scholarly journals Experimental Investigation of Temperature Effects on Low Salinity Enzyme Enhanced Oil Recovery Process

2020 ◽  
Vol 17 (3) ◽  
pp. 156-164
Author(s):  
Tinuola H. Udoh

In this paper, the effect of temperature on low salinity brine and combined low salinity enzyme oil recovery processes in sandstone rock sample was experimentally investigated. The core flooding displacement tests were conducted with the injection of the enzyme in post-tertiary mode after secondary high salinity brine and tertiary low salinity brine injection processes. Effluents analyses of each of the flooding were carried out and used to evaluate the effect of temperature on rock-fluid interactions and enhanced oil recovery processes. The results showed that tertiary low salinity brine injection and post-tertiary enzyme injection increased recovery by 2.4-8.72% over the secondary high salinity brine flooding at 25 oC. Also, increase in oil recovery (0.57-13.18%) was observed with increase in the system temperature from 25 oC to 70 oC. Furthermore, the effluent of the 70 oC flooding was associated with the earliest low salinity brine ionic breakthrough front at 10 injected pore volume, while the 25 oC flooding breakthrough front occurred at 22 pore volume. However, no obvious effect of temperature on pH of the effluents was observed with all the floodings, but temperature effects were observed with the conductivity and ionic concentrations of all the effluents as evident by varied breakthrough times. Hence, the observed increased recovery in this study is attributable to combined effects of electric double-layer expansion, oil viscosity reduction and interfacial tension reduction. This novel study of the combined low salinity enzyme injection process is significant for the design of enzyme enhanced oil recovery processes. Keywords: Enhanced oil recovery, enzyme, sandstone, low salinity, core flooding, temperature.

2013 ◽  
Vol 26 ◽  
pp. 111-116 ◽  
Author(s):  
Hasan Soleimani ◽  
Noorhana Yahya ◽  
Noor Rasyada Ahmad Latiff ◽  
Hasnah Mohd Zaid ◽  
Birol Demiral ◽  
...  

Research on the application of nanoparticles, specifically magnetic nanoparticles in enhanced oil recovery has been increasing in recent years due to their potential to increase the oil production despite having to interact with reservoirs of high salinity, high pressure and temperature and un-natural pH. Unlike other conventional EOR agents e.g. surfactants and polymers, a harsh environment will cause degradation and failure to operate. Magnetic nanoparticles which are activated by a magnetic field are anticipated to have the ability to travel far into the oil reservoir and assist in the displacement of the trapped oil. In this work, ferromagnetic Co2+xFe2+1-xFe3+2O4 nanoparticles were synthesized and characterized for their morphological, structural and magnetic properties. At a composition x = 0.75, this nanomaterial shows its best magnetisation parameters i.e. highest value of saturation magnetization, remanence and coercivity of 65.23 emu/g, 12.18 emu/g and 239.10 Oe, respectively. Subsequently, a dispersion of 0.01 wt% Co2+0.75Fe2+0.25Fe3+2O4 nanoparticles in distilled water was used for core flooding test to validate its feasibility in enhanced oil recovery. In a core flooding test, the effect of electromagnetic waves irradiation to activate the magnetization of Co2+0.75Fe2+0.25Fe3+2O4 nanofluid was also investigated by irradiating a 78 MHz square wave to the porous medium while nanofluid injection was taking place. In conclusion, an almost 20% increment in the recovery of oil was obtained with the application of electromagnetic waves in 2 pore volumes injection of a Co2+0.75Fe2+0.25Fe3+2O4 nanofluid.


Low salinity and carbonated water flooding have been investigated as possible techniques of improved/enhanced oil recovery. Carbonated water injection consists of dissolving carbon dioxide CO2 in water prior to injection and could be considered as a way to store greenhouse gas safely. Low salinity water flooding is a process of diluting high salinity injection water to a very low level of salinity. In this project, the effect of combining the two techniques in a sequential flooding was studied. The primary aim of this study is to optimize the oil recovery and evaluate CO2 storage during this process, employing low permeability carbonate cores and different sequential carbonated and non-carbonated brines flooding. Formation brine, seawater, low salinity carbonated and non-carbonated were used in this work. Core samples grouped as composite cores with similar over all reservoir permeability. Different sequences of brines were employed to determine the optimum system. The experiment's result showed that carbonated water performs better than the noncarbonated brines. A new technique for estimate CO2 retention based on the displacement efficiency of the carbonated water flooding system is presented. The interfacial tension, contact angle measurements results indicated that wettability is the dominant mechanism of the studied systems. A sequential composite core flooding consists of carbonated low salinity followed by low salinity and seawater injection (CLSW- LSW-SW) is the optimum flooding system among the studied systems. Technically, CLSW flooding displayed an excellent incremental displacement efficiency ∆DE of 21.4% and CSW exhibited the best CO2 retention per incremental ∆Np.


2021 ◽  
Author(s):  
Yongsheng Tan ◽  
Qi Li ◽  
Liang Xu ◽  
Xiaoyan Zhang ◽  
Tao Yu

<p>The wettability, fingering effect and strong heterogeneity of carbonate reservoirs lead to low oil recovery. However, carbon dioxide (CO<sub>2</sub>) displacement is an effective method to improve oil recovery for carbonate reservoirs. Saturated CO<sub>2</sub> nanofluids combines the advantages of CO<sub>2</sub> and nanofluids, which can change the reservoir wettability and improve the sweep area to achieve the purpose of enhanced oil recovery (EOR), so it is a promising technique in petroleum industry. In this study, comparative experiments of CO<sub>2</sub> flooding and saturated CO<sub>2</sub> nanofluids flooding were carried out in carbonate reservoir cores. The nuclear magnetic resonance (NMR) instrument was used to clarify oil distribution during core flooding processes. For the CO<sub>2</sub> displacement experiment, the results show that viscous fingering and channeling are obvious during CO<sub>2</sub> flooding, the oil is mainly produced from the big pores, and the residual oil is trapped in the small pores. For the saturated CO<sub>2</sub> nanofluids displacement experiment, the results show that saturated CO<sub>2</sub> nanofluids inhibit CO<sub>2</sub> channeling and fingering, the oil is produced from the big pores and small pores, the residual oil is still trapped in the small pores, but the NMR signal intensity of the residual oil is significantly reduced. The final oil recovery of saturated CO<sub>2</sub> nanofluids displacement is higher than that of CO<sub>2</sub> displacement. This study provides a significant reference for EOR in carbonate reservoirs. Meanwhile, it promotes the application of nanofluids in energy exploitation and CO<sub>2</sub> utilization.</p>


2021 ◽  
pp. 51725
Author(s):  
Conny Cerai Ferreira ◽  
Thais Barros Gomes Silva ◽  
Agatha Densy dos Santos Francisco ◽  
Lucas Bandeira ◽  
Renato D. Cunha ◽  
...  

2021 ◽  
Author(s):  
Tinuola Udoh

Abstract In this paper, the enhanced oil recovery potential of the application of nanoparticles in Niger Delta water-wet reservoir rock was investigated. Core flooding experiments were conducted on the sandstone core samples at 25 °C with the applications of nanoparticles in secondary and tertiary injection modes. The oil production during flooding was used to evaluate the enhanced oil recovery potential of the nanoparticles in the reservoir rock. The results of the study showed that the application of nanoparticles in tertiary mode after the secondary formation brine flooding increased oil production by 16.19% OIIP. Also, a comparison between the oil recoveries from secondary formation brine and nanoparticles flooding showed that higher oil recovery of 81% OIIP was made with secondary nanoparticles flooding against 57% OIIP made with formation brine flooding. Finally, better oil recovery of 7.67% OIIP was achieved with secondary application of nanoparticles relative to the tertiary application of formation brine and nanoparticles flooding. The results of this study are significant for the design of the application of nanoparticles in Niger Delta reservoirs.


2021 ◽  
Author(s):  
Xia Yin ◽  
Tianyi Zhao ◽  
Jie Yi

Abstract The water channeling and excess water production led to the decreasing formation energy in the oilfield. Therefore, the combined flooding with dispersed particle gel (DPG) and surfactant was conducted for conformance control and enhanced oil recovery in a high temperature (100-110°C) high salinity (>2.1×105mg/L) channel reservoir of block X in Tahe oilfield. This paper reports the experimental results and pilot test for the combined flooding in a well group of Block X. In the experiment part, the interfacial tension, emulsifying capacity of the surfactant and the particle size during aging of DPG were measured, then, the conformance control and enhanced oil recovery performance of the combined flooding was evaluated by core flooding experiment. In the pilot test, the geological backgrounds and developing history of the block was introduced. Then, an integrated study of EOR and conformance control performance in the block X are analyzed by real-time monitoring and performance after treatment. In addition, the well selection criteria and flooding optimization were clarified. In this combined flooding, DPG is applied as in-depth conformance control agent to increase the sweep efficiency, and surfactant solution slug following is used for improve the displacement efficiency. The long term stability of DPG for 15 days ensures the efficiency of in-depth conformance control and its size can increase from its original 0.543μm to 35.5μm after aging for 7 days in the 2.17×105mg/L reservoir water and at 110°C. In the optimization, it is found that 0.35% NAC-1+ 0.25% NAC-2 surfactant solution with interfacial tension 3.2×10-2mN/m can form a relatively stable emulsion easily with the dehydrated crude oil. In the double core flooding, the conformance control performance is confirmed by the diversion of fluid after combined flooding and EOR increases by 21.3%. After exploitation of Block X for 14 years, the fast decreasing formation energy due to lack of large bottom water and water fingering resulted in a decreasing production rate and increasing watercut. After combined flooding in Y well group with 1 injector and 3 producers, the average dynamic liquid level, daily production, and tracing agent breakthrough time increased, while the watercut and infectivity index decreased. The distribution rate of injected fluid and real-time monitoring also assured the conformance control performance. The oil production of this well group was increased by over 3000 tons. Upon this throughout study of combined flooding from experiment to case study, adjusting the heterogeneity by DPG combined with increasing displacement efficiency of surfactant enhanced the oil recovery synergistically in this high salinity high temperature reservoir. The criteria for the selection and performance of combined flooding also provides practical experiences and principles for combined flooding.


2016 ◽  
Vol 4 (2) ◽  
pp. 69 ◽  
Author(s):  
Cristiano José de Andrade ◽  
Gláucia Maria Pastore

Worldwide oil production has been declining. Microbial enhanced oil recovery is one of the most important tertiary recovery processes. The aim of this work was to evaluate the surface activity properties of surfactin and mannosylerithritol lipids-B. In our previous studies, surfactin and mannosylerithritol lipids were produced using cassava wastewater as substrate and then purified by ultrafiltration. Thus, this work extends our previous studies. Experiments of surface activity under extreme conditions (temperature, ionic strength and pH), oil displacement, removal of oil from sand and emulsification index were carried out. Central composite rotational design was performed under extreme conditions of temperature, pH and ionic strength. The results indicated that ionic strength significantly affected the surface activity of surfactin. On the other hand, ionic strength, but also temperature and pH significantly affected the tenso activity of mannosylerithritol lipids-B. Regarding oil displacement test, mannosylerithritol lipids-B showed higher clear zone than surfactin. Contrary, in the experiments of removal of crude oil from sand, minimal differences were observed between surfactin and mannosylerithritol lipids-B. Therefore, both surfactin and mannosylerithritol lipids-B showed good surface activity under extreme conditions. In addition, it seems that mannosylerithritol lipids-B is subtly better than surfactin for microbial enhanced oil recovery.


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