Cu2O Doping Effects on Microstructure and Piezoelectric Properties in (Na0.52K0.44)(Nb0.9Sb0.06)O3-0.04LiTaO3 Pb-Free Ceramics

2012 ◽  
Vol 724 ◽  
pp. 123-126
Author(s):  
Soon Young Kweon ◽  
Youn Ki Lee ◽  
Sung Lim Ryu
Keyword(s):  
Phase Boundary ◽  
Tetragonal Phase ◽  
Piezoelectric Properties ◽  
Solid State Reaction Method ◽  
Coupling Factor ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Mechanical Coupling ◽  
Doping Effects ◽  
Piezoelectric Charge

The (Na0.52K0.44)(Nb0.9Sb0.06)O3-0.04LiTaO3 (NKNS-LT) ceramics doped with various Cu2O contents were prepared by the conventional solid state reaction method. The Cu2O content was varied in the range of 0.1~0.4 wt%. The effects of Cu on microstructure, crystallographic phase transition, and piezoelectric properties were investigated. The material with perovskite structure had a tetragonal phase (T1) when Cu2O concentration was less than 0.3 wt% and it was transformed to another tetragonal phase (T2) when the Cu2O amount was greater than 0.3 wt%. The phase boundary between T1 and T2 phases was appeared at around 0.3 wt% of Cu2O concentration. The piezoelectric properties were shown the maximum values at the composition of the phase boundary. The electro-mechanical coupling factor (kp) was 0.42 and the piezoelectric charge constant (d33) was 245 pC/N at the 0.3 wt% of Cu2O concentration.

Investigation of the Morphotropic Phase Boundary (MPB) of (1-x-y)BaZrO3-x(K0.45Na0.5Li0.05)NbO3-yBi (Mg0.5Ti0.5)O3

2014 ◽  
Vol 787 ◽  
pp. 242-246
Author(s):  
Rui Lin Wu ◽  
Tomoaki Karaki ◽  
Jiang Tao Zeng ◽  
Liao Ying Zheng ◽  
Wei Ruan ◽  
...  
Keyword(s):  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Tetragonal Phase ◽  
Room Temperature ◽  
Piezoelectric Properties ◽  
Piezoelectric Ceramics ◽  
Solid State Reaction Method ◽  
Lead Free ◽  
Reaction Method ◽  
Dielectric And Piezoelectric Properties

Lead-based piezoelectric ceramics have excellent piezoelectric properties with the compositions near the rhombohedral-tetragonal morphotropic phase boundary (MPB)[1,2]. In these materials, the dielectric and piezoelectric properties show the maximal values at MPB. For lead-free piezoelectric ceramics, finding the MPB area is a promising way to improve their properties. In this paper, the (1-x-y)BaZrO3-x(K0.45Na0.5Li0.05)NbO3-yBi (Mg0.5Ti0.5)O3 lead-free piezoelectric ceramics were prepared by solid-state reaction method, and their piezoelectric properties and dielectric properties were investigated. With the increase of KNLN content, the crystal structure changed from rombohedral phase to tetragonal phase, thus existed a MPB[3,4] between rombohedral and tetragonal phase. At room temperature, the specimen with the composition at MPB (x=0.93, y=0.01) shows the optimal piezoelectric properties (d33=225pC/N and kp=45%), which indicates that this material is a potential lead-free piezoceramic.

Study on the Property of Ba0.85Ca0.15Ti0.9Zr0.1O3 Lead-Free Piezoelectric Ceramics Doped with Li2CO3

2012 ◽  
Vol 549 ◽  
pp. 651-654 ◽  
Author(s):  
Zhi Wen Zhu ◽  
Xin You Huang ◽  
Hai Tang Hua ◽  
Yan Li
Keyword(s):  
Grain Size ◽  
Piezoelectric Properties ◽  
Piezoelectric Ceramics ◽  
Solid State Reaction Method ◽  
Lead Free ◽  
Doping Amount ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Mechanical Coupling ◽  
Planar Electron

Ba0.85Ca0.15Ti0.9Zr0.1O3-xLi2CO3 lead-free piezoelectric ceramics (abbreviated as BCZT-xLi) were prepared by conventional solid state reaction method. The microstructure, piezoelectric properties and dielectric properties were studied for BCZT-xLi samples doped with different Li2CO3 content(x= 0, 0.05, 0.1 0.2 0.3, 0.4wt. %). The results show that the piezoelectric constant(d33), planar electron mechanical coupling coefficient(kp) and thickness electron mechanical(kt) of BCZ-T-xLi ceramics increase firstly and decreases subsequently with increasing of Li+ doping amount, the dielectric loss(tanδ) of BCZT-xLi ceramics decreases firstly and then increases at the same time while Li+ doping amount increases. But the r-elative permittivity (εr) of BCZT-xLi ceramics increases all the time. With the in-creasing of the amount of Li2CO3 doped the grain size of BCZT-Li ceramic first increases and then decreases. The BCZT-xLi ceramics display the optimum properties (d33=83, tanδ=0.035, εr=2020, kp=0.41, kt=0.046) while Li2CO3 doped amount is 0.20wt. %.

Study on Dielectric and Ferroelectric Properties of Gd-Doped Sr2Bi4Ti5O18 Ceramics

2011 ◽  
Vol 328-330 ◽  
pp. 1131-1134
Author(s):  
Qian Chen ◽  
Zhi Jun Xu ◽  
Rui Qing Chu ◽  
Yong Liu ◽  
Ming Li Chen ◽  
...  
Keyword(s):  
Piezoelectric Properties ◽  
Ferroelectric Properties ◽  
Solid State Reaction Method ◽  
Lead Free ◽  
Structural Ceramics ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Maximum Value ◽  
Pure Bismuth ◽  
Ferroelectric And Piezoelectric Properties

Lead-free piezoelectric ceramics Sr2Bi4-xGdxTi5O18 were prepared by conventional solid-state reaction method. Pure bismuth layered structural ceramics with uniform gain size were obtained in all samples. The effect of Gd-doping on the dielectric, ferroelectric and piezoelectric properties of Sr2Bi4Ti5O18 ceramics were also investigated. It was found that that Gd3+ dopant gradually decreased the Curie temperature (Tc) with the lower dielectric loss (tand) of SBTi ceramics. In addition, Gd-doping with appropriate content improved the ferroelectric and piezoelectric properties of the SBTi ceramics. The piezoelectric constant (d33) of the Sr2Bi3.9Gd0.1Ti5O18 ceramic reached the maximum value, which is 22 pC/N. The results showed that the Sr2Bi4-xGdxTi5O18 ceramic was a promising lead-free piezoelectric material.

Effect of orthorhombic–tetragonal phase transition on structure and piezoelectric properties of KNN-based lead-free ceramics

2015 ◽  
Vol 44 (17) ◽  
pp. 7797-7802 ◽  
Author(s):  
Yang Zhang ◽  
Lingyu Li ◽  
Bo Shen ◽  
Jiwei Zhai
Keyword(s):  
Phase Transition ◽  
Solid State ◽  
Piezoelectric Properties ◽  
Solid State Reaction Method ◽  
Lead Free ◽  
Polymorphic Phase Transition ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Lead Free Ceramics ◽  
Tetragonal Phase Transition

Lead free piezoelectric ceramics have been prepared by the conventional solid state reaction method and the effects of SrZrO3 content on polymorphic phase transition are investigated.

(1-x)(K0.44Na0.52Li0.04)(Nb0.84Ta0.10Sb0.06)O3-xSrTiO3 Lead Free Piezoelectric Ceramics

2008 ◽  
Vol 368-372 ◽  
pp. 1896-1898
Author(s):  
Ming He Cao ◽  
Wan Qiang Wang ◽  
Zhi Yong Yu ◽  
Hua Hao ◽  
Han Xing Liu
Keyword(s):  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Composition Range ◽  
Piezoelectric Properties ◽  
Piezoelectric Ceramics ◽  
Solid State Reaction Method ◽  
Lead Free ◽  
Sintering Behavior ◽  
Reaction Method ◽  
Na Ions

(1-x)(K0.44Na0.52Li0.04)(Nb0.84Ta0.10Sb0.06)O3-xSrTiO3 (KNNT-ST) lead free piezoelectric ceramics have been synthesized by a solid state reaction method. The effect of SrTiO3 content on the piezoelectric properties, sintering behavior and microstructure of (1-x) KNNT-x ST ceramics was investigated. The experimental results showed that the addition of SrTiO3 can restrain the volatilization of Na ions and K ions and improve relative density of the samples. A morphotropic phase boundary between orthorhombic and tetragonal phases is found in the composition range of 0.03<x<0.05. The piezoelectric properties can be enhanced for (1-x) KNNT-x ST ceramics near the morphotropic phase boundary.

Influence of sintering temperature on structure, microstructure and piezoelectric properties of doped BZT–BCT ceramics

2017 ◽  
Vol 31 (02) ◽  
pp. 1650258 ◽  
Author(s):  
Anh Tuan Dang ◽  
Thanh Tung Vo ◽  
Van Chuong Truong ◽  
Van Hong Le
Keyword(s):  
Solid State ◽  
Piezoelectric Properties ◽  
Sintering Temperature ◽  
Solid State Reaction Method ◽  
Sintering Behavior ◽  
Zno Nanoparticle ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Best Parameters ◽  
Better Than

This work reports the influence of sintering temperature on structure, microstructure and piezoelectric properties of 0.48 Ba(Zr[Formula: see text]Ti[Formula: see text])O3–0.52 (Ba[Formula: see text]Ca[Formula: see text])TiO3(BZT–BCT) doped with ZnO nanoparticle ceramics manufactured by a conventional solid state reaction method. By increasing sintering temperature, the piezoelectric behaviors were improved and rose up to the best parameters at a sintering temperature of 1450[Formula: see text]C ([Formula: see text] pC/N and [Formula: see text]). The corresponding properties of undoped BZT–BCT ceramics were investigated as a comparison. The received results show that the sintering behavior and piezo-parameters of doped BZT–BCT samples are better than the undoped BZT–BCT samples at each sintering temperature.

scholarly journals Electrical and Thermal Properties of Na1–xLixNbO3 (x = 0.08, 0.1 and 0.2) Ceramics Near the Morphotropic Phase Boundary Region

2017 ◽  
Vol 62 (2) ◽  
pp. 539-544 ◽  
Author(s):  
K. Konieczny ◽  
P. Czaja
Keyword(s):  
Thermal Properties ◽  
Electrical Properties ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Solid State Reaction Method ◽  
Boundary Region ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Practical Applications ◽  
Solid Compounds

AbstractNa1-xLixNbO3ceramics (for x = 0.08, 0.1, 0.2) were fabricated by the conventional solid state reaction method. The influence of LiNbO3on the microstructure, electric, thermal properties of Na1-xLixNbO3ceramics was studied and a significant influence of doped Li ions on the electrical properties was observed. The electrical properties were improved and are described as the best for x = 0.1 (near a morphotropic phase boundary) Na1–xLixNbO3solid solutions. After crossing the morphotropic phase boundary for x = 0.2, the electric properties are getting worse. These types of solid compounds show some interesting properties suitable for practical applications.

Effects of B2O3 doping on the dielectric and piezoelectric properties of (K,Na,Li)NbO3-BaZrO3-(Bi,Na)TiO3 ceramics

2021 ◽  
Author(s):  
Nan Wei ◽  
Tomoaki KARAKI ◽  
Tadashi Fujii
Keyword(s):  
Piezoelectric Properties ◽  
Sintering Temperature ◽  
Solid State Reaction Method ◽  
X Ray Diffraction ◽  
Two Phase ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
X Ray ◽  
High Relative Density ◽  
Dielectric And Piezoelectric Properties

Abstract (K,Na,Li)NbO3-BaZrO3-(Bi,Na)TiO3-x B2O3 (abbreviated as KNLN-BZ-BNT-x B2O3) ceramics were prepared by conventional solid state reaction method. The effects of B2O3 content on dielectric and piezoelectric properties of the KNLN-BZ-BNT ceramics have been studied. Based on the identification by X-ray diffraction (XRD), all the samples show a two-phase coexistence zone consisting of rhombohedral (R) and tetragonal (T) phases. For the ceramics with x = 0.5 wt%, the sintering temperature was observed to reduce from 1200 oC to 940 oC, while the samples maintained a high relative density around 97%. Because of the high densification and large grain size, the dielectric and piezoelectric properties were improved. As a result, the ceramics with x = 0.5 wt% sintered at 940 oC exhibited good properties of d 33 = 197 pC/N, k p= 0.29, tan δ = 0.029 and ε r = 1889, together with a Curie temperature (T C) of 222 oC.

The Morphologies and Photoluminescence of Ce3+-Doped 0.5La2O3-2SrO-0.5Al2O3 Phosphors with SrF2

2016 ◽  
Vol 680 ◽  
pp. 228-232
Author(s):  
Xi Guang Gu ◽  
Ren Li Fu ◽  
Ye Tang ◽  
Fang Yang
Keyword(s):  
Solid State ◽  
White Light ◽  
Solid State Reaction ◽  
Emission Intensity ◽  
Solid State Reaction Method ◽  
Conventional Solid State Reaction ◽  
Light Emitting ◽  
Reaction Method ◽  
Reducing Atmosphere ◽  
White Light Emitting Diodes

Ce3+-doped 0.5La2O3-2SrO-0.5Al2O3 (LSA:Ce) phosphors had been successfully synthesized using a conventional solid-state reaction method under reducing atmosphere (H2/N2 =1/5). The phase, morphologies and luminescence properties of the LSA:Ce phosphors were investigated. The emission intensity of LSA:Ce phosphors was improved by the addition of SrF2 as flux, and red shift of PL spectra peak was observed in this phosphors. Research results shown that the LSA:Ce phosphors have the potential to meet the development of white light-emitting diodes.

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