ALDICARB ON GREENHOUSE CHRYSANTHEMUMS IN ONTARIO: EFFICACY FOR CONTROL OF LIRIOMYZA TRIFOLII (BURGESS) (DIPTERA: AGROMYZIDAE) AND RESIDUES IN FOLIAGE

1986 ◽  
Vol 118 (8) ◽  
pp. 789-795 ◽  
Author(s):  
A.B. Broadbent ◽  
M. Chiba ◽  
B.D. McGarvey

AbstractIn two field tests, larvae of Liriomyza trifolii (Burgess) were not controlled by aldicarb (Temik 10G) at three times the recommended rate when applied to soil, dry foliage, or wet foliage of chrysanthemums (cv. White Marble) in Ontario. A second treatment of aldicarb 3 weeks after the first did not prevent the increase in leafmining. Assessment of the top 10 leaves at harvest showed no significant differences in numbers of mines greater than 2 cm between check and treated plots. Residues of aldicarb and its degradation compounds, aldicarb sulfoxide and aldicarb sulfone, were detected by capillary gas chromatography with thermionic specific detection. Substantial residues (> 100 μg/g as total residues), particularly of aldicarb sulfoxide, were found within the 1st week after treatment, but dissipated rapidly in upper leaves by day 7 after the first aldicarb application. Lower leaves, however, maintained residue levels at a constant level for a 3-week period following the first and second applications. Residue levels on lower leaves were consistently higher after wet-foliage application of aldicarb than after soil application.

1980 ◽  
Vol 35 (1-2) ◽  
pp. 45-48 ◽  
Author(s):  
D. L. Struble ◽  
H. Arn ◽  
H. R. Buser ◽  
E. Städler ◽  
J. Freuler

Abstract Evidence obtained by glass capillary gas chromatography coupled to an electroantennographic detector or a mass spectrometer confirmed that Z-11-hexadecenyl acetate is the major component in the pheromone gland washes of calling Mamestra brassicae female moths. Three other components were identified, tetradecanyl acetate, hexadecanyl acetate and E-11-hexadecenyl acetate; but none of these had obvious synergistic effects in attracting males in field tests. The attraction of males to Z -11-hexadecenyl acetate was inhibited by 0.1% Z -11-hexadecenol or 1% Z-9- tetradecenyl acetate.


1989 ◽  
Vol 35 (4) ◽  
pp. 601-607 ◽  
Author(s):  
D Manca ◽  
L Ferron ◽  
J P Weber

Abstract Capillary gas chromatography with nitrogen-specific detection allows rapid screening of numerous drugs of toxicological interest. However, for accurate identification of individual peaks, the system must be well calibrated, e.g., through the use of retention indices (RI). To overcome problems associated with the use of RI's based on homologous series determined with nitrogen-specific detectors, we have developed an RI reference system based on molecular masses and retention times of nitrogen-containing compounds. The standards chosen are easily available in highly purified form and can be detected by the unmodified nitrogen-specific detector. By using temperature programming, we can obtain a linear relationship between the molecular masses of standards and their retention times. Used in conjunction with microcomputer data handling, this screening system is rugged and reliable, operating 22 h per day. In the past two years, we have screened greater than 3000 samples (blood, serum, urine, gastric lavage) without major problems.


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