Study on Solvent Resistance of Ternary Plastic Alloys of PEEK/PEI/PES

2014 ◽  
Vol 900 ◽  
pp. 27-31
Author(s):  
Jian Bing Chen

The PEEK/PEI/PES plastic alloys were processed by twin-screw extruder at 370°C separately with five mass ratios of 70/30/0, 70/25/5, 65/30/5, 60/30/10, The solvent resistance were investigated by experiments, their results showed that the concentrated H2SO4 resistance of alloy plates had been improved by alloying in 6h, the acetone resistance of mass ratio of 70/25/5 is preferably, increasing the content of PES, the acetone resistance becomes relatively stable, in addition, the chloroform and N, N-dimethyl formamide resistance of mass ratio of 70/25/5 is also preferably, and the polarity of the reagent has a limit influence on solvent resistance of plastics alloy materials.

2014 ◽  
Vol 584-586 ◽  
pp. 1523-1526
Author(s):  
Jian Bing Chen ◽  
Zhun Zhun Li ◽  
Jiang Jie Wang ◽  
Jin Ming Qian

The PEEK/PEI/PES plastic alloys were processed by twin-screw extruder at 370°C separately with five mass ratios of 70/30, 70/25/5, 65/30/5, 60/30/10. The flame retardant of plastic alloys were investigated by experiments, their results showed that, the oxygen index declines when PES was added, the oxygen index of plastic alloy with mass ratios of 70/30 is higher than that of pure PEEK or PES, lower than that of pure PEI, which the oxygen index is 37.1%. The volume resistivity plastic alloy with mass ratios of 60/30/10 is 3.72×1017Ω·cm, which is higher than that of pure PEEK and PES for two orders of magnitude, and the insulation performance of PEEK is improved significantly by alloying.


1996 ◽  
Vol 11 (2) ◽  
pp. 139-146 ◽  
Author(s):  
A. De Loor ◽  
P. Cassagnau ◽  
A. Michel ◽  
L. Delamare ◽  
B. Vergnes

2005 ◽  
Vol 82 (5) ◽  
pp. 574-581 ◽  
Author(s):  
Hanwu Lei ◽  
R. Gary Fulcher ◽  
Roger Ruan ◽  
Bernhard van Lengerich

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1058
Author(s):  
Hikaru Okubo ◽  
Haruka Kaneyasu ◽  
Tetsuya Kimura ◽  
Patchiya Phanthong ◽  
Shigeru Yao

Each year, increasing amounts of plastic waste are generated, causing environmental pollution and resource loss. Recycling is a solution, but recycled plastics often have inferior mechanical properties to virgin plastics. However, studies have shown that holding polymers in the melt state before extrusion can restore the mechanical properties; thus, we propose a twin-screw extruder with a molten resin reservoir (MSR), a cavity between the screw zone and twin-screw extruder discharge, which retains molten polymer after mixing in the twin-screw zone, thus influencing the polymer properties. Re-extruded recycled polyethylene (RPE) pellets were produced, and the tensile properties and microstructure of virgin polyethylene (PE), unextruded RPE, and re-extruded RPE moldings prepared with and without the MSR were evaluated. Crucially, the elongation at break of the MSR-extruded RPE molding was seven times higher than that of the original RPE molding, and the Young’s modulus of the MSR-extruded RPE molding was comparable to that of the virgin PE molding. Both the MSR-extruded RPE and virgin PE moldings contained similar striped lamellae. Thus, MSR re-extrusion improved the mechanical performance of recycled polymers by optimizing the microstructure. The use of MSRs will facilitate the reuse of waste plastics as value-added materials having a wide range of industrial applications.


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