Ni, NiSi2 and Si Secondary Ohmic Contacts on SiC with High Thermal Stability

2013 ◽  
Vol 740-742 ◽  
pp. 797-800 ◽  
Author(s):  
Stanislav Cichoň ◽  
Petr Macháč ◽  
Jiří Vojtík

A method for formation of enhanced ohmic contacts on SiC for operation under adverse conditions has been studied. Ni, NiSi2 and Si ohmic contacts were prepared and tested at 300°C on air for hundreds of hours. NiSi2 and Si showed high thermal stability. Moreover, also the so called secondary contacts showed preserved good electrical and structural properties in the thermal test. The secondary ohmic contacts are formed from original ohmic contacts after they are etched off and replaced with new ones. Secondary ohmic contacts originate in a certain surface modification of the SiC substrate created during high temperature annealing of the original contact. All applied contact materials enable formation of quality secondary contacts which is especially noteworthy at NiSi2 and Si. The results bring new SiC device design perspectives with the application of secondary ohmic contacts. For example, the contact is designed so that the primary contact makes as good ohmic behavior as possible with the secondary contact providing further important contact properties as high corrosion resistance, wire-bonding simplicity etc.

1996 ◽  
Vol 448 ◽  
Author(s):  
Serge Oktyabrsky ◽  
M.A. Borek ◽  
M.O. Aboelfotoh ◽  
J. Narayan

AbstractChemistry and interfacial reactions of the Cu-Ge alloyed ohmic contacts to n-GaAs with extremely low specific contact resistivity (6.5×10-7 Ω·cm2 for n~1017 cm-3) have been investigated by transmission electron microscopy, EDX and SIMS. Unique properties of the contact layers are related to the formation (at Ge concentration above 15 at.%) of a polycrystalline layer of ordered orthorhombic ε1-Cu3Ge phase. Formation of the ε1-phase is believed to be responsible for high thermal stability, interface sharpness and uniform chemical composition. The results suggest that the formation of the ζ- and ε1,-Cu3Ge phases creates a highly Ge-doped n+-GaAs interfacial layer which provides the low contact resistivity. Layers with Ge deficiency to form ζ-phase show nonuniform intermediate layer of hexagonal β-Cu3As phase which grows epitaxially on Ga{111} planes of GaAs. In this case, released Ga diffuses out and dissolves in the alloyed layer stabilizing the ζ-phase which is formed in the structures with average Ge concentration of as low as 5 at.%. These layers also exhibit ohmic behavior.


2003 ◽  
Vol 44 (11) ◽  
pp. 2322-2325 ◽  
Author(s):  
Tao Zhang ◽  
Shujie Pang ◽  
Katsuhiko Asami ◽  
Akihisa Inoue

1992 ◽  
Vol 260 ◽  
Author(s):  
Ping Jian ◽  
Douglas G. Ivey ◽  
Robert Bruce ◽  
Gordon Knight

ABSTRACTOhmic contact formation and thermal stability in a Au/Ge/Pd metallization to n-type InP, doped to a level of 1017 cm-3, have been investigated. Contact resistance was measured using a transmission line method, while microstructural changes were examined by means of TEM, EDX, CBED and SAD. Contacts became ohmic after annealing at temperatures ranging from 300°C to 375°C. A minimum contact resistance of 2.5×l0-6 Ω-cm2 was obtained after annealing at 350°C for 320s. The drop in resistance to ohmic behavior corresponded to the decomposition of an epitaxial quaternary phase (Au-Ge-Pd-P). Annealing at 400°C and above resulted in Au10In3 spiking into InP and a break down of contact lateral uniformity, which increased contact resistance.


2019 ◽  
Vol 481 ◽  
pp. 1148-1153
Author(s):  
Yafeng Zhu ◽  
Rong Huang ◽  
Zhengcheng Li ◽  
Hui Hao ◽  
Yuxin An ◽  
...  

Author(s):  
Sheng-Chieh Lin ◽  
Yu-Chieh Cheng ◽  
Man-Kit Leung ◽  
Jiun-Haw Lee ◽  
Tien-Lung Chiu

2011 ◽  
Vol 11 (5) ◽  
pp. 4639-4643 ◽  
Author(s):  
Chang-Hun Seok ◽  
Young-Il Park ◽  
Soo-Kang Kim ◽  
Ji-Hoon Lee ◽  
Jongwook Park

2019 ◽  
Vol 17 (1) ◽  
pp. 1080-1086
Author(s):  
Elżbieta Chmiel-Szukiewicz

AbstractSyntheses of oligoetherols with a 1,3-pyrimidine ring and boron atoms using 6-aminouracil, ethylene carbonate and boric acid has been proposed. The structure of the obtained products were determined by instrumental methods (IR, 1H-NMR and MALDI-ToF spectra). The physicochemical and thermal properties of oligoetherols were examined. The products were characterized by high thermal stability. Based on the tests performed, it was found that oligoetherols obtained from 6-aminouracil, boric acid and ethylene carbonate are suitable for the manufacturing of polyurethane foams with improved thermal stability and reduced flammability.


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