Interface Microstructure and Adhesion of Zinc Coatings on TRIP Steels

2007 ◽  
Vol 539-543 ◽  
pp. 1104-1109 ◽  
Author(s):  
G.M. Song ◽  
Willem G. Sloof ◽  
T. Vystavel ◽  
Jeff T.M. de Hosson

Hot-dip galvanized transformation induced plasticity (TRIP) steel sheets were recently developed for automotive applications. The microstructure and the adhesion of zinc coated CMnSi TRIP steel alloyed with P were studied. The α-Zn coating adjacent to the steel substrate consists of a continuous η-Fe2Al5-xZnx inhibition layer with columnar ζ-FeZn13 intermetallic particles on top. Along the interface between the inhibition layer and the steel substrate Mn/Mn-P oxides were frequently observed. Although these oxides at the steel surface reduce the adhesion between the zinc coating and the TRIP steel, they do not cause any bare spots during galvanizing. Upon tensile deformation of the galvanized steel sheet, cracking along the α-zinc grain boundaries preceded fracture of the interface between the α-Zn layer and the inhibition layer. After 4 % deformation the average interface crack length increased linearly with the applied strain. This interface fracture was strongly influenced by the crystalline orientation of the α-Zn grains.

2016 ◽  
Vol 2016 ◽  
pp. 1-6
Author(s):  
Jarmila Trpčevská ◽  
Mária Kollárová ◽  
Eva Zdravecká ◽  
Jana Tkáčová

The performance of hot-dip coated steel sheets is associated with properties of the zinc coatings on steel substrate. For the characterization of the adhesion behaviour of zinc coating on steel various tests were employed. The study was focused on quantification assessment of galvanized coating adhesion to substrates. Methods for evaluation of the bonding strength of zinc coating by the shear strength and the T-peel tests applying four special types of adhesives were used. The experimental tests of bonded joints show that the adhesion of the zinc coating to the substrate was higher than that of the applied adhesive with the highest strength.


Coatings ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 202
Author(s):  
Gui Li ◽  
Xiaoyu Long

Advanced high strength galvanized steel sheet has been one of the dominant materials of modern automotive panels because of its outstanding mechanical properties and corrosion resistance. The zinc coating thickness of hot dip galvanized steel sheet is only about 10–20 μm, which is a discarded object on the macro level. However, it is obvious to damage and impact on stamping performance. Therefore, this paper takes zinc coating as the research object and builds its mechanical constitutive model based on a nano-indentation test and dimensional analysis theory. We separated the zinc coating from the galvanized steel substrate and constructed a sandwich material model by introducing a cohesive layer to connect the zinc coating and the steel substrate. We obtained the interface binding energy between the zinc coating and the steel substrate through the nano-scratch test. The accuracy of the model is verified by the finite element analysis of hemispherical parts. We used the five-layers element model with 0 thickness cohesive layer to simulate the zinc coating damage of galvanized steel sheet. The hemispherical part drawing experiment is used to verify the feasibility of the finite element analysis results. The results demonstrate that it is more accurate to consider the finite element numerical simulation of the zinc coating, introducing the cohesive element to simulate damage between the coating and the substrate. Drawing depth, stamping force, and the strain of the numerical simulation are closer to the experimental results.


2004 ◽  
Vol 35 (3) ◽  
pp. 813-823 ◽  
Author(s):  
Rodolphe Parisot ◽  
Samuel Forest ◽  
André Pineau ◽  
François Grillon ◽  
Xavier Demonet ◽  
...  

2017 ◽  
Vol 9 (7) ◽  
pp. 168781401771498
Author(s):  
Khasempong Songsorn ◽  
Keartisak Sriprateep ◽  
Sampan Rittidech

In this article, an optimization technique using the Taguchi method with multiple performance characteristics for the percent zinc coating balances edge joints of galvanized steel sheets for metal inert gas pulse brazing process was proposed. The orthogonal array, multi-response signal-to-noise ratio, and analysis of variance were employed to study the performance characteristics. Five metal inert gas pulse brazing process parameters, namely, wire feed speed, arc voltages, travel speed, peak currents, and pulse frequency, were optimized with considerations of multiple performance characteristics including percent zinc coating balances edge joints. Experimental results were provided to confirm the effectiveness of this approach. The optimum metal inert gas pulse brazing technique conditions were wire feed speed of 3.25 m/min, arc voltages of 18 V, travel speed of 0.8 m/min, peak currents of 425 A, and pulse frequency of 35 Hz. Confirmation tests of the optimal levels with the initial cutting parameters are carried out in order to illustrate the effectiveness of this method in metal inert gas pulse brazing technique for galvanized steel sheets.


2015 ◽  
Vol 818 ◽  
pp. 141-144
Author(s):  
Luboš Kaščák ◽  
Janette Brezinová ◽  
Jacek Mucha

The steel sheets used for the car body production are protected against corrosion by zinc coating. Resistance spot welding is used mainly for joining these sheets, because of its high speed and adaptability for automation in high-rate production. However, resistance spot welding has a negative influence on the corrosion resistance of joints. The paper focuses on the analysis of quality of welds on galvanized steel sheets and their corrosive properties. Tensile test and accelerated corrosion test in corrosive environment were used for evaluation of the welds’ quality. Protective efficiency of zinc coatings for automobile sheets was evaluated as well, based on the determination of their electrochemical characteristics in passivated and non-passivated state, as well as their corrosion resistance in simulated corrosion environments. Two types of DX54D+Z material were used for experiments: non-passivated and passivated with Cr3+.


2004 ◽  
Vol 35 (3) ◽  
pp. 797-811 ◽  
Author(s):  
Rodolphe Parisot ◽  
Samuel Forest ◽  
André Pineau ◽  
François Grillon ◽  
Xavier Demonet ◽  
...  

2020 ◽  
Vol 4 (141) ◽  
pp. 140-147
Author(s):  
MIKHAIL VIKHAREV ◽  
◽  
VLADIMIR YUDIN ◽  
VESELOVSKIY NIKOLAY ◽  
◽  
...  

The article shows the role of electroplating in the restoration of parts, indicates the advantages of restoring parts with electroplating over other methods, and gives the characteristics and properties of coatings obtained by electroplating. (Research purpose) The research purpose is in increasing the speed of application of zinc electroplating when restoring parts. (Materials and methods) The cathode current density has a decisive influence on the coating speed. The main reason for limiting the cathode current density during galvanizing from sulfuric acid electrolytes is the chemical polarization of the cathode. The article presents a study on the designed installation for the application of galvanic coatings. When applying coatings to the internal surfaces of parts, there was used a device with activating elements having an electromechanical rotation drive. This device prevents depletion of the near-cathode layer of the electrolyte and reduces the chemical polarization of the cathode. Elements made of moisture-resistant skin were used as activators. (Results and discussion) The article presents the results of experiments as a dependence of the coating speed on the speed of the activator relative to the restoring surface. It also presents the relationship between the size of the abrasive grains of the activating elements, the force of their pressing against the cathode surface, the speed of movement of the activator and the speed of applying the zinc coating, as well as its quality. By activating the cathode surface, it was possible to raise the operating current density to 100-150 amperes per square decimeter. The speed of application of zinc coatings is 16-25 micrometers per minute. (Conclusions) In the course of research, authors determined the conditions of electrolysis during galvanizing, which provide a significant increase in the cathode current density and the rate of application of these coatings during the restoration of parts.


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