Protective Coating Based on Organic Silicon Polymer of Ladder Structure Nanostructured with Alkoxysilane

2020 ◽  
Vol 992 ◽  
pp. 580-584
Author(s):  
V.Yu. Chukhlanov ◽  
O.G. Selivanov ◽  
N.V. Chukhlanova
Keyword(s):  
Atomic Force Microscopy ◽  
Physical Properties ◽  
Protective Coating ◽  
Silicon Oxide ◽  
Polymer Composition ◽  
Orthosilicic Acid ◽  
Force Microscopy ◽  
Atomic Force ◽  
Destruction Kinetics ◽  
The Impact

New materials based on oligooxidridsilmethylensiloxysilane nanostructured with ethyl ester of orthosilicic acid – tetraethoxysilane have been studied in the research. Tetraethoxysilane introduction into the composition is supposed to cause its decomposition up to nanoparticles of silicon oxide. The alkoxysilane hydrolytic destruction kinetics and the impact of the composition and nature of the polymer composition components on the physical properties have been studied. Atomic force microscopy was used to study the structurization kinetics of the polymer composition. The composition hydrophobicity was determined by the edge wetting angle. To study the adhesion characteristics of the obtained material, the method of disc separation from the substrate has been used. The relative rigidity has been determined by a pendulum device M3. Atomic force microscopy revealed the presence of nanoscale neoplasms (at average of one hundred twenty per one square micrometer) in diameter from two to five nanometers in the surface structure of the composition, modified with tetraethoxysilane. Herewith the physical properties of the material change: rigidity increases, the edge angle of wetting increases as well. The studied nanostructured compositions can also be applied. For example – they can be used as a protective coating with a set of special properties, such as high hydrophobicity.

In Operando Detection of the Physical Properties Change of the Interfacial Electrolyte during Li-Metal Electrode Reaction by Atomic Force Microscopy

2020 ◽  
Author(s):  
Mitsunori Kitta
Keyword(s):  
Atomic Force Microscopy ◽  
Energy Dissipation ◽  
Physical Properties ◽  
Electrode Surface ◽  
Electrode Reaction ◽  
Metal Electrode ◽  
Ion Concentration ◽  
Force Microscopy ◽  
Atomic Force ◽  
Discharge Reaction

This manuscript propose the operando detection technique of the physical properties change of electrolyte during Li-metal battery operation.The physical properties of electrolyte solution such as viscosity (η) and mass densities (ρ) highly affect the feature of electrochemical Li-metal deposition on the Li-metal electrode surface. Therefore, the operando technique for detection these properties change near the electrode surface is highly needed to investigate the true reaction of Li-metal electrode. Here, this study proved that one of the atomic force microscopy based analysis, energy dissipation analysis of cantilever during force curve motion, was really promising for the direct investigation of that. The solution drag of electrolyte, which is controlled by the physical properties, is directly concern the energy dissipation of cantilever motion. In the experiment, increasing the energy dissipation was really observed during the Li-metal dissolution (discharge) reaction, understanding as the increment of η and ρ of electrolyte via increasing of Li-ion concentration. Further, the dissipation energy change was well synchronized to the charge-discharge reaction of Li-metal electrode.This study is the first report for direct observation of the physical properties change of electrolyte on Li-metal electrode reaction, and proposed technique should be widely interesting to the basic interfacial electrochemistry, fundamental researches of solid-liquid interface, as well as the battery researches.

scholarly journals Characterisation of InGaN by Photoconductive Atomic Force Microscopy

Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1794 ◽  
Author(s):  
Thomas Weatherley ◽  
Fabien Massabuau ◽  
Menno Kappers ◽  
Rachel Oliver
Keyword(s):  
Atomic Force Microscopy ◽  
Cross Sections ◽  
Indium Content ◽  
Light Emitting ◽  
Force Microscopy ◽  
Turn On ◽  
Atomic Force ◽  
Voltage Curve ◽  
Current Voltage Curve ◽  
The Impact

Nanoscale structure has a large effect on the optoelectronic properties of InGaN, a material vital for energy saving technologies such as light emitting diodes. Photoconductive atomic force microscopy (PC-AFM) provides a new way to investigate this effect. In this study, PC-AFM was used to characterise four thick (∼130 nm) In x Ga 1 − x N films with x = 5%, 9%, 12%, and 15%. Lower photocurrent was observed on elevated ridges around defects (such as V-pits) in the films with x ≤ 12 %. Current-voltage curve analysis using the PC-AFM setup showed that this was due to a higher turn-on voltage on these ridges compared to surrounding material. To further understand this phenomenon, V-pit cross sections from the 9% and 15% films were characterised using transmission electron microscopy in combination with energy dispersive X-ray spectroscopy. This identified a subsurface indium-deficient region surrounding the V-pit in the lower indium content film, which was not present in the 15% sample. Although this cannot directly explain the impact of ridges on turn-on voltage, it is likely to be related. Overall, the data presented here demonstrate the potential of PC-AFM in the field of III-nitride semiconductors.

Nanobubble Formation at the Solid-Liquid Interface Studied by Atomic Force Microscopy

2005 ◽  
Vol 899 ◽  
Author(s):  
Abhinandan Agrawal ◽  
Gareth H. McKinley
Keyword(s):  
Atomic Force Microscopy ◽  
Solid Surface ◽  
Silicon Oxide ◽  
Slip Length ◽  
Hydrophobic Surface ◽  
Force Microscopy ◽  
Atomic Force ◽  
Experimental Values ◽  
Solid Liquid ◽  
Wafer Surfaces

AbstractThe formation of nanobubbles at solid-liquid interfaces has been studied using the atomic force microscopy (AFM) imaging technique. Nanobubble formation strongly depends on both the hydrophobicity of the solid surface and the polarity of the liquid subphase. While nanobubbles do not form on flat hydrophilic (silicon oxide wafer) surfaces immersed in water, they appear spontaneously at the interface of water against smooth, hydrophobic (silanized wafer) surfaces. From the experimental observations we draw the conclusion that the features observed in the AFM images are deformable, air-filled bubbles. In addition to the hydrophobicity of the solid surface, differences in solubility of air between two miscible fluids can also lead to formation of nanobubbles. We observe that nanobubbles appear at the interface of water against hydrophilic silicon oxide surfaces after in-situ mixing of ethanol and water in the fluid-cell.The shapes of the nanobubbles are well approximated by spherical caps, with width much larger than the height of the caps. We quantify the morphological distribution of nanobubbles by evaluating several important bubble parameters including surface coverage and radii of curvature. In conjunction, with an analytical model available in the literature, we use this information to estimate that the present nanobubble morphology may give rise to slip lengths ∼1–2 µm in pressure driven flows for water flowing over the hydrophobic surface. The consistency of the calculated slip length with the experimental values reported in the literature, suggests that the apparent fluid slip observed experimentally at hydrophobic surfaces may arise from the presence of nanobubbles.

scholarly journals Effect of at-home bleaching with different thickeners and aging on physical properties of a nanocomposite

2016 ◽  
Vol 10 (01) ◽  
pp. 082-091 ◽  
Author(s):  
Thayla Hellen Nunes Gouveia ◽  
Juliana do Carmo Públio ◽  
Glaucia Maria Bovi Ambrosano ◽  
Luís Alexandre Maffei Sartini Paulillo ◽  
Flávio Henrique Baggio Aguiar ◽  
...  
Keyword(s):  
Atomic Force Microscopy ◽  
Physical Properties ◽  
Aging Process ◽  
Artificial Aging ◽  
Organic Matrix ◽  
Carbamide Peroxide ◽  
Treatment Control ◽  
Force Microscopy ◽  
Atomic Force ◽  
Knoop Microhardness

ABSTRACT Objective: To evaluate the influence of 16% carbamide peroxide (CP) containing different thickeners on the physical characteristics of a nanocomposite resin submitted or not to accelerated artificial aging (AAA). Materials and Methods: One hundred samples were randomly distributed into two groups (n = 50) according to AAA. Each group was divided into 5 subgroups (n = 10) depending on the bleaching/thickener treatment: CP + carbopol, CP + natrosol, carbopol, natrosol, and no treatment (control). The physical properties tested were color (ΔE), gloss (GU), mean roughness (Ra), and Knoop microhardness (KHN). The resin surface was performed with atomic force microscopy (AFM). Statistical Analysis: The color (variable Δ E) was assessed with two-way analysis of variance (ANOVA) and additionally with Tukey's and Dunnett's tests, the roughness values were submitted to Kruskal–Wallis, Dunn's, and Mann–Whitney's tests. Data on gloss and KHN were submitted to two-way ANOVA and Tukey's test (α = 0.05). Results: Among the physical properties evaluated, CP + carbopol promoted a reduction in composite microhardness only, thus differing statistically from the controls. As for CP + natrosol, such a change was not observed. The aging process reduced all the physical properties, thus differing statistically from the nonaging group. CP + carbopol increased the roughness and decreased the gloss of aged resins, whereas natrosol reduced gloss only, which differed statistically from the controls. Conclusions: AFM showed evidence of the loss of organic matrix and exposure to load particles in the aged samples. Therefore, the replacement of carbopol with natrosol provided maintenance of the composite microhardness following bleaching. The aging process reduced the physical properties evaluated, and some changes were enhanced by the application of bleaching.

Imidazolium-Based Ionic Liquids Affect Morphology and Rigidity of Living Cells: an Atomic Force Microscopy Study

2018 ◽  
Author(s):  
Massimiliano Galluzzi ◽  
Carsten Schulte ◽  
Paolo Milani ◽  
Alessandro Podestà
Keyword(s):  
Atomic Force Microscopy ◽  
Ionic Liquids ◽  
Cell Membrane ◽  
Molecular Mechanisms ◽  
Single Cells ◽  
Metastatic Cancer ◽  
Toxic Effects ◽  
Force Microscopy ◽  
Atomic Force ◽  
The Impact

The study of the toxicity, biocompatibility, and environmental sustainability of room-temperature Ionic Liquids (ILs) is still in its infancy. Understanding the impact of ILs on living organisms, especially from the aquatic ecosystem, is urgent, since on one side large amounts of these substances are widely employed as solvents in industrial chemical processes, and on the other side evidences of toxic effects of ILs on microorganisms and single cells have been observed. To date, the toxicity of ILs have been investigated by means of macroscopic assays aimed at characterizing the effective concentrations (like the EC50) that cause the dead of a significant fraction of the population of microorganisms and cells. These studies allowed to identify the cell membrane as the first target of the IL interaction, whose effectiveness was correlated to the lipophilicity of the cation, i.e. to the length of the lateral alkyl chain. Our study aimed at characterizing the molecular mechanisms of the toxicity of ILs. To this purpose, we carried out a combined topographic and mechanical analysis by Atomic Force Microscopy of living breast metastatic cancer cells (MDA-MB-231) upon interaction with imidazolium-based ILs. We showed that ILs are able to induce modifications of the overall rigidity (effective Young modulus) and morphology of the cells. Our results demonstrate that ILs act on the physical properties of the cell membrane, and possibly induce cytoskeletal reorganization, already at concentrations below the EC50. These potentially toxic effects are stronger at higher IL concentrations, as well as with longer lateral chains in the cation.<br>

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