First-Principles Calculations of Titanium Dopants in Alumina
2005 ◽
Vol 475-479
◽
pp. 3095-3098
Keyword(s):
Band Gap
◽
First-principles pseudopotential calculations were performed to investigate atomic and electronic structures of titanium (Ti) dopants in alumina (Al2O3). It was found that a substitutional Ti3+ defect induced an extra level occupied by one electron within the band gap of Al2O3. When two or more substitutional Ti3+ defects were located closely to each other, the defect-induced levels exhibited strong bonding interactions, and their formation energies decreased with increasing numbers of Ti3+ defects. This indicates that association and clustering of substitutional Ti3+ defects in Al2O3 can take place due to the interaction of the defect-induced levels.
2005 ◽
Vol 475-479
◽
pp. 3111-3114
2018 ◽
Vol 32
(07)
◽
pp. 1850092
◽
2015 ◽
Vol 645-646
◽
pp. 325-329
2014 ◽
Vol 614
◽
pp. 70-74
◽
2012 ◽
Vol 11
(06)
◽
pp. 1261-1280
◽
2003 ◽
Vol 150
(1)
◽
pp. A63
◽
Keyword(s):
2021 ◽
Vol 129
◽
pp. 105779