Mechanical Properties of Superconcentrates Based on Ethylene-Vinyl Acetate Copolymer and Microcrystalline Cellulose

2020 ◽  
Vol 992 ◽  
pp. 306-310
Author(s):  
P.G. Shelenkov ◽  
P.V. Pantyukhov ◽  
A.A. Popov

In the study, highly filled superconcentrates based on various grades of ethylene-vinylacetate copolymer (EVA) and microcrystalline cellulose (MCC) were studied. It is assumed that adding superconcentrates to various polyolefins will make them biodegradable in the environment. The influence of EVA rheological characteristics and the content of vinyl acetate (VA) groups on the properties of the superconcentrates were studied. It was shown that increasing the concentration of VA groups in EVA leads to an increase in the elongation at break of the composites; increase in EVA melt flow index (MFI) greatly reduces the basic mechanical properties of the composite.

2021 ◽  
Vol 316 ◽  
pp. 159-163
Author(s):  
P.G. Shelenkov ◽  
P.V. Pantyukhov ◽  
A.A. Popov

Highly filled bio-composites based on ethylene-vinyl acetate copolymer (EVA) with cellulose and wood flour were prepared in the previous parts of the study. The aim of this work was to dilute them with a polyethylene (PE), to prepare new bio-composites with lower EVA content and to investigate the effect of EVA/PE ratio on the mechanical properties. It was shown that melt flow index (MFI) and elongation at break increased additively with an increase of EVA content in the composition, but yield strength had an inverse tendency. The obtained results are extremely useful for choosing the right composition for the industrial implementation.


2002 ◽  
Vol 10 (5) ◽  
pp. 381-390 ◽  
Author(s):  
Viviane Xavier Moreira ◽  
Bluma Guenther Soares

Rubber blends containing nitrile rubber (NBR) and ground ethylene-vinyl acetate copolymer waste (EVAW) from the footwear industry have been prepared over a wide range of composition (up to 90 phr of waste component). The ground EVAW had particle size in the range of 100-350 mm and a gel content of 60±5%. The effect of different amounts of EVA waste on the tensile strength, elongation at break, hardness, tear strength and dynamic mechanical properties was studied. EVAW had a good reinforcing effect on the NBR matrix. A combination of optimum tensile properties, resistance to solvent penetration and dynamic mechanical properties, such as storage modulus and loss tangent was achieved by introducing 50 phr of EVAW in the NBR matrix. This composition also presents a more uniform morphology, as indicated by scanning electron microscopy.


2017 ◽  
Vol 25 (2) ◽  
pp. 355-361
Author(s):  
Thai Hoang ◽  
Do Van Cong

Composites based on polyethylene grafted acrylic acid (PE-g-AAc)/ethylene-co-vinylacetate copolymer (EVA)/calcium carbonate (CaCO3) were prepared by melt mixing. Relative melt viscosity, morphology, mechanical properties and thermostability of the composites were studied. The experimental results show that the presence of (CaCO3) activated by stearic acid (10-20 wt.%) changes lightly stable torque of polymer blend of PE-g-AAc/EVA. Use of modified PE improves compatibility of PE and EVA as well as makes the components disperse into each other better than in blends using unmodified PE. Tensile strength and elongation at break of both polymer blends decrease with presence of CaCO3. However, tensile strength of the composites of PE-g-AAc/EVA/CaCO3 is higher than that of composites of PE/EVA/CaCO3. Beside that, the composites of PE-g-AAc/EVA/CaCO3 have thermostability higher than the composites of PE/EVA/CaCO3.  


Materials ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 4669
Author(s):  
Łukasz Zedler ◽  
Paulina Burger ◽  
Shifeng Wang ◽  
Krzysztof Formela

Ground tire rubber (GTR) was reclaimed and modified with 10 phr of ethylene-vinyl acetate copolymer via low-temperature extrusion process. Processing, physico-mechanical properties, volatile organic compounds emission, and recycling possibility were investigated. In order to better understand the impact of used modifiers, their efficiency was compared with trans-polyoctenamer, which is an additive that is commercially dedicated to waste rubber recycling. The results showed that a relatively small amount of ethylene-vinyl acetate copolymer improves the mechanical properties of modified reclaimed GTR and also allows further recycling by multiple processing without the deterioration of performance after three cycles.


2020 ◽  
Vol 869 ◽  
pp. 76-81
Author(s):  
Vu Minh Trong ◽  
Bui Dinh Hoan

The fly ash from Pha Lai power plant was modified by vinyltrimetoxysilan (VTMS). The polymer composites based on low-density polyethylene (LDPE), ethylene vinyl acetate copolymer (EVA) and fly ash (FA) without and with vinyltrimetoxysilan (VTMS) modification were prepared by melt mixing in a Haake Rheomixer. The tensile strength and elongation at break of the LDPE/EVA/VFA composites were also higher than those of the LDPE/EVA/FA composites. The FESEM images proved that FA-VTMS particles disperse more regularly in the polymer matrix in comparison with FA without VTMS modification. In addition, the surface modification of the FA reduced the size of agglomeration of FA particles.


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