Second Law of Communal Development: The Correlation of Socialisation and Communal Economy

2022 ◽  
pp. 321-358
Author(s):  
R. M. Maciver
Keyword(s):  
Second Law

First and second laws of thermodynamics: relationship, “inconsistency”, hidden effects

2020 ◽  
pp. 63-73
Author(s):  
A. M. Savchenko ◽  
Yu. V. Konovalov ◽  
A. V. Laushkin
Keyword(s):  
Free Energy ◽  
Internal Energy ◽  
Second Law Of Thermodynamics ◽  
Second Law ◽  
Entropy Of Mixing ◽  
Ideal Mixing ◽  
Laws Of Thermodynamics ◽  
Relationship Of ◽  
The Relationship

The relationship of the first and second laws of thermodynamics based on their energy nature is considered. It is noted that the processes described by the second law of thermodynamics often take place hidden within the system, which makes it difficult to detect them. Nevertheless, even with ideal mixing, an increase in the internal energy of the system occurs, numerically equal to an increase in free energy. The largest contribution to the change in the value of free energy is made by the entropy of mixing, which has energy significance. The entropy of mixing can do the job, which is confirmed in particular by osmotic processes.

Reactions in solution

2018 ◽  
Author(s):  
Dennis Sherwood ◽  
Paul Dalby
Keyword(s):  
Phase Equilibria ◽  
Gas Phase ◽  
First Principles ◽  
Unique Feature ◽  
Life Sciences ◽  
Equilibrium Mixture ◽  
Second Law ◽  
Ideal Solution ◽  
Coupled Reactions ◽  
Definition Of

Another key chapter, examining reactions in solution. Starting with the definition of an ideal solution, and then introducing Raoult’s law and Henry’s law, this chapter then draws on the results of Chapter 14 (gas phase equilibria) to derive the corresponding results for equilibria in an ideal solution. A unique feature of this chapter is the analysis of coupled reactions, once again using first principles to show how the coupling of an endergonic reaction to a suitable exergonic reaction results in an equilibrium mixture in which the products of the endergonic reaction are present in much higher quantity. This demonstrates how coupled reactions can cause entropy-reducing events to take place without breaking the Second Law, so setting the scene for the future chapters on applications of thermodynamics to the life sciences, especially chapter 24 on bioenergetics.

The Analogical Turn (1884–1887)

2018 ◽  
Author(s):  
Olivier Darrigol
Keyword(s):  
Boltzmann Equation ◽  
Statistical Mechanics ◽  
Mechanical System ◽  
Thermal Equilibrium ◽  
Special Kind ◽  
Second Law Of Thermodynamics ◽  
Second Law ◽  
Equipartition Theorem ◽  
Royal Road ◽  
H Theorem

This chapter recounts how Boltzmann reacted to Hermann Helmholtz’s analogy between thermodynamic systems and a special kind of mechanical system (the “monocyclic systems”) by grouping all attempts to relate thermodynamics to mechanics, including the kinetic-molecular analogy, into a family of partial analogies all derivable from what we would now call a microcanonical ensemble. At that time, Boltzmann regarded ensemble-based statistical mechanics as the royal road to the laws of thermal equilibrium (as we now do). In the same period, he returned to the Boltzmann equation and the H theorem in reply to Peter Guthrie Tait’s attack on the equipartition theorem. He also made a non-technical survey of the second law of thermodynamics seen as a law of probability increase.

Second-Law Analysis in a Steam Power Plant for Minimization of Avoidable Exergy Destruction

2010 ◽  
Author(s):  
Tapan K. Ray ◽  
Pankaj Ekbote ◽  
Ranjan Ganguly ◽  
Amitava Gupta
Keyword(s):  
Work Performance ◽  
Operating Conditions ◽  
Performance Criteria ◽  
Second Law ◽  
Feed Water ◽  
Exergy Destruction ◽  
Actual Performance ◽  
Time Operation ◽  
Major Equipment ◽  
Cycle Efficiency

Performance analysis of a 500 MWe steam turbine cycle is performed combining the thermodynamic first and second-law constraints to identify the potential avenues for significant enhancement in efficiency. The efficiency of certain plant components, e.g. condenser, feed water heaters etc., is not readily defined in the gamut of the first law, since their output do not involve any thermodynamic work. Performance criteria for such components are defined in a way which can easily be translated to the overall influence of the cycle input and output, and can be used to assess performances under different operating conditions. A performance calculation software has been developed that computes the energy and exergy flows using thermodynamic property values with the real time operation parameters at the terminal points of each system/equipment and evaluates the relevant rational performance parameters for them. Exergy-based analysis of the turbine cycle under different strategic conditions with different degrees of superheat and reheat sprays exhibit the extent of performance deterioration of the major equipment and its impact to the overall cycle efficiency. For example, during a unit operation with attemperation flow, a traditional energy analysis alone would wrongly indicate an improved thermal performance of HP heater 5, since the feed water temperature rise across it increases. However, the actual performance degradation is reflected as an exergy analysis indicates an increased exergy destruction within the HP heater 5 under reheat spray. These results corroborate to the deterioration of overall cycle efficiency and rightly assist operational optimization. The exergy-based analysis is found to offer a more direct tool for evaluating the commercial implication of the off-design operation of an individual component of a turbine cycle. The exergy destruction is also translated in terms of its environmental impact, since the irretrievable loss of useful work eventually leads to thermal pollution. The technique can be effectively used by practicing engineers in order to improve efficiency by reducing the avoidable exergy destruction, directly assisting the saving of energy resources and decreasing environmental pollution.

First and Second Law Analysis of a Flat Plate Collector Working With Nanofluids

2018 ◽  
Author(s):  
M. T. Nitsas ◽  
I. P. Koronaki ◽  
L. Prentza
Keyword(s):  
Flat Plate ◽  
Second Law Of Thermodynamics ◽  
Climatic Conditions ◽  
Working Fluid ◽  
Second Law ◽  
Inlet Temperature ◽  
Water Tank ◽  
Systems Quality ◽  
Typical Day ◽  
Flat Plate Collector

The utilization of solar energy in thermal energy systems was and always be one of the most effective alternative to conventional energy resources. Energy efficiency is widely used as one of the most important parameters in order to evaluate and compare thermal systems including solar collectors. Nevertheless, the first law of thermodynamics is not solely capable of describing the quantitative and qualitative performance of such systems and thus exergy efficiency is used so as to introduce the systems’ quality. In this work, the performance of a flat plate solar collector using water based nanofluids of different nanoparticle types as a working fluid is analyzed theoretically under the climatic conditions in Greece based on the First and Second Law of Thermodynamics. A mathematical model is built and the model equations are solved iteratively in a MATLAB code. The energy and exergy efficiencies as well as the collector losses coefficient for various parameters such as the inlet temperature, the particles concentration and type are determined. Moreover, a dynamic model is built so as to determine the performance of a flat plate collector working with nanofluids and the useful energy that can be stored in a water tank. The exergy destruction and exergy leakage are determined for a typical day in summer during which high temperatures and solar intensity values are common for the Greek climate.

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