Organofilization of Smectite Clay from Pedra Lavrada, PB, with Nonionic Surfactant

2014 ◽  
Vol 805 ◽  
pp. 480-485
Author(s):  
Isabelle Albuquerque Silva ◽  
Alexsandra Cristina Chaves ◽  
Julliana Marques Rocha Figueirêdo ◽  
Carla Dantas Silva ◽  
Gelmires Araújo Neves ◽  
...  
Keyword(s):  
Nonionic Surfactant ◽  
Rheological Properties ◽  
Petroleum Industry ◽  
Oil Wells ◽  
Drilling Fluids ◽  
X Ray Diffraction ◽  
Smectite Clay ◽  
X Ray ◽  
Water Based ◽  
Mineral Production

The petroleum industry has been investing for many years in the use of smectite as dispersant agent in the composition of oil-based and water-based fluids for drilling oil wells. The State of Paraíba is one of the largest producers of such clays and new deposits have been recently discovered in the regions of Cubati and Pedra Lavrada, causing many expectations for the expansion of the national mineral production. The objective of the present work is the organofilization of smectite clay from Pedra Lavrada, PB, through the addition of nonionic surfactant. After organofilization, the clay was characterized through X-ray diffraction and Foster swelling, so that the most suitable surfactant could be chosen for diesel as organic dispersant media. The results show that the incorporation of the surfactant used with the clay caused a significant increase in the interlamellar distance, and that the dispersions presented rheological properties that meet Petrobras' specifications for the use of organoclays in non aqueous based drilling fluids. Keywords: Smectite, drilling fluids, organofilization.

Purification of Bentonite Clays from the District of Cubati, PB, for Obtainment of Organoclays for Use in Drilling Fluids

2012 ◽  
Vol 727-728 ◽  
pp. 1444-1450
Author(s):  
J.M.R. de Figueirêdo ◽  
Carla Dantas da Silva ◽  
Isabelle Albuquerque da Silva ◽  
Heber Sivini Ferreira ◽  
Gelmires Araújo Neves ◽  
...  
Keyword(s):  
Petroleum Industry ◽  
Diesel Oil ◽  
The State ◽  
Drilling Fluids ◽  
X Ray Diffraction ◽  
X Ray ◽  
Granulometric Analysis ◽  
Dta Analysis ◽  
Bentonite Clays

The main deposits of bentonite clays are located in the district of Boa Vista, in the State of Paraiba, Brazil. The random exploration of these deposits for many years is causing the clays to be depleted, and this will turn into a serious problem to the national petroleum industry. So, this work aims to study the characterization of new deposits of bentonite clays in the district of Cubati, in the State of Paraiba, Brazil, with the objective of developing purified organoclays, using a hydrocyclone, from ionic and non-ionic surfactants for use in drilling fluids. The characterization of the studied clay samples was done by applying the following techniques: granulometric analysis by laser diffraction (GA), X-ray diffraction (XRD) and chemical analysis by X-ray fluorescence (EDX) and thermogravimetric (TGA) and differential thermogravimetric (DTA) analysis. The characterization is typical of bentonites and the dispersions present rheological properties which meet Petrobras’ specifications for diesel oil media, organofilized with Praepagen WB.

scholarly journals Influence of the purification of bentonite clay from new deposits in the state of Paraíba-Brazil for use in water-based drilling fluids

Cerâmica ◽  
2018 ◽  
Vol 64 (372) ◽  
pp. 538-546 ◽  
Author(s):  
I. D. S. Pereira ◽  
V. C. Silva ◽  
J. F. Duarte Neto ◽  
G. A. Neves ◽  
H. C. Ferreira ◽  
...  
Keyword(s):  
Bentonite Clay ◽  
Exchange Capacity ◽  
The State ◽  
Drilling Fluids ◽  
Purification Process ◽  
X Ray Diffraction ◽  
Fluid System ◽  
X Ray ◽  
Water Based ◽  
Filtration Properties

Abstract Bentonite clay is used all around the world as an additive in drilling fluids. However, impurities present in this material can compromise the compatibility of the clay-fluid system. The present study aimed to analyze the effects of the purification of bentonite samples from new deposits in the state of Paraíba, Brazil, in order to make them usable in water-based drilling fluids. The samples were first purified by centrifugation, and their characteristics were determined using the following techniques: laser granulometry, X-ray diffraction, chemical analysis, cation exchange capacity, thermogravimetric analysis, and differential thermal analysis. After these determinations, the polycationic clay samples were made sodic through the addition of sodium carbonate (Na2CO3) in the proportion of 125 meq/100 g of dry clay. The rheological and filtration properties (apparent viscosity, plastic viscosity, and filtrate volume) were then tested. The results showed that the purification process was efficient for removing accessory minerals such as quartz, iron, and carbonates. With regard to rheological and filtration properties, the results following centrifugation showed that the material can be suitable for use in water-based drilling fluids.

Development of Organoclays for Use in Oil-Based Drilling Fluids

2012 ◽  
Vol 727-728 ◽  
pp. 1557-1562 ◽  
Author(s):  
Mirtys Allamana Ferreira Cardoso ◽  
Heber Sivini Ferreira ◽  
Isabelle Albuquerque da Silva ◽  
Heber Carlos Ferreira ◽  
Gelmires Araújo Neves
Keyword(s):  
Aqueous Solution ◽  
Apparent Viscosity ◽  
Bentonite Clay ◽  
Oil Wells ◽  
Ionic Surfactants ◽  
Organic Layer ◽  
Drilling Fluids ◽  
X Ray Diffraction ◽  
X Ray ◽  
Bentonite Clays

The organoclays are derived from bentonite clays treated in aqueous solution with surfactants, which are incorporated into the interlayer surface of clays, covering them with an organic layer; so, the naturally hydrophilic clay becomes hydrophobic. This paper proposes a study to find the dispersant media (diesel, paraffin or ester) which is more suitable for use in fluids, using the bentonite clay Cloisite Na +, treated with ionic surfactants Praepagen HY and Praepagen WB. The organoclay obtained was characterized by X-ray diffraction, and we measured the apparent viscosity and plastic dispersions. We observed the importance of the type of surfactant and dispersant amid to obtain organoclays for non-aqueous drilling fluids with the dispersants that meet existing specifications for drilling oil wells.

scholarly journals Investigation of regulating rheological properties of water-based drilling fluids by ultrasound

2021 ◽  
Author(s):  
Wei-An Huang ◽  
Jing-Wen Wang ◽  
Ming Lei ◽  
Gong-Rang Li ◽  
Zhi-Feng Duan ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Drilling Fluids ◽  
Water Based

Annular Frictional Pressure Losses During Drilling—Predicting the Effect of Drillstring Rotation

2014 ◽  
Vol 136 (3) ◽  
Author(s):  
Arild Saasen
Keyword(s):  
Rheological Properties ◽  
Pressure Loss ◽  
Drilling Fluid ◽  
Axial Flow ◽  
Drilling Fluids ◽  
Unstable Flow ◽  
Pressure Losses ◽  
Shear Dependent Viscosity ◽  
Water Based ◽  
Dependent Viscosity

Controlling the annular frictional pressure losses is important in order to drill safely with overpressure without fracturing the formation. To predict these pressure losses, however, is not straightforward. First of all, the pressure losses depend on the annulus eccentricity. Moving the drillstring to the wall generates a wider flow channel in part of the annulus which reduces the frictional pressure losses significantly. The drillstring motion itself also affects the pressure loss significantly. The drillstring rotation, even for fairly small rotation rates, creates unstable flow and sometimes turbulence in the annulus even without axial flow. Transversal motion of the drillstring creates vortices that destabilize the flow. Consequently, the annular frictional pressure loss is increased even though the drilling fluid becomes thinner because of added shear rate. Naturally, the rheological properties of the drilling fluid play an important role. These rheological properties include more properties than the viscosity as measured by API procedures. It is impossible to use the same frictional pressure loss model for water based and oil based drilling fluids even if their viscosity profile is equal because of the different ways these fluids build viscosity. Water based drilling fluids are normally constructed as a polymer solution while the oil based are combinations of emulsions and dispersions. Furthermore, within both water based and oil based drilling fluids there are functional differences. These differences may be sufficiently large to require different models for two water based drilling fluids built with different types of polymers. In addition to these phenomena washouts and tool joints will create localised pressure losses. These localised pressure losses will again be coupled with the rheological properties of the drilling fluids. In this paper, all the above mentioned phenomena and their consequences for annular pressure losses will be discussed in detail. North Sea field data is used as an example. It is not straightforward to build general annular pressure loss models. This argument is based on flow stability analysis and the consequences of using drilling fluids with different rheological properties. These different rheological properties include shear dependent viscosity, elongational viscosity and other viscoelastic properties.

scholarly journals Studies of new occurrences of bentonite clays in the State of Paraíba for use in water based drilling fluids

2013 ◽  
Vol 66 (4) ◽  
pp. 485-491 ◽  
Author(s):  
Isabelle A. Silva ◽  
Julliana Marques R. Costa ◽  
Romualdo R. Menezes ◽  
Heber S. Ferreira ◽  
Gelmires de A. Neves ◽  
...  
Keyword(s):  
Bentonite Clay ◽  
Particle Size Analysis ◽  
The State ◽  
Size Analysis ◽  
Drilling Fluids ◽  
X Ray ◽  
Clay Deposits ◽  
Water Based ◽  
Bentonite Clays ◽  
New Occurrences

New bentonite clay deposits have recently been discovered in the state of Paraíba, mainly in the municipalities of Cubati and Pedra Lavrada, creating great expectations in view of the possibility of expanding industrial production using these new reserves. The aim of this study was to study the new occurrences of bentonite clay in Paraíba, particularly in the municipality of Pedra Lavrada, for use in water based drilling fluids. The mineralogical properties of the clays were characterized by particle size analysis using laser diffraction, and thermogravimetric and differential thermal analysis, and its chemical composition was analyzed by X-ray fluorescence, X-ray diffraction, cation exchange capacity and specific surface area. The bentonite clays were treated with sodium carbonate at concentrations of 75, 100, 125, 150 and 175mEq/100g of dry clay, to transform them from polycationic to sodium form. For the technological characterization, drilling fluids were prepared according to the standards of Petrobras. The results indicated that the mineralogical composition of the samples consisted of montmorillonite, kaolinite and quartz. As for their rheological properties, the samples were found to partially meet the rheological requirements of the Petrobras standard.

Method and Mechanism of Regulating Rheological Properties of Water-Based Drilling Fluid by High-Frequency and High-Voltage Alternating Current Electric Field

SPE Journal ◽  
2020 ◽  
Vol 25 (05) ◽  
pp. 2220-2233
Author(s):  
Weian Huang ◽  
Ming Lei ◽  
Jingwen Wang ◽  
Kaihe Lv ◽  
Lin Jiang ◽  
...  
Keyword(s):  
Electric Field ◽  
Rheological Properties ◽  
High Voltage ◽  
High Frequency ◽  
Pulse Width ◽  
Drilling Fluid ◽  
Width Ratio ◽  
Drilling Fluids ◽  
Water Based ◽  
Bentonite Suspension

Summary The rheology of drilling fluid is commonly regulated by chemical methods. In this work, a physical method of a high-frequency and high-voltage alternating current (AC) electric field to regulate the rheological properties of water-based drilling fluid is established. The effects of the electric field on the continuous phase and dispersed phase, as well as two kinds of water-based drilling fluids, were investigated, and the response relationship among rheological properties modeled by Bingham and Herschel-Bulkley (H-B) models and electric-field parameters was explored. Results showed that water conductivity increased when voltage reached 4 kV, whereas it was restored to the original state after 3 hours in the absence of an electric field, showing a memory effect. The effect was also observed on bentonite suspension, whose plastic viscosity increased with the aid of an electric field and decreased over time. Voltage showed the greatest effect on bentonite-suspension viscosity, followed by frequency and pulse-width ratio. Under the condition of voltage of 5 kV, frequency of 5 kHz, and pulse-width ratio of 80%, there was a maximum increase of 50% in viscosity. The addition of salts caused bentonite-suspension flocculation, and electric field reduced the consistency coefficient and relieved flocculation state. When polymers were incorporated in bentonite suspension, the electric field could decrease the adsorption amount between clay particles and polymeric additives such as amphoteric and acrylamide-based polymers. For two typical drilling fluids, the voltage of an introduced electric field was the main controlling factor to change the rheological properties; their plastic viscosity and consistency coefficient both started to increase when voltage reached 4 kV.

Physico-Mineralogical Characterization: Bentonitic Clays Recently Found in Olivedos, Paraíba, Brazil

2015 ◽  
Vol 820 ◽  
pp. 56-59
Author(s):  
F.K.A. Sousa ◽  
I.A. Silva ◽  
W.S. Cavalcanti ◽  
Gelmires Araújo Neves ◽  
Heber Carlos Ferreira
Keyword(s):  
Cation Exchange Capacity ◽  
Petroleum Industry ◽  
Specific Area ◽  
Exchange Capacity ◽  
X Ray Diffraction ◽  
Mineralogical Characterization ◽  
X Ray ◽  
Petroleum Wells ◽  
The Town

Used in various branches of the industry, bentonitic clays are considered a valuable mineral, used specially in the petroleum industry for manufacturing of fluids used the drilling of petroleum wells in long depth. Recently, a deposit of this valuable mineral was discovered in the town of Olivedos-PB. There are data that prove that this is a very poor and underdeveloped town. So, this work aims at the physico-mineralogical characterization of clays recently discovered and, this way, verify if they present similar characteristics which allow them to replace the clays from Boa Vista-PB, and if they can be used by the industry, thus bringing social development for that town. The characterization was made by means of the analysis of chemical composition by X-ray fluorescence (EDX), thermogravimetric and thermal differential analyses (TG and DTA), X-ray diffraction (XRD), cation-exchange capacity (CEC) and specific area (SA). The results show that the clays recently discovered in Olivedos-PB are polycationic clays, presenting MgO, CaO and K2O content, and that they are constituted by smectitic clay mineral, by quartz and kaolinite.

Development and Characterization of Cementing Composites with Blast Furnace Slag Replacement

2014 ◽  
Vol 976 ◽  
pp. 246-250
Author(s):  
Reyna Sánchez-Ramírez ◽  
Manuela Diaz-Cruz ◽  
Sebastían Díaz de La Torre ◽  
Enrique Rocha-Rangel
Keyword(s):  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Bending Strength ◽  
Isothermal Calorimetry ◽  
Oil Wells ◽  
X Ray Diffraction ◽  
Hydration Kinetics ◽  
X Ray ◽  
Furnace Slag

In this work, they were produced and characterized cementing composites made with blast furnace slag replacement, for their use in the construction of oil wells. To this, slurries were prepared with a replacement of 20 and 30% slag, as well as a slurry with 100 % slag and a slurry with 100% H-cement were prepared. Starting materials were characterized by chemical analysis, X-ray diffraction and Fourier Transformed Infra Red. Slurries also were activated with sodium silicate in order to study theirs hydration kinetics, driving by isothermal calorimetry. These studies were complemented by the preparation of specimens of 4 X 4 X 16 cm to which they determine its compressive and bending strength during 2 and 28 days of curing. From the results it can be concluded that it was obtained a product that can be effectively used in the construction of oil wells.

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