The Complexation of Calix[6]Arene Sulfoxide Derivative with Uranium

2013 ◽  
Vol 842 ◽  
pp. 170-174
Author(s):  
Yin An Pi ◽  
Jing Song Wang ◽  
Qing Wei Guo ◽  
Hui Yan Mo ◽  
Yong Feng Xia ◽  
...  
Keyword(s):  
Ir Spectra ◽  
Potential Application ◽  
Extraction Efficiency ◽  
Carbon Chain ◽  
Uv Spectra ◽  
Uranium Extraction ◽  
Job's Method ◽  
Extraction Agent ◽  
Sulfoxide Group

Calix[6]arene carbon chain alkyl sulfoxide derivative have been successfully synthesized. IR spectra confirmed the introduction of sulfoxide group on calix[6]arene. UV spectra indicated that calix[6]arene sulfoxide derivative has a high complexation of uranium. The coordination ratio between the calix[6]arene sulfoxide derivative with uranium is 3:2, which was determined by Job’s method. Extraction experiments showed that the extraction efficiency of uranium is able to achieve 73.8%, which suggested the potential application of calix[6]arene sulfoxide derivative as an excellent uranium extraction agent.

Preparation and Research of Polymolybdate/Polymer Composite Membrane by Electrospinning and its Photo-Catalytic Property

2013 ◽  
Vol 395-396 ◽  
pp. 415-418
Author(s):  
Zhi Ming Zhang ◽  
Ting Ting Li ◽  
Ce Liu
Keyword(s):  
Hydrogen Bond ◽  
Ir Spectra ◽  
Composite Membrane ◽  
Phosphomolybdic Acid ◽  
Uv Spectra ◽  
Polarizing Microscopy ◽  
Optimum Parameters ◽  
Anhydrous Alcohol ◽  
Cellulosic Membrane ◽  
Strong Absorption Peak

Composite cellulosic membrane of PMMA and phosphomolybdic acid was prepared by electrospinning. During the progress, the factor of electrospinning and the optimum parameters was found out within the orthogonal combination experiment program. Then the morphology of the composite cellulosic membrane was observed by polarizing microscopy. To resolve PMMA, DMF and anhydrous alcohol were used. When their ratios were 1:1, the diameter of the fibre was the most homogeneous. During the electrospinning, the concentration of PMMA was the most important factor. When the concentrations were less then 10%, there were hardly fibres on the foil. The diameter of the fibre ranged from 0.5 to 1.2 μm along with the increment of the concentration of PMMA. The addition of phosphomolybdic acid made the diameter of the fibre decrease. IR-spectra showed that phosphomolybdic acid kept its Keggin structure, and it interacted with PMMA through hydrogen bond. The composite cellulosic membrane changed its color when imposed in bright space. UV spectra represented that the composite cellulosic membrane had a strong absorption peak at 700nm.

Spectral Investigations of the Effects of 60Co-Gamma Irradiation on Iodothyronine and Iodotyrosines

1987 ◽  
Vol 41 (1) ◽  
pp. 74-79
Author(s):  
A. Obaid ◽  
S. Basahl ◽  
A. Diefallah ◽  
R. Abu-Eittah
Keyword(s):  
Ir Spectra ◽  
Gamma Irradiation ◽  
Uv Spectra ◽  
Uv And Ir Spectra ◽  
60Co Gamma ◽  
Carbonyl Absorption

Solids of 3-iodo-, 3–5–di-iodotyrosine and 3,5-di-iodothyronine were irradiated by 60Co-gamma irradiation for a period of about twenty hours. The effects of irradiation were investigated through a study of the UV and IR spectra of irradiated samples. UV spectra showed the presence of a new band at 360 nm which was assigned to the formation of IO−. IR spectra showed a strong carbonyl absorption and the removal of the carboxylate band in the case of thyronine only. For comparison, the spectra of the studied compounds were investigated before irradiation.

Synthesis and Dye Degradation Properties of Cu2+ Complexes with Benzimidazole Derivatives

2013 ◽  
Vol 726-731 ◽  
pp. 2449-2452 ◽  
Author(s):  
Yin Zhi Jiang ◽  
Yong Qiang Shi ◽  
Lian Zhu Tian ◽  
Huo Ying Xu
Keyword(s):  
Methyl Orange ◽  
Ir Spectra ◽  
Dye Degradation ◽  
Degradation Products ◽  
Hplc Method ◽  
Uv Spectra ◽  
Benzimidazole Derivatives ◽  
Coordination Sites ◽  
Degradation Properties ◽  
Degradation Of Methyl Orange

Six benzimidazole derivatives were synthesized and charactrized by IR spectra, 1H-NMR spectra and MS spectra. The coordination reaction of the derivatives with CuCl2. And six novel Cu (II) complexes with the derivatives were prepared and characterized by UV spectra, IR spectra and elemental analysis. The catalytic degradation of methyl orange aqueous solution was investigated using the complexes as catalysis in presence H2O2 by HPLC method and Vis-spectrophotometry. The result of characterization showed that there are four coordination sites around Cu (II) in all complexes, which are respectively occupied by one sulfur atom (from the derivative), one nitrogen atom (from the derivative), one oxygen atom ( from the OH-) and one chlor atom (from the Cl-). The degradation of methyl orange indicated that all the complexes show the properties of enzyme activity. And the main degradation products determined were hydroquinone and maleic acid.

Spectral manifestations of strong hydrogen bonds in seven-membered rings of pyrazolecarboxylic acid derivatives

1979 ◽  
Vol 44 (3) ◽  
pp. 781-787 ◽  
Author(s):  
Emil Svátek ◽  
Viktor Zikán ◽  
Miroslav Semonský
Keyword(s):  
Hydrogen Bonds ◽  
Ir Spectra ◽  
Frequency Shift ◽  
Bond Order ◽  
Electronic System ◽  
Uv Spectra ◽  
Carboxyl Group ◽  
Opinion Formation ◽  
Frequency Shifts ◽  
Resonance Stabilization

Strong downward frequency shifts of ν(C=O) of benzoyl or carboxyl group have been found in IR spectra of some pyrazolecarboxylic acid derivatives, and bathochromic shifts of maximum of the first band of π-π* transition have been found in their UV spectra, which can be explained by the presence of strong hydrogen bonds in seven-membered rings. Considerable frequency shift of ν(C=O) indicates lowering of order of this bond which is comparable with the bond order lowering of C=O group in six-membered conjugated chelates of the type of enolized β-diketones. In our opinion, formation of strong hydrogen bonds in seven-membered rings in pyrazolecarboxylic acids is due to the presence of the adjoining five-membered aromatic ring, which enables resonance stabilization of the whole π-electronic system in a pseudo-azulene structure.

Interconversion of Nitrenes, Carbenes, and Nitrile Ylides by Ring Expansion, Ring Opening, Ring Contraction, and Ring Closure: 3-Quinolylnitrene, 2-Quinoxalylcarbene, and 3-Quinolylcarbene

2009 ◽  
Vol 62 (3) ◽  
pp. 275 ◽  
Author(s):  
David Kvaskoff ◽  
Ullrich Mitschke ◽  
Chris Addicott ◽  
Justin Finnerty ◽  
Pawel Bednarek ◽  
...  
Keyword(s):  
Ir Spectra ◽  
Ring Opening ◽  
Density Functional ◽  
Diazo Compound ◽  
Density Functional Theory Calculations ◽  
Ring Expansion ◽  
Uv Spectra ◽  
Ring Closure ◽  
High Yield ◽  
Uv And Ir Spectra

Photolysis of 3-azidoquinoline 6 in an Ar matrix generates 3-quinolylnitrene 7, which is characterized by its electron spin resonance (ESR), UV, and IR spectra in Ar matrices. Nitrene 7 undergoes ring opening to a nitrile ylide 19, also characterized by its UV and IR spectra. A subsequent 1,7-hydrogen shift in the ylide 19 affords 3-(2-isocyanophenyl)ketenimine 20. Matrix photolysis of 1,2,3-triazolo[1,5-c]quinoxaline 26 generates 4-diazomethylquinazoline 27, followed by 4-quinazolylcarbene 28, which is characterized by ESR and IR spectroscopy. Further photolysis of carbene 28 slowly generates ketenimine 20, thus suggesting that ylide 19 is formed initially. Flash vacuum thermolysis (FVT) of both 6 and 26 affords 3-cyanoindole 22 in high yield, thereby indicating that carbene 28 and nitrene 7 enter the same energy surface. Matrix photolysis of 3-quinolyldiazomethane 30 generates 3-quinolylcarbene 31, which on photolysis at >500 nm reacts with N2 to regenerate diazo compound 30. Photolysis of 30 in the presence of CO generates a ketene (34). 3-Quinolylcarbene 31 cyclizes on photolysis at >500 nm to 5-aza-2,3-benzobicyclo[4.1.0]hepta-2,4,7-triene 32. Both 31 and 32 are characterized by their IR and UV spectra. FVT of 30 yields a mixture of 2- and 3-cyanoindenes via a carbene–carbene–nitrene rearrangement 31 → 2-quinolylcarbene 39 → 1-naphthylnitrene 43. The reaction mechanisms are supported by density functional theory calculations of the energies and spectra of all relevant ground and transition state structures at the B3LYP/6–31G* level.

A selective uranium extraction agent prepared by polymer imprinting

2000 ◽  
pp. 273-274 ◽  
Author(s):  
Gregory D. Saunders ◽  
Simon P. Foxon ◽  
Paul H. Walton ◽  
Malcolm J. Joyce ◽  
Simon N. Port
Keyword(s):  
Uranium Extraction ◽  
Extraction Agent

scholarly journals USE OF MEMBRANE EMULSION SPAN 80 AND TOPO IN URANIUM EXTRACTION AND STRIPPING

2017 ◽  
Vol 22 (3) ◽  
Author(s):  
Kris Tri Basuki ◽  
Nurimaniwathy Nurimaniwathy ◽  
Dian Puspita ◽  
Bambang E H.B
Keyword(s):  
Aqueous Phase ◽  
Extraction Efficiency ◽  
Influence Factors ◽  
Membrane System ◽  
Total Efficiency ◽  
Phase 3 ◽  
Uranium Extraction ◽  
Span 80 ◽  
Stripping Efficiency ◽  
Feed Volume

USE OF MEMBRANE EMULSION SPAN 80 AND TOPO IN URANIUM EXTRACTION AND STRIPPING. Membrane emulsion span 80 and TOPO used in uranium extraction and stripping has been done. The extraction was carried outby emulsion membrane H3PO4 in TOPO-Kerosene. The feed or external aqueous phase was uranium in  HNO3. The emulgator span-80 was used to obtain a stable emulsion membrane system. The influence factors were percentage of TOPO-Kerosene, time extraction,  molarity of external aqueous phase and  molarity of internal aqueous. After the emulsion membrane was formed, the extractionand stripping process was performed. The ratio volume feed : volume membrane phase equal to 1 : 1 and volume of 5 % TOPO-Kerosene : Volume 3 M H3PO4 equal 1 : 1 were used. The relative good yield were obtained at concentration of TOPO in Kerosene and 3 M H3PO4 was 5 %, molarity of internal aqueous phase equal to 1 M, molarity of external aqueous phase 3 M H3PO4 and time extraction equalto 10 minutes with the speed of emulsification was 8000 rpm. At this condition the extraction efficiency of uranium obtained was 97.8 %, the stripping efficiency 52.56 %, and the total efficiency was 53.80 %.Keywords: membrane emulsion, extraction, stripping, span 80, kerosene, uranium. PENGGUNAAN MEMBRAN EMULSI SPAN 80 DAN TOPO UNTUK EKSTRASI DAN STRIPPING URANIUM. Telah dilakukan penelitian membran emulsi span 80 dan TOPO yang digunakan untuk ekstraksi uranium. Extraksi dengan membran emulsi H3PO4 dalam TOPO-Kerosen. Larutan umpan untuk fasa air eksternal adalah uranium dalam asam nitrat. Untuk memperoleh sistem emulsi yang stabil dipakai emulgator Span 80. Parameter yang berpengaruh adalah persen TOPO-Kerosene, molaritas fasa air internal H3PO4, molaritas fasa air eksternal HNO3 dan waktu ekstraksi. Setelah diperoleh membran emulsi, kemudian dilakukan proses ekstraksi dan stripping, dengan rasio volume umpan : volume membran sebesar 1 : 1; volume 5% TOPO-Kerose : volume 3M H3PO4 sebesar 1 : 1. Hasil relatif lebih baik diperoleh pada konsen-trasi TOPO Kerosene: volume  3 M H3PO4 adalah 5 %, molaritas larutan fasa internal sebesar 1 M, molaritas larutan fasa eksternal adalah 3 M H3PO4 dan waktu ekstraksi sebesar 10 menit dengan kecepatan emulsi 8000 rpm. Pada kondisi ini diperoleh effisiensi ekstraksi uranium 97,8 %, efisiensi stripping 52,56 % dan efisiensi total adalah 53,8 %.Kata Kunci : membran emulsi, ekstraksi, stripping, span 80, kerosen, uranium.

scholarly journals Programs to Estimate UV Dosage and Damage

1999 ◽  
Author(s):  
Brian Dickens ◽  
Eric Byrd
Keyword(s):  
Ir Spectra ◽  
Wavelength Range ◽  
Uv Spectra ◽  
Uv Absorption ◽  
Visible Radiation ◽  
Rapid Estimation ◽  
Interference Filters ◽  
User Friendly

The system of programs described in this paper is concerned with estimating the damage ensuing from exposure of specimens in dry and humid atmospheres to UV and visible radiation covering the solar range. Damage is monitored quantitatively by changes in IR spectra. The dose is estimated from UV spectra of the lamps and the interference filters (used to isolate a particular wavelength range). The dosage is estimated from the dose and the UV absorption of the specimens themselves. These programs allow rapid estimation of dosage and damage from regions of data, and manipulation and processing of the massive amounts of data required to carry out such comprehensive tests in a complete yet user-friendly manner.

Supramolecular Assembly of Functional Cholesteryl Substituted Luminol Derivative in Organized Molecular Films

2012 ◽  
Vol 581-582 ◽  
pp. 176-179
Author(s):  
Jing Xin Zhou ◽  
Ti Feng Jiao ◽  
Adan Li ◽  
Yuan Yuan Xing
Keyword(s):  
Ir Spectra ◽  
Potential Application ◽  
Water Surface ◽  
Supramolecular Assembly ◽  
Cd Spectra ◽  
Functional Material ◽  
Lb Films ◽  
Uv And Ir Spectra ◽  
Imide Group ◽  
Luminol Derivative

Functional luminol derivative with cholesteryl substituted group has been designed and synthesized from the reaction of the corresponding precursor cholesteryl chloroformate with luminol. This compound can be spread on water surface to form stable monolayer. It has been found that UV and IR spectra confirmed the characteristic aromatic segment, imide group and cholesteryl substituted group. In addition, the CD spectra also showed positive CD signals, which may be attributed to the chiral cholesteryl substituted groups. AFM investigation indicated some aggregated domains with the averaged height about 3.6  0.2 nm appeared. This suggested an organized structure of double molecules may be fabricated in the transferred LB films. The present results have demonstrated that the interfacial properties of luminol derivative can be modified by changing proper substituted groups of luminol, which show potential application in functional material fields such as ECL sensor.

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