Thermodynamic modelling of roasting of molybdenum sulphide concentrate with calcium hydroxide

This work aims to determine the conditions for the CaMoO4, CaSO4, Ca(ReO4)2 formation during oxidation of MoS2 and ReS2 in the presence of Ca(ОН)2. The concentrate from the Yuzhno-Shameyskoye deposit in the Sverdlovsk region, having 37% wt. Мо and 0.005% wt. Re, was selected as a feedstock for thermodynamic modelling of sweet roasting in the presence of Ca(OH)2. To determine the optimal amount of calcium-containing additives, the thermodynamic modelling was carried out using the following mass ratios: molybdenum concentrate: Ca(OH)2 = 1:0.8, 1:1, 1:1.2 and 1:1.5 in the temperature range of 100–800°С, with a step of 100°С, system pressure of 0.1 MPa in the air (molar ratio: molybdenum concentrate + Ca(OH)2: air = 1:5). The content of all sample components in moles was entered into the HSC 6.1 software package. The main reactions associated with the sweet roasting of molybdenum concentrate in the presence of calcium hydroxide were shown. It was established that the main phases formed as a result of roasting comprise CaSO4, CaSO3, MoO3, CaMoO4, CaMoO3 and CaReO4. The effect of temperature on the formation of the main gaseous products was studied under different mass ratios of molybdenum concentrate and Ca(OH)2. It was found that up to 600°C, with molybdenum concentrate to Ca(OH)2 ratio of 1:1, the concentrations of released sulphurous anhydride are lower than the maximum permissible concentrations. The calculated thermodynamic data was used for modelling the roasting process of molybdenum concentrate with calcium hydroxide. An optimal ratio necessary for the successful process operation was established: molybdenum concentrate: Ca(OH)2 = 1:1 by weight. Thermodynamic modelling showed that, in the temperature range of 100–600°С when using Ca(OH)2, no rhenium and molybdenum loss is observed, the release of sulfur is less than 10 mg/m3.

First Step towards the Upscaling of the Production of Washing Fines - Hemp Composite. Study of Multiphysical Properties

This study investigates the feasibility of scaling-up to industrial scale the production of washing fines – hemp composite. In previous studies (Mazhoud, 2017), (Mazhoud et al., 2017), such composites were developed with a high control of formulation. The washing mud were fully dried, and then milled. The washing fine – hemp composites were prepared from stabilized washing fine and hemp. This study aims to reduce the mud conditioning process in order to save energy and time. In a first time, the methodology for the conditioning of washing mud is detailed. Composite are then prepared considering unstabilized matrix and stabilized matrix with three stabilizer to fine mass ratios (5, 10 and 20 %). The apparent density increases with stabilizer to fine mass ratios according a degree two polynomial law. The mechanical compressive strength increases linearly with apparent density and the performance allows the studied composites to be used as wall formulation regarding the French national rules for hemp concrete. The thermal conductivity values range from 0.107 to 0.123 W/(m.K) at (23°C; 50%RH) reached from production point, this corresponds to a mass water content about 6%. Like for mechanical compressive strength, the thermal conductivity is mainly induced by apparent density. These thermal conductivity values make studied composite suitable for use as distributed insulation or thermal corrector. On hygric point of view, the Moisture Buffer Values classify all formulations as excellent hygric regulators. Finally, this paper shows the feasibility of scaling-up and that multi-physical properties of produced composites make them suitable for use in building envelop. The HSC-10 formulation seems to be the most promising regarding MBV results and considering that it would be possible to reduce thermal conductivity by acting on implementation in order to reduce apparent density.

Systematic KMTNet Planetary Anomaly Search. II. Six New q < 2 × 10−4 Mass-ratio Planets

We apply the automated AnomalyFinder algorithm of Paper I to 2018–2019 light curves from the ≃13 deg2 covered by the six KMTNet prime fields, with cadences Γ ≥ 2 hr−1. We find a total of 11 planets with mass ratios q < 2 × 10−4, including 6 newly discovered planets, 1 planet that was reported in Paper I, and recovery of 4 previously discovered planets. One of the new planets, OGLE-2018-BLG-0977Lb, is in a planetary caustic event, while the other five (OGLE-2018-BLG-0506Lb, OGLE-2018-BLG-0516Lb, OGLE-2019-BLG-1492Lb, KMT-2019-BLG-0253, and KMT-2019-BLG-0953) are revealed by a “dip” in the light curve as the source crosses the host-planet axis on the opposite side of the planet. These subtle signals were missed in previous by-eye searches. The planet-host separations (scaled to the Einstein radius), s, and planet-host mass ratios, q, are, respectively, (s, q × 105) = (0.88, 4.1), (0.96 ± 0.10, 8.3), (0.94 ± 0.07, 13), (0.97 ± 0.07, 18), (0.97 ± 0.04, 4.1), and (0.74, 18), where the “ ± ” indicates a discrete degeneracy. The 11 planets are spread out over the range − 5 < log q < − 3.7 . Together with the two planets previously reported with q ∼ 10−5 from the 2018–2019 nonprime KMT fields, this result suggests that planets toward the bottom of this mass-ratio range may be more common than previously believed.

The Environmental Dependence of Gas Properties in Dense Cores of a Protocluster at z ∼ 2.5 Revealed with ALMA

In a protocluster USS1558-003 at z = 2.53, galaxies in the dense cores show systematically elevated star-forming activity compared to those in less dense regions. To understand its origin, we look into the gas properties of the galaxies in the dense cores by conducting deep 1.1 mm observations with the Atacama Large Millimeter/submillimeter Array. We detect interstellar dust continuum emission from 12 member galaxies and estimate their molecular gas masses. Comparing these gas masses with our previous measurements from the CO(3–2) line, we infer that the latter might be overestimated. We find that the gas to stellar mass ratios of the galaxies in the dense cores tend to be higher (at M * ∼ 1010 M ⊙ where we see the enhanced star-forming activity), suggesting that such large gas masses can sustain their high star-forming activity. However, if we compare the gas properties of these protocluster galaxies with the gas scaling relations constructed for field galaxies at a similar cosmic epoch, we find no significant environmental difference at the same stellar mass and star formation rate. Although both gas mass ratios and star-forming activity are enhanced in the majority of member galaxies, they appear to follow the same scaling relation as field galaxies. Our results are consistent with the scenario in which the cold gas is efficiently supplied to protocluster cores and to galaxies therein along surrounding filamentary structures, which leads to the high gas mass fractions and thus the elevated star formation activity, but without changing the star formation law.

Effect of Pre-Injection on Combustion and Emission Characteristics of a Diesel Engine Fueled with Diesel/Methanol/n-Butanol Blended Fuel

In this study, the combustion and emission characteristics of a diesel/methanol/n-butanol blended fuel engine with different pre-injection timings and pre-injection mass ratios were investigated by a computational fluid dynamics (CFD) model. The CFD model was verified by the measured results and coupled with a simplified chemical kinetics mechanism. Firstly, the corresponding three-dimensional CFD model was established by CONVERGE software and the CHEKMIN program, and a chemical kinetic mechanism containing 359 reactions and 77 species was developed. Secondly, the combustion and emission characteristics of the diesel engine with different diesel/methanol/n-butanol blended fuels were analyzed and discussed. The results showed that increases in the pre-injection timing and the pre-injection mass ratio could increase cylinder pressure and cylinder temperature and decrease soot, HC, and CO emissions. At 100% load, the maximum cylinder pressures at the start of pre-injection timing from −15 °CA to −45 °CA, were 7.71, 9.46, 9.85, 9.912, and 9.95 MPa, respectively. The maximum cylinder pressures at pre-injection fuel mass ratios from 0.1 to 0.9 were 7.98, 9.10, 9.96, 10.52, and 11.16 MPa, respectively. At 50% load, with increases of the pre-injection timing and pre-injection fuel mass ratio, the soot emission decreased by 7.30%, 9.45%, 27.70%, 66.80%, 81.80% and 11.30%, 20.03%, 71.32%, 83.80%, 93.76%, respectively, and CO emissions were reduced by 5.77%, 12.31%, 22.73%, 53.59%, 63.22% and 8.29%, 43.97%, 53.59%, 58.86%, 61.18%, respectively. However, with increases of the pre-injection timing and pre-injection mass ratio, NOx emission increased. In addition, it was found that the optimal pre-injection timing and optimal pre-injection mass ratio should be −30 °CA and 0.5, respectively. Therefore, through this study we can better understand the potential interaction of relevant parameters and propose pre-injection solutions to improve combustion and emission characteristics.

Composite Nanocellulose Fibers-Based Hydrogels Loading Clindamycin HCl with Ca2+ and Citric Acid as Crosslinking Agents for Pharmaceutical Applications

Biocomposite hydrogels based on nanocellulose fibers (CNFs), low methoxy pectin (LMP), and sodium alginate (SA) were fabricated via the chemical crosslinking technique. The selected CNFs-based hydrogels were loaded with clindamycin hydrochloride (CM), an effective antibiotic as a model drug. The properties of the selected CNFs-based hydrogels loaded CM were characterized. The results showed that CNFs-based hydrogels composed of CNFs/LMP/SA at 1:1:1 and 2:0.5:0.5 mass ratios exhibited high drug content, suitable gel content, and high maximum swelling degree. In vitro assessment of cell viability revealed that the CM-incorporated composite CNFs-based hydrogels using calcium ion and citric acid as crosslinking agents exhibited high cytocompatibility with human keratinocytes cells. In vitro drug release experiment showed the prolonged release of CM and the hydrogel which has a greater CNFs portion (C2P0.5A0.5/Ca + Ci/CM) demonstrated lower drug release than the hydrogel having a lesser CNFs portion (C1P1A1/Ca + Ci/CM). The proportion of hydrophilic materials which were low methoxy pectin and sodium alginate in the matrix system influences drug release. In conclusion, biocomposite CNFs-based hydrogels composed of CNFs/LMP/SA at 1:1:1 and 2:0.5:0.5 mass ratios, loading CM with calcium ion and citric acid as crosslinking agents were successfully developed for the first time, suggesting their potential for pharmaceutical applications, such as a drug delivery system for healing infected wounds.

Compressive mechanical behavior and model of composite elastic-porous metal materials

This work presents the experimental characterization and theoretical modeling of composite elastic-porous metal materials (C-EPMM). C-EPMM is a novel porous metallic damping material made of wire mesh and wire helix. A series of quasi-static compressive experiments were carried out to investigate the stiffness and energy absorption ability of the C-EPMM with different mass ratios. The experimental results show that the mass ratios can significantly affect the stiffness and loss factor of C-EPMM. To efficiently predict the nonlinear mechanical properties of the C-EPMM a theoretical model of C-EPMM was proposed for the first time, the model was based on the manufacturing process. A comparison between the predicted data and the experimental data was conducted. The results show that the theoretical model can accurately predict the mechanical performance of C-EPMM. The conclusions derived from this work can provide a new method for adjusting the mechanical performance of EPMM in applications.

Two Contact Binaries with Mass Ratios Close to the Minimum Mass Ratio

The cutoff mass ratio is under debate for contact binaries. In this paper, we present the investigation of two contact binaries with mass ratios close to the low mass ratio limit. It is found that the mass ratios of VSX J082700.8+462850 (hereafter J082700) and 1SWASP J132829.37+555246.1 (hereafter J132829) are both less than 0.1 (q ∼ 0.055 for J082700 and q ∼ 0.089 for J132829). J082700 is a shallow contact binary with a contact degree of ∼19%, and J132829 is a deep contact system with a fill-out factor of ∼70%. The O − C diagram analysis indicated that the two systems manifested long-term period decreases. In addition, J082700 exhibits a cyclic modulation which is more likely resulting from the Applegate mechanism. In order to explore the properties of extremely low mass ratio contact binaries (ELMRCBs), we carried out a statistical analysis on contact binaries with mass ratios of q ≲ 0.1 and discovered that the values of J spin/J orb of three systems are greater than 1/3. Two possible explanations can interpret this phenomenon. One explanation is that some physical processes, unknown to date, are not considered when Hut presented the dynamic stability criterion. The other explanation is that the dimensionless gyration radius (k) should be smaller than the value we used (k 2 = 0.06). We also found that the formation of ELMRCBs possibly has two channels. The study of evolutionary states of ELMRCBs reveals that their evolutionary states are similar with those of normal W UMa contact binaries.