scholarly journals Effect of Different Binder Proportions on Properties of Silicon-based Anode Materials

2021 ◽  
Vol 2 (2) ◽  
Keyword(s):  
Anode Materials ◽  
Large Scale ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Volume ◽  
Silicon Anode ◽  
Change Rate ◽  
Sei Film ◽  
Battery Technology ◽  
Silicon Based

With the development of lithium-ion battery technology, silicon anode is deemed as an ideal next-generation anode materials by virtue of its extremely high specific capacity. Nevertheless, higher requirements are raised for the properties of the binder owing to the high volume change rate of silicon anode during charging and discharging and the thickening of SEI film. In respect of the binders such as polyacrylic acid (PAA), polyvinyl alcohol (PVA), sodium alginate (Alginate), sodium carboxymethylcellulose (CMC) in possession of large-scale application value, this paper studies the effects of different binders and mixed binders with different ratios on the properties of silicon anode materials. As a result, it is suggested that the binders acquired when PAA:PVA=9:1 can render it possible for the electrode to be provided with better charge-discharge cyclic performance.

scholarly journals Effect of Different Binder Proportions on Properties of Silicon-based Anode Materials

2021 ◽  
Vol 2 (2) ◽  
Keyword(s):  
Anode Materials ◽  
Large Scale ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Volume ◽  
Silicon Anode ◽  
Change Rate ◽  
Sei Film ◽  
Battery Technology ◽  
Silicon Based

With the development of lithium-ion battery technology, silicon anode is deemed as an ideal next-generation anode materials by virtue of its extremely high specific capacity. Nevertheless, higher requirements are raised for the properties of the binder owing to the high volume change rate of silicon anode during charging and discharging and the thickening of SEI film. In respect of the binders such as polyacrylic acid (PAA), polyvinyl alcohol (PVA), sodium alginate (Alginate), sodium carboxymethylcellulose (CMC) in possession of large-scale application value, this paper studies the effects of different binders and mixed binders with different ratios on the properties of silicon anode materials. As a result, it is suggested that the binders acquired when PAA:PVA=9:1 can render it possible for the electrode to be provided with better charge-discharge cyclic performance.

scholarly journals Silicon and Iron as Resource-Efficient Anode Materials for Ambient-Temperature Metal-Air Batteries: A Review

2019 ◽  
Author(s):  
Henning Weinrich ◽  
Yasin Emre Durmus ◽  
Hermann Tempel ◽  
Hans Kungl ◽  
Rüdiger-A. Eichel
Keyword(s):  
Anode Materials ◽  
Large Scale ◽  
Lithium Ion ◽  
Primary Silicon ◽  
Extensive Literature ◽  
Metal Electrodes ◽  
Material Supply ◽  
Experimental Approaches ◽  
Battery Technology ◽  
Zinc Air Batteries

Abstract: Metal-air batteries provide a most promising battery technology given their outstanding potential energy densities, which are desirable for both stationary and mobile applications in a ‘beyond lithium-ion’ battery market. Silicon- and iron-air batteries underwent less research and development compared to lithium- and zinc-air batteries. Nevertheless, in the recent past, the two also-ran battery systems made considerable progress and attracted rising research interest due to the excellent resource-efficiency of silicon and iron. Silicon and iron are among the top five of the most abundant elements in the earth’s crust, which ensures almost infinite material supply of the anode materials, even for large scale applications. Furthermore, primary silicon-air batteries are set to provide one of the highest energy densities among all batteries, while iron-air batteries are frequently considered as a highly rechargeable system with decent performance characteristics. Considering fundamental aspects for the anode materials, i.e., the metal electrodes, in this review, we will first outline the challenges, which explicitly apply to silicon- and iron-air batteries and prevented them from a broad implementation so far. Afterwards, we provide an extensive literature survey regarding state-of-the-art experimental approaches, which are set to resolve the aforementioned challenges and might enable the introduction of silicon- and iron-air batteries into the battery market in the future.

scholarly journals The influence of different Si : C ratios on the electrochemical performance of silicon/carbon layered film anodes for lithium-ion batteries

RSC Advances ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 6660-6666 ◽  
Author(s):  
Jun Wang ◽  
Shengli Li ◽  
Yi Zhao ◽  
Juan Shi ◽  
Lili Lv ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Lithium Ions ◽  
High Specific Capacity ◽  
Silicon Carbon ◽  
Silicon Based

With a high specific capacity (4200 mA h g−1), silicon based materials have become the most promising anode materials in lithium-ions batteries.

Large-scale fabrication of porous carbon-decorated iron oxide microcuboids from Fe–MOF as high-performance anode materials for lithium-ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (10) ◽  
pp. 7356-7362 ◽  
Author(s):  
Minchan Li ◽  
Wenxi Wang ◽  
Mingyang Yang ◽  
Fucong Lv ◽  
Lujie Cao ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Large Scale ◽  
Specific Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
High Specific Capacity ◽  
Excellent Cycling Stability ◽  
Good Rate Capability

A novel microcuboid-shaped C–Fe3O4 assembly consisting of ultrafine nanoparticles derived from Fe–MOFs exhibits a greatly enhanced performance with high specific capacity, excellent cycling stability and good rate capability as anode materials for lithium ion batteries.

scholarly journals Silicon and Iron as Resource-Efficient Anode Materials for Ambient-Temperature Metal-Air Batteries: A Review

Materials ◽  
2019 ◽  
Vol 12 (13) ◽  
pp. 2134 ◽  
Author(s):  
Henning Weinrich ◽  
Yasin Emre Durmus ◽  
Hermann Tempel ◽  
Hans Kungl ◽  
Rüdiger-A. Eichel
Keyword(s):  
Anode Materials ◽  
Large Scale ◽  
Lithium Ion ◽  
Primary Silicon ◽  
Extensive Literature ◽  
Metal Electrodes ◽  
Material Supply ◽  
Experimental Approaches ◽  
Battery Technology ◽  
Zinc Air Batteries

Metal-air batteries provide a most promising battery technology given their outstanding potential energy densities, which are desirable for both stationary and mobile applications in a “beyond lithium-ion” battery market. Silicon- and iron-air batteries underwent less research and development compared to lithium- and zinc-air batteries. Nevertheless, in the recent past, the two also-ran battery systems made considerable progress and attracted rising research interest due to the excellent resource-efficiency of silicon and iron. Silicon and iron are among the top five of the most abundant elements in the Earth’s crust, which ensures almost infinite material supply of the anode materials, even for large scale applications. Furthermore, primary silicon-air batteries are set to provide one of the highest energy densities among all types of batteries, while iron-air batteries are frequently considered as a highly rechargeable system with decent performance characteristics. Considering fundamental aspects for the anode materials, i.e., the metal electrodes, in this review we will first outline the challenges, which explicitly apply to silicon- and iron-air batteries and prevented them from a broad implementation so far. Afterwards, we provide an extensive literature survey regarding state-of-the-art experimental approaches, which are set to resolve the aforementioned challenges and might enable the introduction of silicon- and iron-air batteries into the battery market in the future.

scholarly journals Nanostructured Fe2O3 Based Composites Prepared through Arc Plasma Method as Anode Materials in the Lithium-Ion Battery

2016 ◽  
Vol 2016 ◽  
pp. 1-9
Author(s):  
Minpeng Liang ◽  
Jianxin Zou ◽  
Xiaoqin Zeng ◽  
Wenjiang Ding
Keyword(s):  
Lithium Batteries ◽  
Anode Materials ◽  
Large Scale ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Oxidation Temperature ◽  
Arc Plasma ◽  
Oxidation In Air ◽  
The One ◽  
A Current

In the present work, a method combining arc plasma evaporation of a metal followed by oxidation in air was developed to produce nanosized metal oxide based composites in large scale. As an example, Fe2O3 based nanocomposites were prepared through such a method. With increasing the oxidation temperature, α-Fe2O3 content in the composites increases, while γ-Fe2O3 and residual α-Fe contents decrease. As anode materials for lithium batteries, the electrochemical properties of nanosized Fe2O3 composites were tested. It was found that the anode materials changed to tiny crystallites and then followed by grain growth during the galvanostatic charge/discharge cycles. A capacity rising was observed for the composites obtained at 400°C and 450°C, which was more prominent with increasing the oxidation temperature. Among these composites, the one obtained at 450°C showed the best performance: a specific capacity of 507.6 mAh/g remained after 150 cycles at a current density of 200 mA/g, much higher than that of the commercial nano-Fe2O3 powder (~180 mAh/g after 30 cycles).

scholarly journals The Progress of Cobalt-Based Anode Materials for Lithium Ion Batteries and Sodium Ion Batteries

2020 ◽  
Vol 10 (9) ◽  
pp. 3098 ◽  
Author(s):  
Yaohui Zhang ◽  
Nana Wang ◽  
Zhongchao Bai
Keyword(s):  
Energy Storage ◽  
Anode Materials ◽  
High Performance ◽  
Large Scale ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Sodium Ion ◽  
Electrochemical Performances ◽  
Sodium Ion Batteries ◽  
Preparation Methods

Limited by the development of energy storage technology, the utilization ratio of renewable energy is still at a low level. Lithium/sodium ion batteries (LIBs/SIBs) with high-performance electrochemical performances, such as large-scale energy storage, low costs and high security, are expected to improve the above situation. Currently, developing anode materials with better electrochemical performances is the main obstacle to the development of LIBs/SIBs. Recently, a variety of studies have focused on cobalt-based anode materials applied for LIBs/SIBs, owing to their high theoretical specific capacity. This review systematically summarizes the recent status of cobalt-based anode materials in LIBs/SIBs, including Li+/Na+ storage mechanisms, preparation methods, applications and strategies to improve the electrochemical performance of cobalt-based anode materials. Furthermore, the current challenges and prospects are also discussed in this review. Benefitting from these results, cobalt-based materials can be the next-generation anode for LIBs/SIBs.

Preparation and application of energy materials from biomass

2018 ◽  
Vol 32 (19) ◽  
pp. 1840081 ◽  
Author(s):  
Jinlong Cui ◽  
Juncai Sun
Keyword(s):  
Lithium Ion Battery ◽  
Anode Materials ◽  
Electrode Materials ◽  
Low Cost ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Rice Husks ◽  
Energy Materials ◽  
Silicon Based ◽  
Battery Application

Silicon-based anode materials in recent years has gained tremendous interest due to high theoretical specific capacity for next generation lithium ion battery. Some biomass, such as rice husks (RHs), has contained a lot of inorganic silicon, which are abundant in all the countryside and farmland. Considering that RHs are mainly composed of organic lignin, cellulose, hemicellulose, and inorganic Si compound, they could be used to prepare low-cost electrode materials, such as carbonaceous and silicon-based anode materials. In this work, we will present the synthesis of various anode materials from RHs with prominent performance for lithium ion battery application, such as porous C/SiO[Formula: see text] composites and Al-doped porous carbonized RHs husks composites.

scholarly journals Silicon-Based Anode of Lithium Ion Battery Made of Nano Silicon Flakes Partially Encapsulated by Silicon Dioxide

Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2467
Author(s):  
Yonhua Tzeng ◽  
Raycheng Chen ◽  
Jia-Lin He
Keyword(s):  
Silicon Dioxide ◽  
Lithium Ion Battery ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Current Collector ◽  
High Volume ◽  
Cycling Performance ◽  
Electrical Contacts ◽  
Silicon Based ◽  
Electrical Connections

Ubiquitous mobile electronic devices and rapidly increasing electric vehicles demand a better lithium ion battery (LIB) with a more durable and higher specific charge storage capacity than traditional graphite-based ones. Silicon is among the most promising active media since it exhibits ten times of a specific capacity. However, alloying with lithium by silicon and dissociation of the silicon-lithium alloys induce high volume changes and result in pulverization. The loss of electrical contacts by silicon with the current collector of the anode causes rapid capacity decay. We report improved anode cycling performance made of silicon flakes partially encapsulated by silicon dioxide and coated with conductive nanocarbon films and CNTs. The silicon dioxide surface layer on a silicon flake improves the physical integrity for a silicon-based anode. The exposed silicon surface provides a fast transport of lithium ions and electrons. CNTs and nanocarbon films provide electrical connections between silicon flakes and the current collector. We report a novel way of manufacturing silicon flakes partially covered by silicon dioxide through breaking oxidized silicon flakes into smaller pieces. Additionally, we demonstrate an improved cycling life and capacity retention compared to pristine silicon flakes and silicon flakes fully encapsulated by silicon dioxide. Nanocarbon coatings provide conduction channels and further improve the anode performance.

Effect of Phosphorus Doping into the Silicon as an Anode Material for Lithium Secondary Batteries

2007 ◽  
Vol 26-28 ◽  
pp. 333-336 ◽  
Author(s):  
Myung Ho Kong ◽  
Dong Jin Byun ◽  
Joong Kee Lee
Keyword(s):  
Electrical Resistivity ◽  
Anode Material ◽  
Anode Materials ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Carbonaceous Material ◽  
Cycle Performance ◽  
Lithium Secondary Batteries ◽  
High Electrical Resistivity ◽  
Silicon Based

Carbonaceous material has been used as an anode in lithium-ion secondary batteries due to their good stability during charging and discharging. But this material has the problems like irreversible capacity and low specific capacity that is about 372mAh/g. Because of the problems as stated above, silicon-based materials have been reported as possible anode materials to replace carbon. But they have high electrical resistivity and large volume changes associated with alloying and dealloying of lithium during electrochemical cycling. This study is performed to obtain higher capacity of anode material with a good cycle performance and to reduce electrical resistivity. It is expected that phosphor doping silicon and graphite mixture exhibit higher capacity than that of raw graphite and the doping of phosphorous will be able to decrease electrical resistivity of anode materials.

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