Martensitic Transformation of High-Entropy and Medium-Entropy Shape Memory Alloys

2021 ◽  
Vol 1016 ◽  
pp. 1802-1810
Author(s):  
Hiromichi Matsuda ◽  
Masayuki Shimojo ◽  
Hideyuki Murakami ◽  
Yoko Yamabe-Mitarai
Keyword(s):  
Solid Solution ◽  
High Temperature ◽  
Martensitic Transformation ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Transformation Temperature ◽  
Solid Solution Hardening ◽  
Solution Hardening ◽  
High Entropy ◽  
The One

As new generation of high-temperature shape memory alloys, high-entropy alloys (HEAs) have been attracted for strong solid-solution hardened alloys due to their severe lattice distortion and sluggish diffusion. TiPd is the one potential high-temperature shape memory alloys because of its high martensitic transformation temperature above 500 °C. As constituent elements, Zr expected solid-solution hardening, Pt expected increase of transformation temperature, Au expected keeping transformation temperature, and Co expected not to form harmful phase. By changing the alloy composition slightly, two HEAs and two medium entropy alloys (MEAs) were prepared. Only two MEAs, Ti45Zr5Pd25Pt20Au5, and Ti45Zr5Pd25Pt20Co5 had the martensitic transformation. The perfect recovery was obtained in Ti45Zr5Pd25Pt20Co5 during the repeated thermal cyclic test, training, under 200 MPa. On the other hand, the small irrecoverable strain was remained in Ti45Zr5Pd25Pt20Au5 during the training under 150 MPa because of the small solid-solution hardening effect. It indicates that Ti45Zr5Pd25Pt20Co5 is the one possible HT-SMA working between 342 and 450 °C.

scholarly journals TiPd- and TiPt-Based High-Temperature Shape Memory Alloys: A Review on Recent Advances

Metals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1531
Author(s):  
Yoko Yamabe-Mitarai
Keyword(s):  
High Temperature ◽  
Martensitic Transformation ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Transformation Temperature ◽  
Ternary Alloys ◽  
Alloying Elements ◽  
Martensitic Transformation Temperature ◽  
High Entropy ◽  
Perfect Recovery

In this paper high-temperature shape memory alloys based on TiPd and TiPt are reviewed. The effect of the alloying elements in ternary TiPd and TiPt alloys on phase transformation and strain recovery is also discussed. Generally, the addition of alloying elements decreases the martensitic transformation temperature and improves the strength of the martensite and austenite phases. Additionally, it also decreases irrecoverable strain, but without perfect recovery due to plastic deformation. With the aim to improve the strength of high-temperature shape memory alloys, multi-component alloys, including medium- and high-entropy alloys, have been investigated and proposed as new structural materials. Notably, it was discovered that the martensitic transformation temperature could be controlled through a combination of the constituent elements and alloys with high austenite finish temperatures above 500 °C. The irrecoverable strain decreased in the multi-component alloys compared with the ternary alloys. The repeated thermal cyclic test was effective toward obtaining perfect strain recoveries in multi-component alloys, which could be good candidates for high-temperature shape memory alloys.

Development of High-Temperature Shape Memory Alloys above 673 K

2016 ◽  
Vol 879 ◽  
pp. 107-112 ◽  
Author(s):  
Yoko Yamabe-Mitarai
Keyword(s):  
High Temperature ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Martensite Transformation ◽  
Shape Recovery ◽  
Solid Solution Hardening ◽  
Alloying Element ◽  
Solution Hardening

TiPd was investigated as a candidate of high-temperature shape memory alloys. To improve shape recovery, solid-solution hardening by addition of alloying element has been performed. The effect of alloying on martensite transformation temperature, shape memory effect, and yield strength of martensite and austenite phases were investigated. Zr and Hf were found to be effective element to improve shape memory effect. The most important factor to improve shape memory effect of TiPd is temperature to form Ti2Pd3 precipitates rather than strengthening.

Temperature Dependence and Martensitic Transformation of Ti50Pt50 Shape Memory Alloys

2014 ◽  
Vol 1019 ◽  
pp. 379-384
Author(s):  
M.P. Mashamaite ◽  
Hasani Rich Chauke ◽  
Rosinah Mahlangu ◽  
P.E. Ngoepe
Keyword(s):  
Molecular Dynamics ◽  
High Temperature ◽  
Martensitic Transformation ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Temperature Dependence ◽  
Effect Of Temperature ◽  
Displacive Transformation ◽  
B2 Phase ◽  
Recent Experimental Work

Shape memory alloys (SMAs) are a fascinating group of metals that have two remarkable properties, the shape memory effect and superelasticity. The TiPt structure with the B2 phase has been reported to undergo a reversible displacive transformation to B19 martensite at about 1200K. However, this system could serve in principle as the basis of high-temperature shape memory alloys. Molecular dynamics study of martensitic transformation in platinum titanium alloys was performed to investigate the effect of temperature dependence on B2 and B19 structures at 50 at.%Pt. The NPT ensemble was used to determine the properties of these systems and we found good comparisons with recent experimental work. The temperature dependence of TiPt shows potential martensitic change when B19 is heated to extreme high temperatures of 273K up to 1573K.

scholarly journals Microstructure Formation in Cast TiZrHfCoNiCu and CoNiCuAlGaIn High Entropy Shape Memory Alloys: A Comparison

Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4227 ◽  
Author(s):  
Tetiana A. Kosorukova ◽  
Gregory Gerstein ◽  
Valerii V. Odnosum ◽  
Yuri N. Koval ◽  
Hans Jürgen Maier ◽  
...  
Keyword(s):  
Martensitic Transformation ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Microstructure Characterization ◽  
Microstructure Formation ◽  
High Entropy

The present study is dedicated to the microstructure characterization of the as-cast high entropy intermetallics that undergo a martensitic transformation, which is associated with the shape memory effect. It is shown that the TiZrHfCoNiCu system exhibits strong dendritic liquation, which leads to the formation of martensite crystals inside the dendrites. In contrast, in the CoNiCuAlGaIn system the dendritic liquation allows the martensite crystals to form only in interdendritic regions. This phenomenon together with the peculiarities of chemical inhomogeneities formed upon crystallization of this novel multicomponent shape memory alloys systems will be analyzed and discussed.

Evolutions of Microstructure and Phase Transformation in Cu-Al-Fe-Nb/Ta High-Temperature Shape Memory Alloys

2015 ◽  
Vol 833 ◽  
pp. 67-70
Author(s):  
Shui Yuan Yang ◽  
Cui Ping Wang ◽  
Yu Su ◽  
Xing Jun Liu
Keyword(s):  
Phase Transformation ◽  
High Temperature ◽  
Martensitic Transformation ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Transformation Behavior ◽  
Two Phase ◽  
Phase Transformation Behavior ◽  
Three Phase

The evolutions of microstructure and phase transformation behavior of Cu-Al-Fe-Nb/Ta high-temperature shape memory alloys under the quenched and aged states were investigated in this study, including Cu-10wt.% Al-6wt.% Fe, Cu-10wt.% Al-4wt.% Fe-2wt.% Nb and Cu-10wt.% Al-4wt.% Fe-2wt.% Ta three types alloys. The obtained results show that after quenching, Cu-10wt.% Al-6wt.% Fe alloy exhibits two-phase microstructure of β′1 martensite + Fe (Al,Cu) phase; Cu-10wt.% Al-4wt.% Fe-2wt.% Nb alloy also has two-phase microstructure of (β′1 + γ′1 martensites) + Nb (Fe,Al,Cu)2 phase; Cu-10wt.% Al-4wt.% Fe-2wt.% Ta alloy is consisted of three-phase of (β′1 + γ′1 martensites) + Fe (Al,Cu,Ta) + Ta2(Al,Cu,Fe)3 phases. However, α (Cu) phase precipitates after aging for three alloys; and Fe (Al,Cu,Nb) phase is also present in Cu-10wt.% Al-4wt.% Fe-2wt.% Nb alloy. All the studied alloys exhibit complicated martensitic transformation behaviors resulted from the existence of two types martensites (β′1 and γ′1).

Modelling solid solution hardening in high entropy alloys

2015 ◽  
Vol 85 ◽  
pp. 14-23 ◽  
Author(s):  
Isaac Toda-Caraballo ◽  
Pedro E.J. Rivera-Díaz-del-Castillo
Keyword(s):  
Solid Solution ◽  
Solid Solution Hardening ◽  
High Entropy Alloys ◽  
Solution Hardening ◽  
High Entropy
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