Synthesis of Porous Anodic Alumina (PAA) on Aluminum Alloy AA6061 in Mixture of Phosphoric Acid and Oxalic Acid
In this study, porous anodic alumina was formed on aluminum alloy AA6061 by anodizing using mixture of 0.3 M oxalic acid and phosphoric acid with concentration ranged from 0.1 M to 1.0 M. AA6061 alloys were anodized at 40 V and 25°C for 60 minutes. FESEM images show that the uniformity of the pores arrangement of porous anodic alumina decreased with the increasing concentration of phosphoric acid in the electrolyte. Well-ordered porous anodic alumina was formed in mixture of 0.3 M oxalic acid and 0.1 M phosphoric acid while disordered porous anodic alumina were formed when the concentration of phosphoric acid were in the range of 0.3 M to 1.0 M. Pore size and interpore distance were found to increase with the concentration of phosphoric acid in the mixture. X-ray diffraction patterns show that to γ-Al2O3 were formed on the surface of AA6061 after the anodizing process, regardless of the concentration of phosphoric acid in the mixture electrolyte.