Preparation of Superhydrophobic Coatings on Filter Paper for Oil-Water Separation

2020 ◽  
Vol 978 ◽  
pp. 492-498
Author(s):  
Sangeetha Sriram ◽  
R.K. Singh ◽  
Aditya Kumar
Keyword(s):  
Filter Paper ◽  
Separation Efficiency ◽  
Impact Resistance ◽  
Industrial Applications ◽  
Water Separation ◽  
Casting Technique ◽  
Prime Concern ◽  
Oil Water Separation ◽  
Oil Water ◽  
Filter Papers

Oil-water separation has become the prime concern for fossil fuel exploration industries. In the present study, superhydrophobic coating on filter paper was prepared to repellent water while allowing oil to flow freely from its porous structures. Coating was generated by solution-casting technique on cellulosic filter paper using silica nanoparticles (SiO2) along with silane coupler hexadecyltrimethoxysilane (HDTMS). The contact angle was measured, and it has shown 175.1° ± 1.5°, and the tilting angle is 1.5° ± 0.2°. The surface topography of coated and treated samples was also examined. Furthermore, thermal stability of fabricated filter papers was evaluated by annealing at a different range of temperatures (20 °C-220 °C). The pH resistance of the coatings were inspected by immersing the specimens in acidic and alkali solutions (pH 2-13). The mechanical durability was examined by tape-peeling and abrasion tests. Moreover, these samples have shown waterjet impact resistance. Filtration study was performed on coated filter papers using various oil-water mixtures of kerosene-water and petroleum ether-water and results have shown the separation efficiency of 99% and 98.5%, respectively. Thus these filter papers can have potential practical and industrial applications.

Facile fabrication of superhydrophobic filter paper with improved durability and water repellency

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Lizheng Sha ◽  
Chao Ma ◽  
Huifang Zhao ◽  
Supeng Qiu ◽  
Zhongyu Yan ◽  
...  
Keyword(s):  
Filter Paper ◽  
Separation Efficiency ◽  
Cellulose Nanofibrils ◽  
Water Repellency ◽  
Step Method ◽  
Water Contact ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water ◽  
Self Cleaning

Abstract Superhydrophobic surfaces have high potential in self-cleaning and oil-water separation applications. We developed a three-step method for the preparation of superhydrophobic filter paper. It involved citric acid (CA) pretreatment to activate cellulose fibers, coating with cellulose nanofibrils/functionalized silica (CNFs/m-SiO2) slurry to increase surface roughness, and grafting of hexadecyltrimethoxysilane (HDTMS) to enhance water resistance. The water contact angle (WCA) and siding angle (SA) of the prepared filter paper reached 151.5° and 7.5°, respectively. The results showed that, compared to the coated filter paper without the added CNFs, the coated paper with CNFs had higher retention of m-SiO2, thus roughness required for superhydrophobic surface was achieved. Further test under frequent abrasion and acid or alkali conditions showed that CA pretreatment improved the durability of superhydrophobic filter paper due to chemical crosslinking between the modified substrate and m-SiO2. Besides, the prepared superhydrophobic filter paper had outstanding self-cleaning property and high oil-water separation efficiency for various oil-water mixtures. Therefore, it is expected to be used for the treatment of oily wastewater.

An Investigation of Wavy Flow Passages on the Performance of Oil-Water Separators

2001 ◽  
Author(s):  
Michael A. Langerman ◽  
Chenoa J. Jensen
Keyword(s):  
Separation Efficiency ◽  
Continuous Phase ◽  
Industrial Applications ◽  
Spatial Density ◽  
Dispersed Phase ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water ◽  
Phase Water ◽  
Oil Particles

Abstract The purpose of this research is to analyze flow fields within channels bounded by wavy plates and assess the effects of these flow passages on the efficiency of oil-water separators. Results from this study are used to analytically assess an industry accepted result that wavy plate channel surfaces promote a more effective oil-water separation process. For this investigation, an uncoupled, two-dimensional, dispersed-phase, simulation is implemented using a commercially available computational fluid dynamics code. First, the continuous phase (water) velocity field is calculated. For comparison purposes, both fiat and wavy passages are simulated. Next, buoyant oil particles (specific gravity of 0.70 and 0.95) are superimposed as the dispersed phase at the inlet to the channel. Oil droplet diameters of 100, 200, and 300 μm, which are typical droplet diameters encountered in industrial applications, are simulated. The particle trajectories are then determined and observations made of the particle behavior near the channel walls for both channel geometries. Results show that a percentage of the particles are captured in vortices generated in the fluid within the wavy plate corrugations. As more particles are captured within these vortices, the spatial density of oil particles increases thus promoting coalescence. The coalescence results in larger oil particle diameters that, in turn, enhance separation through increased buoyancy. These results appear to substantiate industry observations regarding an increased oil-water separation efficiency using wavy channel passages. Nevertheless, more research is needed to optimize the design of the passages and better understand the coalescence phenomena.

scholarly journals High-flux underwater superoleophobic hybrid membranes for effective oil–water separation from oil-contaminated water

RSC Advances ◽  
2017 ◽  
Vol 7 (15) ◽  
pp. 9051-9056 ◽  
Author(s):  
Minxiang Zeng ◽  
Baoliang Peng ◽  
Carlos Ybanez ◽  
Nian Wei Tan ◽  
Ehab Abo Deeb ◽  
...  
Keyword(s):  
Polyvinyl Alcohol ◽  
Separation Efficiency ◽  
Contaminated Water ◽  
Hybrid Membranes ◽  
High Flux ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water ◽  
Filter Papers ◽  
Tolylene Diisocyanate

The pristine filter papers were crosslinked with polyvinyl alcohol by tolylene diisocyanate, leading to a superoleophobic surface which enables excellent oil–water separation efficiency.

scholarly journals Dodecyl Mercaptan Functionalized Copper Mesh for Water Repellence and Oil-water Separation

2021 ◽  
Vol 18 (4) ◽  
pp. 887-899
Author(s):  
Yanling Tian ◽  
Jiekai Feng ◽  
Zexin Cai ◽  
Jiaqi Chao ◽  
Dawei Zhang ◽  
...  
Keyword(s):  
Separation Efficiency ◽  
Synthesis Process ◽  
Water Separation ◽  
Oil Water Separation ◽  
One Step ◽  
Oil Water ◽  
Water Repellence ◽  
Copper Mesh ◽  
Dodecyl Mercaptan

AbstractReckless discharge of industrial wastewater and domestic sewage as well as frequent leakage of crude oil have caused serious environmental problems and posed severe threat to human survival. Various nature inspired superhy-drophobic surfaces have been successfully applied in oily water remediation. However, further improvements are still urgently needed for practical application in terms of facile synthesis process and long-term durability towards harsh environment. Herein, we propose a simple one-step dodecyl mercaptan functionalization method to fabricate Super-hydrophobic-Superoleophilic Copper Mesh (SSCM). The prepared SSCM possesses excellent water repellence and oil affinity, enabling it to successfully separate various oil-water mixtures with high separation efficiency (e.g., > 99% for hexadecane-water mixture). The SSCM retains high separating ability when hot water and strong corrosive aqueous solutions are used to simulate oil-water mixtures, indicating remarkable chemical durability of the dodecyl mercaptan functionalized copper mesh. Additionally, the efficiency can be well maintained during 50 cycles of separation, and the water repellence is even stable after storage in air for 120 days, demonstrating the reusability and long-term stability of the SSCM. Furthermore, the functionalized mesh also shows good mechanical robustness towards abrasion by sandpaper, and oil-water separation efficiency of > 96% can be obtained after 10 cycles of abrasion. The reported one-step dodecyl mercaptan functionalization could be a simple method for increasing the water repellence of copper mesh, and thereby be a great candidate for treating large-scale oily wastewater in harsh environments.

scholarly journals Fabricated of Superhydrophobic Silanized Melamine Sponge with Photochromic Properties for Efficiency Oil/Water Separation

2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Peng Hong ◽  
Zhu Liu ◽  
Yang Gao ◽  
Yubin Chen ◽  
Mingxun Zhuang ◽  
...  
Keyword(s):  
Large Scale ◽  
Separation Efficiency ◽  
Low Cost ◽  
Water Repellency ◽  
Dip Coating ◽  
Absorption Capacity ◽  
Photochromic Properties ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water

Superhydrophobic sponge as potential absorbing material for oil/water separation is attracting great attention recently. However, there are still some challenges to feasibly fabricate superhydrophobic sponge with large scale and low cost. Herein, a novel photochromic superhydrophobic melamine sponge (PDMS-SP sponge) is fabricated by facilely dip-coating and thermocuring of hydroxyl-terminated polydimethylsiloxanes mixed with photochromic spiropyran. FT-IR, EDS, and XPS results confirm the successful coating of PDMS-SP upon melamine sponge. The resultant sponge not only possesses excellent water repellency with a contact angle of 154.5° and oil-water separation efficiency with an oil absorption capacity of 48–116 folds of itself weight, but also shows photochromic phenomenon between colorless and purple when it is successively exposed to UV irradiation and visible light.

scholarly journals PP/TiO2 Melt-Blown Membranes for Oil/Water Separation and Photocatalysis: Manufacturing Techniques and Property Evaluations

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 775 ◽  
Author(s):  
Fei Sun ◽  
Ting-Ting Li ◽  
Haitao Ren ◽  
Qian Jiang ◽  
Hao-Kai Peng ◽  
...  
Keyword(s):  
Separation Efficiency ◽  
Decomposition Temperature ◽  
Particle Dispersion ◽  
Tio2 Content ◽  
Scanning Calorimetry ◽  
Water Separation ◽  
Photocatalytic Effect ◽  
Oil Water Separation ◽  
Oil Water ◽  
Manufacturing Techniques

This study aims to produce polypropylene (PP)/titanium dioxide (TiO2) melt-blown membranes for oil/water separation and photocatalysis. PP and different contents of TiO2 are melt-blended to prepare master batches using a single screw extruder. The master batches are then fabricated into PP/TiO2 melt-blown membranes. The thermal properties of the master batches are analyzed using differential scanning calorimetry and thermogravimetric analysis, and their particle dispersion and melt-blown membrane morphology are evaluated by scanning electron microscopy. TiO2 loaded on melt-blown membranes is confirmed by X-ray diffraction (XRD). The oil/water separation ability of the melt-blown membranes is evaluated to examine the influence of TiO2 content. Results show that the thermal stability and photocatalytic effect of the membranes increase with TiO2 content. TiO2 shows a good dispersion in the PP membranes. After 3 wt.% TiO2 addition, crystallinity increases by 6.4%, thermal decomposition temperature increases by 25 °C compared with pure PP membranes. The resultant PP/TiO2 melt-blown membrane has a good morphology, and better hydrophobicity even in acetone solution or 6 h ultraviolet irradiation, and a high oil flux of about 15,000 L·m−2·h−1. Moreover, the membranes have stabilized oil/water separation efficiency after being repeatedly used. The proposed melt-blown membranes are suitable for mass production for separating oil from water in massively industrial dyeing wastewater.

scholarly journals Facile Fabrication of Magnetic, Durable and Superhydrophobic Cotton for Efficient Oil/Water Separation

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 442 ◽  
Author(s):  
Mingguang Yu ◽  
Qing Wang ◽  
Wenxin Yang ◽  
Yonghang Xu ◽  
Min Zhang ◽  
...  
Keyword(s):  
Separation Efficiency ◽  
Water Repellency ◽  
Cotton Fabrics ◽  
Ammonia Solution ◽  
Hot Water ◽  
Water Contact ◽  
Water Separation ◽  
Efficient Strategy ◽  
Oil Water Separation ◽  
Oil Water

In this paper, we present a facile and efficient strategy for the fabrication of magnetic, durable, and superhydrophobic cotton for oil/water separation. The superhydrophobic cotton functionalized with Fe3O4 magnetic nanoparticles was prepared via the in situ coprecipitation of Fe2+/Fe3+ ions under ammonia solution on cotton fabrics using polyvinylpyrrolidone (PVP) as a coupling agent and hydrophobic treatment with tridecafluorooctyl triethoxysilane (FAS) in sequence. The as-prepared cotton demonstrated excellent superhydrophobicity with a water contact angle of 155.6° ± 1.2° and good magnetic responsiveness. Under the control of the external magnetic field, the cotton fabrics could be easily controlled to absorb the oil from water as oil absorbents, showing high oil/water separation efficiency, even in hot water. Moreover, the cotton demonstrated remarkable mechanical durable properties, being strongly friction-resistant against sandpaper and finger wipe, while maintaining its water repellency. This study developed a novel and efficient strategy for the construction of magnetic, durable, and superhydrophobic biomass-based adsorbent for oil/water separation, which can be easily scaled up for practical oil absorption.

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