Elastomers Containing Fillers with Magnetic Properties

2009 ◽  
Vol 154 ◽  
pp. 121-126 ◽  
Author(s):  
Marian Zaborski ◽  
Joanna Pietrasik ◽  
Marcin Masłowski

Composites of rubbers such as ethylene – propylene and acrylonitrile – butadiene with micro size Fe¬3O4, Fe2O3, and nano size Fe3O4 as the fillers were tested. Iron oxides were found to be active fillers which improved mechanical properties of elastomers. Additionally, they also changed their magnetic properties. Furthermore, the surface of micro size Fe3O4 was modified to upgrade mechanical properties of the vulcanizates. Itaconic acid, methacryloxypropyltrimethoxysilane and monododecyl maleate were used as modifying agents. To improve dispersion of applied fillers in polymers matrix, non-ionic (NF-PEG), anionic (calcium stearate ), cationic (DTAB, DTAC, DDAB, CTAD) and ionic liquids (HMIMBF4, BMIMPF6, OMIMPF6) were used. It was observed that both non-modified and modified micro iron oxides and nano iron oxides improved the properties of the vulcanizates the most effectively.

2021 ◽  
Vol 9 (8) ◽  
pp. 4679-4686
Author(s):  
Coby J. Clarke ◽  
Richard P. Matthews ◽  
Alex P. S. Brogan ◽  
Jason P. Hallett

Gels prepared from metal containing ionic liquids with cross-linked poly(ethylene glycol) have surface compositions and mechanical properties that can be controlled by Lewis basicity and acidity of the metal species.


2006 ◽  
Vol 45 ◽  
pp. 1423-1428
Author(s):  
Somsak Woramongconchai ◽  
Chatchawan Lohitvisat ◽  
Aree Wichainchai

The effect of magnetic powders and powders loading on magnetic properties and mechanical properties of magnetic rubbers were studied. The natural rubber with magnetic powders, Barium ferrite, Neodymium iron boron, were used as starting materials to prepare magnetic rubbers. Barium ferrite (BaO.6F2O3) powders had been sintered at 1285 oC for 30 hours to improve its crystal structure. The physical properties of magnetic rubbers, residual flux density (Br), coercive force (Hc), maximum energy product (BHmax), hardness and density, had a trend to increase as enhancing magnetic powders loading. However, some properties such as, intrinsic coercive force (Hci), tensile strength and elongation at break, had a trend to decrease when the magnetic powder loading was increased. Magnetic properties of the anisotropic type, sintered powders, were higher than isotropic type, non-sintered powders, except the Hci because anisotropic magnetic rubber indicated crystal orientation in the same direction.


1990 ◽  
Vol 195 ◽  
Author(s):  
T.E. Schlesinger ◽  
A. Gavrin ◽  
R.C. Cammarata ◽  
C.-L. Chien

ABSTRACTThe mechanical properties of sputtered Ni-Al2O3 granular thin films were investigated by low load microharaness testing. It was found that the microhardness of these films displayed a percolation threshold at a nickel volume fraction of about 0.6, below which the hardness is greatly enhanced. This behavior is qualitatively similar to the electrical and magnetic properties of these types of films. A percolation threshold in hardness can be understood as due to a change in the mechanism for plastic deformation.


1999 ◽  
Vol 11 (17) ◽  
pp. L179-L185 ◽  
Author(s):  
D Kaptás ◽  
T Kemény ◽  
J Balogh ◽  
L Bujdosó ◽  
L F Kiss ◽  
...  

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