Bulk Ferromagnetic (Fe0.87Co0.13)71.5-xTb3.5NbxB25 Glassy Alloys with a High Glass-Forming Ability

Author(s):  
Yi Long ◽  
Rong Chang Ye ◽  
Yong Qing Chang ◽  
Farong Wan
2010 ◽  
Vol 18 (10) ◽  
pp. 1876-1879 ◽  
Author(s):  
Qikui Man ◽  
Huaijun Sun ◽  
Yaqiang Dong ◽  
Baolong Shen ◽  
Hisamichi Kimura ◽  
...  

2007 ◽  
Vol 22 (2) ◽  
pp. 471-477 ◽  
Author(s):  
Dong Ho Kim ◽  
Jin Man Park ◽  
Do Hyang Kim ◽  
Won Tae Kim

The effects of niobium (Nb) addition on the glass-forming ability (GFA), crystallization behavior, and compressive mechanical property of iron (Fe)–boron (B)–yttrium (Y) alloys have been investigated. Among the (Fe71.2B24Y4.8)100−xNbx (x = 0, 2, 4, 6, 8) alloys investigated, (Fe71.2B24Y4.8)96Nb4 exhibits the highest GFA, enabling the formation of glassy rods with a maximum diameter of 7 mm, which is the largest among quaternary Fe-based alloys. The comparison of the crystallization behavior of the alloys shows that the formation of metastable Fe23B6 phase during crystallization in the (Fe71.2B24Y4.8)96Nb4 alloy can suppress the formation of other stable crystalline phases such as α-Fe, enhancing the stability of the glass phase. The present results show that the attainment of a significantly high GFA is possible even in a quaternary Fe-based alloy system by properly tailoring the competing crystalline phase by the modification of liquid chemistry.


2008 ◽  
Vol 148 (1-3) ◽  
pp. 92-96 ◽  
Author(s):  
Wei Zhang ◽  
Qingsheng Zhang ◽  
Chunling Qin ◽  
Akihisa Inoue

2005 ◽  
Vol 97 (10) ◽  
pp. 10F913 ◽  
Author(s):  
Kenji Amiya ◽  
Akiri Urata ◽  
Nobuyuki Nishiyama ◽  
Akihisa Inoue

2006 ◽  
Vol 21 (1) ◽  
pp. 234-241 ◽  
Author(s):  
W. Zhang ◽  
A. Inoue

The addition of Ag to Cu–Zr alloys is very effective for the increase in the stability of supercooled liquid as well as the glass-forming ability (GFA). The large supercooled liquid region (ΔTx) exceeding 60 K in Cu–Zr–Ag ternary system was obtained in a wide range of 25–55 at.% Cu, 40–65 at.% Zr, and 5–25 at.% Ag. The best GFA was obtained around Cu45Zr45Ag10, and glassy alloy rods with diameters up to 6.0 mm were formed by copper mold casting. The bulk glassy alloys exhibit good mechanical properties, i.e., compressive fracture strength of 1780–1940 MPa, Young's modulus of 106–112 GPa, compressive plastic elongation of 0.2–2.9%, and Vickers hardness of 534–599. The finding of the new Cu–Zr–Ag ternary glassy alloy system with high GFA and good mechanical properties is important for development and scientific studies of bulk glassy alloys.


2008 ◽  
Vol 23 (8) ◽  
pp. 2283-2287 ◽  
Author(s):  
Dmitri V. Louzguine-Luzgin ◽  
Takanobu Saito ◽  
Junji Saida ◽  
Akihisa Inoue

In this work, we study the cooling behavior of several typical bulk glassy alloys on casing and present the relationship between the thermal conductivity of a glassy alloy and the cooling rate upon mold casting. The cooling rates obtained for Ti-, Zr-, Pd-, and Cu-based bulk glass forming alloys are found to scale with the thermal conductivities of the studied glassy alloys.


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