The Study on Tuning Photoluminescence of Colloidal Graphene Quantum Dots Synthesized through Laser Ablation

2019 ◽  
Vol 966 ◽  
pp. 3-7
Author(s):  
Fiqhri Heda Murdaka ◽  
Agustinus Agung Nugroho ◽  
Ahmad Kusumaatmaja ◽  
Isnaeni ◽  
Iman Santoso

We report photoluminescence study of Colloidal Graphene Quantum Dots (GQDs) that synthesized from ablation of rGO solution. The rGO solution was ablated using 800 nm Ti-Sapphire femtosecond laser by varying the synthesize parameters such as laser power and ablation time. We observed that changing laser power 1 Watt to become 1.7 Watt and time ablation 20 minutes to become 60 minuteswill alterate the Photoluminescence (PL) curve peak of GQDs. In case of ablation power variation, PL data shows that the PL curve peak excited by 280 nm laser changed from 369.09 nm to 371.02 nm, and when it excited by 290 nm the PL curve peak slightly changed from 388.17 nm to 393.8 nm. The alteration of Photoluminescence peak is also observed in the variation of time ablation experiment, The PL curve peaks from GQDs time ablation variation samples excited by 280 nm were slightly changed from 376.81 nm to 373.59 nm, and when it excited by 290 nm laser, the PL curve peak is 391.55 nm then changed to 392.11. The change of PL peak on laser power or time ablation variation shows that both parameters will alter either the size, shape, or the edge-type of GQDs.

2021 ◽  
Author(s):  
Li Shen ◽  
Sikun Zhou ◽  
Fei Huang ◽  
Hao Zhou ◽  
Hong Zhang ◽  
...  

Abstract In this work, graphene quantum dots (GQDs) synthesized by femtosecond laser ablation in liquid (LAL) using laser-induced graphene (LIG) as the carbon source. Nitrogen-doped graphene quantum dots (N-GQDs) were successfully synthesized by adding ammonia water to the graphene suspension. The GQDs/N-GQDs structure consist of a graphitic core with oxygen and nitrogen functionalities and particle size less than 10 nm, as demonstrated by X-ray photoelectron spectroscopy, Fourier infrared spectrometer spectroscopy and transmission electron microscopy. The absorption peak and PL spectrum and quantum yield of the N-GQDs were significantly enhanced compared with the undoped GQDs. Further, the possible mechanism of synthesis GQDs is discussed. Furthermore, the N-GQDs were used as a fluorescent probe for detection of Fe3+ ions. The N-GQDs may extend the application of graphene-based materials to bioimaging, sensor and, photoelectronic.


Nanoscale ◽  
2016 ◽  
Vol 8 (16) ◽  
pp. 8863-8877 ◽  
Author(s):  
Paola Russo ◽  
Robert Liang ◽  
Elahe Jabari ◽  
Ehsan Marzbanrad ◽  
Ehsan Toyserkani ◽  
...  

2017 ◽  
Vol 19 (33) ◽  
pp. 22395-22400 ◽  
Author(s):  
S. R. M. Santiago ◽  
T. N. Lin ◽  
C. H. Chang ◽  
Y. A. Wong ◽  
C. A. J. Lin ◽  
...  

We report a facile, fast, and one-step approach to prepare N-doped graphene quantum dots (GQDs) using pulsed laser ablation with diethylenetriamine (DETA).


2020 ◽  
Vol 58 (11) ◽  
pp. 808-814
Author(s):  
Jung-Il Lee ◽  
Jeong Ho Ryu

Graphene oxide quantum dots (GOQDs) are nanometer-sized graphene oxide fragments that exhibit unique properties, making them interesting candidates for a range of new applications. Carbon black, one of the commercially available carbon precursors, is produced by the thermal decomposition or incomplete combustion of organic compounds. It is commonly used as a supporting material for catalysts because of its excellent electrical conductivity, high surface area, and stability. In this paper, we report the transformation of carbon black into GOQDs in 10 min using a one-step facile approach. This transformation was achieved by pulsed laser ablation (PLA) in ethanol using the earth-abundant and low-cost carbon black as precursor. Only ethanol and carbon black were used for the transformation. The carbon clusters ablated from the carbon black were completely transformed into GOQDs with a homogeneous size distribution and heights in the range of 0.3-1.7 nm. This confirmed that the transformed GOQDs consisted of only single- or few-layered graphene quantum dots. The UV-vis spectra showed absorption bands at 215, 260, and 320 nm, which were attributed to the π→π* transition of the C=C of the sp<sup>2</sup> C bond in the sp<sup>3</sup> C matrix. A distinct blue emission peak at 450 nm was evident at an excitation wavelength of 360 nm. The broader PL emission spectra are due to the oxygen-related functional groups emitting PL between 300 and 440 nm.


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