scholarly journals The Formation of the Anorthosite Lunar Crust: A Mineral Dissolution Model

2020 ◽  
Author(s):  
Dan Zhu
Fuel ◽  
2022 ◽  
Vol 308 ◽  
pp. 121992
Author(s):  
Wei Meng ◽  
Fenggui Sui ◽  
Xuefeng Hao ◽  
Shoupeng Zhang ◽  
Yue Jiang ◽  
...  

Author(s):  
David L. Kirchman

Geomicrobiology, the marriage of geology and microbiology, is about the impact of microbes on Earth materials in terrestrial systems and sediments. Many geomicrobiological processes occur over long timescales. Even the slow growth and low activity of microbes, however, have big effects when added up over millennia. After reviewing the basics of bacteria–surface interactions, the chapter moves on to discussing biomineralization, which is the microbially mediated formation of solid minerals from soluble ions. The role of microbes can vary from merely providing passive surfaces for mineral formation, to active control of the entire precipitation process. The formation of carbonate-containing minerals by coccolithophorids and other marine organisms is especially important because of the role of these minerals in the carbon cycle. Iron minerals can be formed by chemolithoautotrophic bacteria, which gain a small amount of energy from iron oxidation. Similarly, manganese-rich minerals are formed during manganese oxidation, although how this reaction benefits microbes is unclear. These minerals and others give geologists and geomicrobiologists clues about early life on Earth. In addition to forming minerals, microbes help to dissolve them, a process called weathering. Microbes contribute to weathering and mineral dissolution through several mechanisms: production of protons (acidity) or hydroxides that dissolve minerals; production of ligands that chelate metals in minerals thereby breaking up the solid phase; and direct reduction of mineral-bound metals to more soluble forms. The chapter ends with some comments about the role of microbes in degrading oil and other fossil fuels.


2021 ◽  
Vol 11 (6) ◽  
pp. 2464
Author(s):  
Sha Yang ◽  
Neven Ukrainczyk ◽  
Antonio Caggiano ◽  
Eddie Koenders

Modelling of a mineral dissolution front propagation is of interest in a wide range of scientific and engineering fields. The dissolution of minerals often involves complex physico-chemical processes at the solid–liquid interface (at nano-scale), which at the micro-to-meso-scale can be simplified to the problem of continuously moving boundaries. In this work, we studied the diffusion-controlled congruent dissolution of minerals from a meso-scale phase transition perspective. The dynamic evolution of the solid–liquid interface, during the dissolution process, is numerically simulated by employing the Finite Element Method (FEM) and using the phase–field (PF) approach, the latter implemented in the open-source Multiphysics Object Oriented Simulation Environment (MOOSE). The parameterization of the PF numerical approach is discussed in detail and validated against the experimental results for a congruent dissolution case of NaCl (taken from literature) as well as on analytical models for simple geometries. In addition, the effect of the shape of a dissolving mineral particle was analysed, thus demonstrating that the PF approach is suitable for simulating the mesoscopic morphological evolution of arbitrary geometries. Finally, the comparison of the PF method with experimental results demonstrated the importance of the dissolution rate mechanisms, which can be controlled by the interface reaction rate or by the diffusive transport mechanism.


Author(s):  
Kyung Tae Kim ◽  
Mantha Sai Pavan Jagannath ◽  
Gregory M. Su ◽  
Guillaume Freychet ◽  
Tongzhou Zeng ◽  
...  

2020 ◽  
Vol 124 (35) ◽  
pp. 19166-19173
Author(s):  
Yubing Ouyang ◽  
Shujian Chen ◽  
Weiqiang Chen ◽  
Lihai Zhang ◽  
Stephan Matthai ◽  
...  

Geophysics ◽  
1978 ◽  
Vol 43 (6) ◽  
pp. 1235-1249 ◽  
Author(s):  
J. D. Klein ◽  
R. T. Shuey

The impedance of the interface between an acidic electrolyte and monomineralic, polished electrodes of galena, graphite, and chalcopyrite has been investigated at current densities in the nonlinear range (up to [Formula: see text]). The potential across a single interface relative to a reference electrode was measured in response to a current sinusoid of low frequency, 0.002 Hz. Polarization curves, or linear plots of current density versus electrode potential, consisted of distorted Lissajous patterns. Onset of a new electrochemical reaction resulted in a decrease in impedance of the interface, and hence increase in slope of the polarization curve. For some reactions, the electrical characteristics were diagnostic of bulk mineral composition. Diagnostic reactions include (1) mineral dissolution and gas evolution reactions at extreme anodic and cathodic potentials, (2) reactions at intermediate potentials which involve reaction products from previous reactions. Response is thus dependent on previous reactions and therefore on sample history. Anodic reactions were generally independent of pH, and consisted primarily of mineral dissolution reactions. Potentials of cathodic reactions increased with increasing pH indicating the involvement of [Formula: see text] as demonstrated by the evolution of hydrogen gas and/or [Formula: see text] gas. The potentials of the main graphite reactions were larger in magnitude than any of the sulfide reaction potentials. Measurements with polymineralic electrodes indicate that current flows mainly through minerals with reactions at less extreme potentials and consequently reactions involving other minerals at higher potential do not occur. Due to its more extreme reaction potentials, graphite does not respond in the presence of sulfide minerals. It appears that nonlinear phenomena could be used for mineral discrimination in drill hole logging.


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