scholarly journals Inter-annual variability of surface ozone at coastal (Dumont d’Urville, 2004–2014) and inland (Concordia, 2007–2014) sites in East Antarctica

Author(s):  
M. Legrand ◽  
S. Preunkert ◽  
J. Savarino ◽  
M. M. Frey ◽  
A. Kukui ◽  
...  

Abstract. Surface ozone has been measured since 2004 at the coastal East Antarctic site of Dumont d'Urville (DDU) and since 2007 at the Concordia station located on the high East Antarctic plateau. This paper discusses long-term trends, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites. At Concordia, near surface ozone data were complemented by balloon soundings and compared to similar measurements done at the South Pole. The DDU record is compared to those obtained at the coastal site of Syowa also located in East Antarctica, as well as the coastal sites of Neumayer and Halley, both located at the coast of the Weddell Sea in West Antarctica. Surface ozone mixing ratios exhibit very similar seasonal cycle at Concordia and the South Pole. However, in summer the diurnal cycle and the vertical distribution of ozone above the snow surface are different at the two sites with a drop of ozone in the afternoon at Concordia and not at the South Pole, and a far well-mixed rich ozone layer within the lower 250 m at Concordia than at the South Pole during sunlight hours. These differences are related to different solar radiation and wind regimes encountered at these two inland sites. DDU appears to be the coastal site where the impact of the late winter/spring bromine chemistry is the weakest, but where the impact of NOx snow emissions from the high Antarctic plateau is the highest. The highest impact of the bromine chemistry is seen at Halley and Neumayer, and to a lesser extent at Syowa. These three sites are only weakly impacted by the NOx chemistry and the net ozone production occurring on the high Antarctic plateau. The differences in late winter/spring are attributed to the abundance of sea-ice offshore the sites whereas those in summer are related to the topography of East Antarctica that promotes the katabatic flow bringing oxidant-rich inland air masses to the site. There appears to be a decreasing trend in summer at the two East Antarctic sites of Concordia and DDU over the most recent period (2004/2007–2014). Further researches including continuing monitoring are needed at these two sites to better separate effect of synoptic transport from possible change of NOx snow emissions in response to change of the stratospheric ozone layer.

2016 ◽  
Vol 16 (12) ◽  
pp. 8053-8069 ◽  
Author(s):  
Michel Legrand ◽  
Susanne Preunkert ◽  
Joël Savarino ◽  
Markus M. Frey ◽  
Alexandre Kukui ◽  
...  

Abstract. Surface ozone has been measured since 2004 at the coastal East Antarctic site of Dumont d'Urville (DDU), and since 2007 at the Concordia station located on the high East Antarctic plateau. This paper discusses long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites. At Concordia, near-surface ozone data were complemented by balloon soundings and compared to similar measurements done at the South Pole. The DDU record is compared to those obtained at the coastal site of Syowa, also located in East Antarctica, as well as the coastal sites of Neumayer and Halley, both located on the coast of the Weddell Sea in West Antarctica. Surface ozone mixing ratios exhibit very similar seasonal cycles at Concordia and the South Pole. However, in summer the diurnal cycle of ozone is different at the two sites with a drop of ozone in the afternoon at Concordia but not at the South Pole. The vertical distribution of ozone above the snow surface also differs. When present, the ozone-rich layer located near the ground is better mixed and deeper at Concordia (up to 400 m) than at the South Pole during sunlight hours. These differences are related to different solar radiation and wind regimes encountered at these two inland sites. DDU appears to be the coastal site where the impact of the late winter/spring bromine chemistry is the weakest, but where the impact of elevated ozone levels caused by NOx snow emissions from the high Antarctic plateau is the highest. The highest impact of the bromine chemistry is seen at Halley and Neumayer, and to a lesser extent at Syowa. These three sites are only weakly impacted by the NOx chemistry and the net ozone production occurring on the high Antarctic plateau. The differences in late winter/spring are attributed to the abundance of sea ice offshore from the sites, whereas those in summer are related to the topography of East Antarctica that promotes the katabatic flow bringing oxidant-rich inland air masses to the site. There appears to be a decreasing change in summer surface ozone at the two East Antarctic sites of Concordia and DDU over the most recent period (2004–2014 and 2007–2014). Further research, including continued monitoring, is needed at these two sites to better separate the effect of synoptic transport from possible change of NOx snow emissions in response to recovery of the stratospheric ozone layer leading to penetration of more UV radiation to the surface.


2008 ◽  
Vol 5 (4) ◽  
pp. 268 ◽  
Author(s):  
P. D. Hamer ◽  
D. E. Shallcross ◽  
A. Yabushita ◽  
M. Kawasaki

Environmental context. The study of surface photochemical ozone production on the Antarctic continent has direct relevance to climate change and general air quality and is scientifically noteworthy given the otherwise pristine nature of this environmental region. The identification of possible direct ozone emissions from snow surfaces and their contribution to the already active photochemical pollution present there represents a unique physical phenomenon. This process could have wider global significance for other snow-covered regions and therefore for global climate change. Abstract. O(3P) emissions due to photolysis of nitrate were recently identified from ice surfaces doped with nitric acid. O(3P) atoms react directly with molecular oxygen to yield ozone. Therefore, these results may have direct bearing on photochemical activity monitored at the South Pole, a site already noted for elevated summertime surface ozone concentrations. NO2 is also produced via the photolysis of nitrate and the firn air contains elevated levels of NO2, which will lead to direct emission of NO2. A photochemical box model was used to probe what effect O(3P) and NO2 emissions have on ozone concentrations within the South Pole boundary layer. The results suggest that these emissions could account for a portion of the observed ozone production at the South Pole and may explain the observed upward fluxes of ozone identified there.


Author(s):  
David Beerling

By arriving at the South Pole on 14 December 1911, the Norwegian explorer Roald Amundsen (1872–1928) reached his destination over a month ahead of the British effort led by Captain Robert Falcon Scott (1868–1912). As Scott’s party approached the South Pole on 17 January 1912, they were devastated to see from afar the Norwegian’s black flag. On arrival, they discovered the remains of his camp with ski and sledge tracks, and numerous dog footprints. Amundsen, it turned out, had used dogs and diversionary tactics to secure victory while the British team had man-hauled their sledges. These differences were not lost on The Times in London, which marked the achievement with muted praise, declaring it ‘not quite in accordance with the spirit of fair and open competition which hitherto marked Antarctic exploration’. Exhausted, Scott and his men spent time the following day making scientific observations around the Pole, erected ‘our poor slighted Union Jack’, and photographed themselves in front of it (Plate 11). Lieutenant Bowers took the picture by pulling a string to activate the shutter. It is perhaps the most well known, and at the same time the saddest picture, of the entire expedition—a poignant image of the doomed party, all of whom look utterly fed up as if somehow sensing the fate awaiting them. The cold weather, icy wind, and dismal circumstances led Scott to acerbically remark in his diary: ‘Great god! This is an awful place and terrible enough to have laboured to it without the reward of priority.’ By this time, the party had been hauling their sledges for weeks, and all the men were suffering from dehydration, owing to fatigue and altitude sickness from being on the Antarctic plateau that sits nearly 3000m above sea level. Three of them, Captain Oates, Seaman Evans, and Bowers, were badly afflicted with frostbitten noses and cheeks. Ahead lay the return leg, made all the more unbearable by the crippling psychological blow of knowing they had been second to the Pole. After a gruelling 21-day trek in bitterly cold summit winds, the team reached their first cache of food and fuel, covering the distance six days faster than it had taken them to do the leg in the other direction.


1999 ◽  
Vol 29 ◽  
pp. 55-60 ◽  
Author(s):  
Qin Dahe ◽  
Paul A. Mayewski ◽  
Ren Jiawen ◽  
Xiao Cunde ◽  
Sun Junying

AbstractGlaciochemical analysis of surface snow samples, collected along a profile crossing the Antarctic ice sheet from the Larsen Ice Shelf, Antarctic Peninsula, via the Antarctic Plateau through South Pole, Vostok and Komsomolskaya to Mirny station (at the east margin of East Antarctica), shows that the Weddell Sea region is an important channel for air masses to the high plateau of the Antarctic ice sheet (>2000 m a.s.l.). This opinion is supported by the following. (1) The fluxes of sea-salt ions such as Na+, Mg2 + and CF display a decreasing trend from the west to the east of interior Antarctica. In |eneral, as sea-salt aerosols are injected into the atmosphere over the Antarctic ice sheet from the Weddell Sea, large aerosols tend to decrease. For the inland plateau, few large particles of sea-salt aerosol reach the area, and the sea-salt concentration levels are low (2) The high altitude of the East Antarctic plateau, as well as the polar cold high-pressure system, obstruct the intrusive air masses mainly from the South Indian Ocean sector. (3) For the coastal regions of the East Antarctic ice sheet, the elevation rises to 2000 m over a distance from several to several tens of km. High concentrations of sea salt exist in snow in East Antarctica but are limited to a narrow coastal zone. (4) Fluxes of calcium and non-sea-salt sulfate in snow from the interior plateau do not display an eastward-decreasing trend. Since calcium is mainly derived from crustal sources, and nssSO42- is a secondary aerosol, this again confirms that the eastward-declining tendency of sea-salt ions indicates the transfer direction of precipitation vapor.


2021 ◽  
Author(s):  
Mathieu Casado ◽  
Christophe Leroy-Dos Santos ◽  
Elise Fourré ◽  
Vincent Favier ◽  
Cécile Agosta ◽  
...  

<p>Stable water isotopes are effective hydrological tracers due to fractionation processes throughout the water cycle, and thus, the stable isotopes from ice cores can serve as valuable proxies for past changes in the climate and local environment of polar regions. Proper interpretation of these isotopes requires to understand the influence of each potential fractionating process, such as initial evaporation over the ocean and precipitation events, but also the effects of post-depositional exchange between snow and moisture in the atmosphere. Thanks to new developments in infrared spectroscopy, it is now possible to continuously monitor the isotopic composition of atmospheric water vapor in coordination with discrete snow sampling. This allows us to readily document the isotopic and mass exchanges between snow and vapor as well as the stability of the atmospheric boundary layer, as has recently been shown on the East Antarctic Plateau at Kohnen (Ritter et al., TC, 2016) and Dome C (Casado et al., ACP, 2016) stations where substantial diurnal isotopic variations have been recorded.</p><p>In this study, we present the first vapor monitoring of an East Antarctic transect that covered more than 3600 km over a period of 3 months from November 2019 to February 2020 as part of the EAIIST mission. The isotopic record therefore describes the evolution from typical coastal values to highly depleted values deep inside the continent on the high-altitude plateau. In parallel, we also monitored the vapor isotopic composition at two stations: the coastal starting point of Dumont D’Urville (DDU) and the plateau halfway point of Dome C. Two automatic weather stations (at Paleo and Megadunes sites) were also installed in a previously unexplored region of the East Antarctic plateau that was covered by this transect. This suite of cross-calibrated vapor isotope observations and weather stations, coupled with Modele Atmospherique Régional (MAR) climate modeling, offers a unique opportunity to compare the spatial and temporal gradients of humidity, temperature, and water vapor isotopic composition in East Antarctica during the summer season, and to estimate how the water vapour isotope measurements at Dome C and DDU are representative of the conditions in East Antarctica. The quantitative agreement between the EAIIST record and those recorded at DDU and Dome C stations at the times the raid was nearby, gives confidence in the quality of the results acquired on this traverse. Although further comparisons with the surface snow isotopic composition are required to quantify the impact of the snow-atmosphere exchanges on the local surface mass balance, these initial results of vapor isotopic composition show the potential of using water stables isotopes to evaluate hydrological processes in East Antarctica and better reconstruct past climate changes through ice cores.</p>


1990 ◽  
Vol 33 (6) ◽  
pp. 23-26
Author(s):  
Kurt Weigel

Scientific evidence indicates that ozone depletion over the South Pole is more serious than was suspected a few years ago. As a result, production of the principal ozone-depleting compounds is scheduled to be phased out over the next decade. The impact of the elimination of these chemicals on industries will be immediate and significant, with the aerospace and electronics industries among the most severely affected. Alternative solvents, refrigerants, and foam-blowing agents are being developed, but will not be available in commercial quantities until 1992 at the earliest. Meanwhile, CFC users are working with the chemical manufacturers, EPA, DoD, and various research organizations, to speed up the process of identifying and implementing alternative compounds or processes. Most of the proposed alternatives have some drawbacks when compared with CFCs, but can be implemented safely if the user takes the time to understand the issues thoroughly and involves all affected parties in the decision-making process.


2004 ◽  
Vol 21 (3) ◽  
pp. 256-263 ◽  
Author(s):  
Paolo G. Calisse ◽  
Michael C. B. Ashley ◽  
Michael G. Burton ◽  
Michael A. Phillips ◽  
John W. V. Storey ◽  
...  

AbstractWe have developed a 350 μm radiometer to perform automated site testing in remote regions of Antarctica. In summer 2000–2001 the instrument operated at Concordia, a new station under construction at Dome C on the Antarctic Plateau. We present the results, and compare them with the atmospheric opacity measured at the South Pole in the same five-week period. During these five weeks, observing conditions at Dome C were, on average, substantially better than those at the South Pole.


1995 ◽  
Vol 21 ◽  
pp. 131-138 ◽  
Author(s):  
E. Mosley-Thompson ◽  
L. G. Thompson ◽  
J. F. Paskievitch ◽  
M. Pourchet ◽  
A. J. Gow ◽  
...  

This paper summarizes the 37 year history of net accumulation measurements at the geographic South Pole obtained by numerous investigators using a variety of techniques. These data lead to the conclusion that annual net snow accumulation has increased in the vicinity of South Pole Station (SPS) since 1955. The records were examined for evidence of a “station effect” and it is concluded that not all of the observed increase can be attributed to snow drift associated with the presence of the station. Furthermore, the accumulation increase at the South Pole appears consistent with increases observed at other locations on the East Antarctic Plateau, and in the Peninsula region as well. These data suggest that the recent accumulation increase at SPS may be regionally extensive over the East Antarctic Plateau.


1999 ◽  
Vol 16 (2) ◽  
pp. 167-174 ◽  
Author(s):  
L. Valenziano ◽  
G. Dall'Oglio

AbstractPreliminary site testing results at Dome C (Antarctica) are presented, using both Automatic Weather Station (AWS) meteorological data (1986–1993) and Precipitable Water Vapour (PWV) measurements made by the authors. A comparison with the South Pole and other sites is made. The South Pole is a well established astrophysical observing site, where extremely good conditions are reported for a large fraction of time during the year. Dome C, where Italy and France are building a new scientific station, is a potential observing site in the millimetre and submillimetre range. AWS are operating at both sites and they have been continuously monitoring temperature, pressure and wind speed and direction for more than ten years. Site testing instruments are already operating at the South Pole (AASTO, Automated Astrophysical Site-Testing Observatory), while light experiments have been running at Dome C (APACHE, Antarctic Plateau Anisotropy CHasing Experiment) during summertime. A direct comparison between the two sites is planned in the near future, using the AASTO. The present analysis shows that the average wind speed is lower at Dome C (∼1 ms−1) than at the South Pole (∼2 ms−1), while temperature and PWV are comparable.


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