Influence of Novel Electron Beam Modified Surface Treated Dual Phase Filler on Rheometric and Mechanical Properties of Styrene Butadiene Rubber Vulcanizates

2003 ◽  
Vol 76 (2) ◽  
pp. 299-317 ◽  
Author(s):  
A. M. Shanmugharaj ◽  
Anil K. Bhowmick
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Electron Beam ◽  
Styrene Butadiene Rubber ◽  
Dual Phase ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Polymer Filler ◽  
Modified Surface ◽  
Styrene Butadiene

Abstract Rheometric and mechanical properties, hysteresis and swelling behavior of the Styrene-Butadiene Rubber vulcanizates (SBR) filled with unmodified and novel electron beam modified surface treated dual phase fillers were investigated. Scorch time increases for these modified filler loaded vulcanizates due to introduction of quinone type oxygen on the surface. Electron beam modification of dual phase filler in the absence of trimethylol propanetriacrylate (TMPTA) or triethoxysilylpropyltetrasulphide (Si-69) significantly improves the modulus of the SBR vulcanizates, whereas the values of tensile strength and elongation at break drop. However, presence of TMPTA or silane slightly increases the modulus with significant improvement in tensile strength. This effect is more pronounced at higher loading of these modified fillers in SBR vulcanizates. These variations in modulus and tensile strength are explained by the equilibrium swelling data, Kraus plot and a new mathematical model interpreting the polymer-filler interaction. Hysteresis loss ratio of SBR vulcanizates loaded with irradiated fillers in absence and presence of TMPTA or silane increases due to highly aggregated structure of the filler.

Effects of Carbon Nanotube on Tensile and Dynamic Mechanical Properties of NR/SBR and NR/XSBR Nanocomposites Prepared by Latex Compounding

2012 ◽  
Vol 488-489 ◽  
pp. 612-616 ◽  
Author(s):  
Anyaporn Boonmahitthisud ◽  
Saowaroj Chuayjuljit
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Carbon Nanotube ◽  
Storage Modulus ◽  
Dynamic Mechanical Properties ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Styrene Butadiene ◽  
Latex Compounding

In this study, natural rubber/styrene butadiene rubber (NR/SBR) and NR/carboxylated styrene butadiene rubber (NR/XSBR) nanocomposites with carbon nanotube (CNT) were prepared by a latex compounding method. The dry weight ratio of either NR/SBR or NR/XSBR was fixed to 80/20 and the CNT loading in each blend was varied from 0.1 to 0.4 phr. The nanocomposite latices were cast into sheets on a glass mold and then cured at 80°C for 3 h. The tensile properties (tensile strength, modulus at 300% strain, elongation at break) and dynamic mechanical properties (storage modulus, loss tangent) of the vulcanizates were then evaluated. The results showed that the addition of CNT at a very loading could enhance the tensile strength, modulus at 300% strain and storage modulus of these two rubber bends in a dose dependent manner, except that the tensile strength peaked at an optimum filler level, declining at higher filler loadings, whilst the elongation at break deteriorated. Moreover, the tensile strength and modulus at 300% strain of the NR/XSBR nanocomposites appeared to be higher than those of the NR/SBR nanocomposites at the same CNT loadings.

scholarly journals Short Nylon Fibers Waste Modified with Glycidyl 3-Pentadecenyl Phenyl Ether to Reinforce Styrene Butadiene Rubber Tread Compounds

2019 ◽  
Vol 2019 ◽  
pp. 1-10
Author(s):  
Lan Cen ◽  
Guo-zheng Lv ◽  
Xin-wen Tan ◽  
Zhan-lin Gong
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Phenyl Ether ◽  
Styrene Butadiene Rubber ◽  
Wear Volume ◽  
Butadiene Rubber ◽  
Environmental Benefit ◽  
Elongation At Break ◽  
Tear Strength ◽  
Styrene Butadiene

The utilization of waste fibers represents an important environmental benefit and great economic savings for the community. In this study short nylon fibers waste was modified with Glycidyl 3-Pentadecenyl Phenyl Ether (GPPE) in the presence of Triethylamine/Ammonium persulfate by a simple two-step procedure. The reinforcing effects of modified fibers (MNSF-2) on the vulcanization characteristics, mechanical properties, dynamic mechanical properties, and the wear resistant property of Styrene Butadiene Rubber (SBR) tread compounds were investigated. The addition of the MNSF-2 resulted in slightly lower minimum torque (ML) and maximum torque (MH), as well as longer cure time (t90) and scorch time (t10) of tread compounds. The deterioration of tensile strength and elongation at break of the tread compound containing short nylon fibers waste (NSF) was apparent. Conversely, the modified fibers showed reinforcing effect on tread compounds. The tensile strength values of compounds increased with MNSF-2 content, passed through a maximum value, and then reduced slightly. The modulus and the tear strength of compounds increased significantly with fiber loadings. The highest tear strength value was observed in 8phr MNSF-2 reinforced SBR compounds, 31.9% higher than that of the gum compound. Meanwhile elongation at break of MNSF-2 compound maintained a relative high value than that of NSF/SBR compound. The addition of NSF exaggerated wear volume of compounds. However, the wear resistance of MNSF-2 compounds was superior to that of NSF compounds and comparable with that of the gum compound. The DMA results reveal that E′ and tan⁡δ values decreased at elevated temperature. Meanwhile enhanced storage modulus in MNSF-2/SBR tread compound can be observed. It is worth highlighting that MNSF-2/SBR compounds show higher tan⁡δ at 0°C, indicating improved wet traction of tread compounds, while tan⁡δ at 60°C maintains almost the same value as that of the gum sample. The results of this study are encouraging, demonstrating that the use of short nylon fibers waste in composites offers promising potential for the green tire application.

The Mechanical Properties of Modified Attapulgite Reinforced Nature Rubber and Styrene-Butadiene Rubber Nanocomposites

2010 ◽  
Vol 150-151 ◽  
pp. 762-765
Author(s):  
Ji Hu Wang ◽  
Hong Bo Liu ◽  
Shao Guo Wen ◽  
Yan Shen
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Natural Rubber ◽  
Coupling Agent ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
The Matrix ◽  
Modified Attapulgite ◽  
Rubber Nanocomposites ◽  
Styrene Butadiene

Attapulgite (AT)/natural rubber (NR)/ styrene-butadiene rubber (SBR) nanocomposites have been prepared after attapulgite was modified by different coupling agent. The treatment of AT caused the adhesion between AT nanorods and the nature rubber/styrene-butadiene rubber was improved, which enhanced the tensile properties of the matrix. The tensile strength of composites attained 15.6 MPa after AT was modified by 3%wt Si-69 coupling with addition of 20 phr.

Effect of Epoxidized Palm Oil Loading on the Swelling and Mechanical Properties of SBR Vulcanizates

2013 ◽  
Vol 812 ◽  
pp. 236-240
Author(s):  
Mohd Zaki Nurul Ayunie ◽  
Ahmad Zafir Romli ◽  
M.A. Wahab ◽  
Mohd Hanafiah Abidin
Keyword(s):  
Tensile Strength ◽  
Carbon Black ◽  
Palm Oil ◽  
Crosslink Density ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Epoxidized Palm Oil ◽  
Opposite Trend ◽  
Styrene Butadiene

The effects of epoxidized palm oil (EPO) content in carbon black filled styrene butadiene rubber (SBR) on tensile strength, elongation at break and crosslink density were investigated. Five different loadings of EPO in parts per hundred rubbers (phr) were used to test the tensile strength of the carbon black filled SBR which showed a decreasing trend as the content of EPO in the vulcanizates increased. In contrast, elongation at break showed the opposite trend where the elongation at break increased as the content of the EPO increased. The SBR vulcanizates with the highest content of EPO gave the highest value of elongation at break which is 2393.56%. In the case of swelling index, it was found to increase as the amount of EPO increased.

scholarly journals Mechanical Properties of Water Purification Industry Used Natural Rubber/Styrene-Butadiene Rubber Blends that Prepared Via Different Sulfur Curing Systems

2020 ◽  
Author(s):  
Wenfa Dong ◽  
Ruogu Tang
Keyword(s):  
Mechanical Properties ◽  
Relative Volume ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Water Industry ◽  
High Modulus ◽  
Elongation At Break ◽  
Tear Strength ◽  
Rubber Blends ◽  
Styrene Butadiene

<div>The water industry used NR was selected for blending with SBR. A series of NR/SBR vulcanizates were prepared through three different vulcanization systems, conventional vulcanization (CV), effective vulcanization (EV) and semi-effective vulcanization (SEV) respectively, basing on each formulation and optimum curing time. We examined the mechanical properties of NR/SBR vulcanizates including tensile strength, tear strength, elongation at break, modulus, Shore A hardnessand and relative volume abrasion. The results indicated that NR/SBR vulcanizates prepared in different systems differed in mechanical properties. Vulcanizates prepared via CV showed higher tensile and tear strength; vulcanizates prepared via EV had high modulus and hardness, and vulcanizates prepared via SEV performed high abrasion resistance. </div>

scholarly journals Improvement The Mechanical Properties of Styrene Butadiene Rubber By Using Silica Fume

2017 ◽  
Vol 2 (12) ◽  
pp. 31
Author(s):  
Ali Abed Salman
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Flexural Strength ◽  
Silica Fume ◽  
Polymeric Materials ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Materials Used ◽  
Styrene Butadiene

Styrene butadiene rubber (SBR) is considered to be one of the greatest important polymeric materials used as a bond, so we discussed in this study to improve its properties .This study covers the effect of silica fume on mechanical properties of styrene butadiene rubber reinforced with silica fume. The composites were prepared with (1 to 3 wt. %) of silica fume particles .The results had indicated  that the tensile strength and flexural strength are improved by (11.6% and 13.5%) respectively at 2 wt% and the hardness is  improved by (9.3%) at 3wt%.

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