Ethylene Dichloride (EDC)

Author(s):  
G Margaret Wells
Keyword(s):  
1996 ◽  
Vol 35 (10) ◽  
pp. 3803-3807 ◽  
Author(s):  
Isao Mochida ◽  
Tadanori Tsunawaki ◽  
Chiaki Sotowa ◽  
Yozo Korai ◽  
Kazuo Higuchi

2007 ◽  
Vol 20 (3) ◽  
pp. 281-285 ◽  
Author(s):  
F. Van den Schoor ◽  
F. Norman ◽  
L. Tangen ◽  
O. Sæter ◽  
F. Verplaetsen

2021 ◽  
pp. 41-47
Author(s):  
B. Stepasiuk ◽  
◽  
T. Haievska ◽  
O. Spaska ◽  
Yu. Bilokopytov ◽  
...  

The paper is devoted to experimental development of method for 1,1,2-trichlorethane (TCE) dehydrochlorination (DHC). The economic and environmental issues of organic chlorinated compounds processing are described. The basic principle and possible products of TCE processing are presented. The DHC of TCE, which is one of the chlorinated organic wastes produced in the ethylene dichloride process, to vinylidene chloride (VDC) was carried out over over CaO, MgO supported on SiO2 and modified with CsCl catalysts. This process was carried out in a continuous flow fixed-bed reactor. The prepared catalysts were characterized by surface area and base properties before/after reaction. The methodology for determining properties of catalyst is described. Laboratory activity test apparatus was developed, and the schematic diagram is presented in the paper. The method of determination of TCE concentration of was calculated from its partial saturation vapor pressure at a given temperature is presented. Encouraging results were obtained on the catalyst containing 10 % CsCl/CaO·SiO2. The direction of the DHC reaction changed radically under described conditions: VDC was not formed at all and the major products were cis- and trans-1,2-dichloroethene. Interesting results were obtained with the catalytic system comprising 10 % (MgO-CsCl) (1:1) supported on SiO2. DHC of 2 % TCE/Ar at 302 °C proceeds quantitatively over 20 h with selectivity for VDC of more than 80%. These systems are suitable to study the factors providing the binding and removal of HCl from the reaction zone. A possible way to increase the selectivity for VDC is the creation of the conditions favoring the DHC of TCE into VDC by the radical mechanism, which was observed in experiments with 10% CsCl/CaSiO3. The directions for future researches are formulated and described.


1949 ◽  
Vol 27b (11) ◽  
pp. 813-827 ◽  
Author(s):  
F. L. W. McKim ◽  
A. Cambron

The catalytic oxidation of ethylene to ethylene oxide was investigated in flow experiments over silver catalysts at atmospheric pressure between 260° and 350 °C. Calcium oxalate and stannous oxide were used as catalyst promoters. Close temperature control was provided by mounting the catalyst on a silver support. At 270 °C. the selectivity increased from about 25%, with ethylene in large excess, to about 55%, with oxygen in large excess. With air constant and in large excess, the over-all reaction rate was found to be proportional to the square root of the ethylene concentration. With ethylene constant and in large excess, the reaction rate was found to be roughly proportional to the oxygen concentration. The presence of methane, ethane, or propane promoted the complete oxidation of ethylene to carbon dioxide and water. In the absence of paraffins the addition of traces of ethylene dichloride only served to poison the catalyst.


Author(s):  
M.H.A. Wahab ◽  
N. A. M. Jamail ◽  
E. Sulaiman ◽  
Q.E. Kamarudin ◽  
N.A. Othman ◽  
...  

<p>Nowadays, XLPE cable has been widely used because it has better resistance than other cables. XLPE insulation has unique features including a high dielectric strength and high insulation resistance. A lot of researches based on hardware and software have been conducted to prove the effectiveness of XLPE cable such as AC and DC applications and Space Charge Distribution measurement under HVDC at High Temperature. This research focused on analysis of space charge and electric field on XLPE cable with effect of non-uniform contamination layer by using Quickfield Software. Non-uniform contaminations have been applied along XLPE cable using Arsenic Tribromide (AsBr3), Boron Bromide (BBr3), Ethylene Dichloride (CH2C1), Formic Acid (CH1O2), Formamide (CH3NO) and Alcohol element. Presence of these contamination elements represent of underground contamination. The size and layer of the contamination were non-uniform type. From the results, it is shown that lower dielectric constant of contamination will affect more on charge of XLPE insulation. As a conclusion, it can be seen lower dielectric constant value of contamination element greatly affecting the performance of XLPE insulation. Furthermore, size of contamination also influences the content of charge in contamination where the bigger the contamination size, the more charge contained in the contamination.</p>


2010 ◽  
Vol 31 (4) ◽  
pp. 247-253 ◽  
Author(s):  
M. R. Kalaee ◽  
M. H.N. Famili ◽  
M. Mortezaei ◽  
M. Zeeb

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