction of quinone type oxygen on the surface. Electron beam modification of dual phase filler in the absence of trimethylol propanetriacrylate (TMPTA) or triethoxysilylpropyltetrasulphide (Si-69) significantly improves the modulus of the SBR vulcanizates, whereas the values of tensile strength and elongation at break drop. However, presence of TMPTA or silane slightly increases the modulus with significant improvement in tensile strength. This effect is more pronounced at higher loading of these modified fillers in SBR vulcanizates. These variations in modulus and tensile strength are explained by the equilibrium swelling data, Kraus plot and a new mathematical model interpreting the polymer-filler interaction. Hysteresis loss ratio of SBR vulcanizates loaded with irradiated fillers in absence and presence of TMPTA or silane increases due to highly aggregated structure of the filler.

The Vulcanization of Styrene-Butadiene Rubber with 2-Pentadecyl-Benzoquinone Dioxime

1979 ◽  
Vol 52 (2) ◽  
pp. 353-360 ◽  
Author(s):  
N. D. Ghatge ◽  
N. N. Maldar
Keyword(s):  
Tensile Strength ◽  
Raw Material ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Red Lead ◽  
Styrene Butadiene ◽  
Resistance To Heat ◽  
Curing Systems ◽  
Sulfur Curing

Abstract The authors propose a new active vulcanizing agent 2-pentadecylbenzo-quinone dioxime, derivable from the indigenous raw material, cashewnutshell liquid. This vulcanizing agent, when oxidized by red lead, gives styrene-butadiene vulcanizates of improved tensile strength and elongation at break, compared to vulcanizates cured by p-benzoquinone dioxime, 2-methylbenzo-quinone dioxime or standard sulfur curing systems. The new vulcanizates have much greater resistance to heat aging than the corresponding sulfur vulcanisates.

Characterization of Natural Rubber (NR), Polybutadiene Rubber (BR) and Styrene-Butadiene Rubber (SBR) Blends Cured in a Vulcanization System

2021 ◽  
Vol 1039 ◽  
pp. 51-64
Author(s):  
Muhsin Jaber Jweeg ◽  
Zaid G.A. Al-Jlaihawi
Keyword(s):  
Tensile Strength ◽  
Carbon Black ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Maximum Value ◽  
Polybutadiene Rubber ◽  
Maximum Tensile Strain ◽  
Number Of Cycles ◽  
Styrene Butadiene

In this work, the mechanical properties of three types of dough rubber NR, NR/BR, and NR/SBR have been investigated using five percentages of materials fill (30, 40, 50, 60, and 70) pphr. Carbon black was used as a filler material. The tensile test was achieved with 300% elongation and strain rates of (100, 200, 300, 400, and 500) mm/min. The tensile strength results indicate that the maximum value of tensile strength for NR Dough carbon black 60 pphr reaches 23.2 MPa; the maximum tensile strain of NR dough (carbon black 50 pphr) reaches 805.5%, and the modulus of elasticity with carbon black 70 pphr reaches 4.3 MPa. It was found that the compression strength decreases with increasing the carbon black, and the maximum value of compression set at NR dough (carbon black 30 pphr) reaches 29.3%. Fatigue crack growth was achieved according to ASTM D 813 for rubber testing. The minimum value of fatigue strength dough (carbon black 70 pphr) reaches 68 (IRHD). For NR dough (carbon black 30,40,50 pphr) reaches 3.5 mm at the number of cycles 15000 cycle. Finally, the maximum hardness of NR.

Mechanical and Vulcanization Behaviors of SBR/N330 and SBR/N330/PBMCN Nanocomposites

2011 ◽  
Vol 230-232 ◽  
pp. 103-106
Author(s):  
Hai Tao Liu ◽  
Jing Feng Zhang ◽  
Yi Guang Tian ◽  
Xue Jun Weng ◽  
Shi E Lin
Keyword(s):  
Tensile Strength ◽  
Electron Microscope ◽  
Mass Fraction ◽  
Partial Replacement ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Melt Mixing ◽  
Elongation At Break ◽  
Styrene Butadiene ◽  
Scanning Electron

Mechanical and vulcanization behaviors of styrene-butadiene rubber(SBR)/N330 and SBR/N330/PBMCN nanocomposites were investigated via partial replacement of SBR with pyrophyllite based modified composite nanopowder(PBMCN), which were prepared by melt mixing procedure. Results show a fairly good dispersion of PBMCN in the SBR/N330/PBMCN composites characterized by field-emission scanning electron microscope (FESEM). Mechanical and vulcanization behaviors of the as-abtained pruducts were measured according to GB/T 528-2009 and GB/T 16584-1996, respectively. Near properties in tensile strength, elongation at break and vulcanization behaviors were observed in SBR/N330/PBMCN nanocomposites when SBR was partially replaced by PBMCN for 8% mass fraction. A possible reinforcement mechanism of PBMCN to SBR/N330/PBMCN nanocomposites is also dicussed based on the experiment.

Effects of Carbon Nanotube on Tensile and Dynamic Mechanical Properties of NR/SBR and NR/XSBR Nanocomposites Prepared by Latex Compounding

2012 ◽  
Vol 488-489 ◽  
pp. 612-616 ◽  
Author(s):  
Anyaporn Boonmahitthisud ◽  
Saowaroj Chuayjuljit
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Carbon Nanotube ◽  
Storage Modulus ◽  
Dynamic Mechanical Properties ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Styrene Butadiene ◽  
Latex Compounding

In this study, natural rubber/styrene butadiene rubber (NR/SBR) and NR/carboxylated styrene butadiene rubber (NR/XSBR) nanocomposites with carbon nanotube (CNT) were prepared by a latex compounding method. The dry weight ratio of either NR/SBR or NR/XSBR was fixed to 80/20 and the CNT loading in each blend was varied from 0.1 to 0.4 phr. The nanocomposite latices were cast into sheets on a glass mold and then cured at 80°C for 3 h. The tensile properties (tensile strength, modulus at 300% strain, elongation at break) and dynamic mechanical properties (storage modulus, loss tangent) of the vulcanizates were then evaluated. The results showed that the addition of CNT at a very loading could enhance the tensile strength, modulus at 300% strain and storage modulus of these two rubber bends in a dose dependent manner, except that the tensile strength peaked at an optimum filler level, declining at higher filler loadings, whilst the elongation at break deteriorated. Moreover, the tensile strength and modulus at 300% strain of the NR/XSBR nanocomposites appeared to be higher than those of the NR/SBR nanocomposites at the same CNT loadings.

The Influence of Zinc Dimethacrylate on Crosslink Density, Physical Properties and Heat Aging Resistance of Sulfur Vulcanized Styrene Butadiene Rubber

2013 ◽  
Vol 844 ◽  
pp. 45-48
Author(s):  
Weerawut Naebpetch ◽  
Banja Junhasavasdikul ◽  
Anuwat Saetung ◽  
Tulyapong Tulyapitak ◽  
Nattapong Nithi-Uthai
Keyword(s):  
Physical Properties ◽  
Crosslink Density ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Cure Rate ◽  
Elongation At Break ◽  
Roll Mill ◽  
Aging Resistance ◽  
Equilibrium Swelling ◽  
Styrene Butadiene

In this work, to study the utilization of zinc dimethacrylate (ZDMA) in sulfur vulcanized styrene butadiene rubber (SBR). The compounds were prepared by two roll mill mixer. Crosslink density and crosslink types were determined with an equilibrium swelling method. Physical properties and heat aging resistance were studied. The results shows that increase of ZDMA will decrease cure rate index and crosslink density which lead to decreased in 300% modulus and hardness. However, the addition of ZDMA can improve tensile strength, tear strength, elongation at break and heat aging resistance.

Effect of Epoxidized Palm Oils Loading on the Crosslink Density and Rebound Resilience Characteristic of SBR Vulcanizates

2013 ◽  
Vol 748 ◽  
pp. 206-210
Author(s):  
Mohd Zaki Nurul Ayunie ◽  
A.Z. Romli ◽  
M.A. Wahab ◽  
M.H. Abidin
Keyword(s):  
Carbon Black ◽  
Crosslink Density ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Swelling Behaviour ◽  
The Past ◽  
Natural Oils ◽  
Sunflower Oils ◽  
Styrene Butadiene ◽  
Processing Aids

The study about natural oils as processing aids in rubber was reported by several researchers for the past few years. The natural oils like rice bran oils, soybean oils, sunflower oils, vegetables oils and palm oils can be used as processing oils in rubber compounding [1-3]. These natural oils have been reported to have certain advantages compared to the petroleum based processing oils. In this study the potential of epoxidized palm oils (EPO) as additive and processing oils in carbon black filled styrene butadiene rubber was investigated. The main ingredients used were butadiene rubber (SBR), epoxidized palm oil (EPO) and carbon black. The vulcanized SBR rubber is then undergo several testing like swelling test, hardness and rebound resilience. An attempt was made to see whether the amount of EPO added to the SBR vulcanizates will affect the rebound resilience and swelling behaviour of the SBR vulcanizates. From this study, it was found that the compound contained higher EPO content tend to have lower rebound resilience, similar trend can be observed for hardness properties. While the crosslink density of the vulcanizates is decrease as the EPO content increases.

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