scholarly journals Supplementary material to "Semi-volatile and highly oxygenated gaseous and particulate organic compounds observed above a boreal forest canopy"

Author(s):  
Ben H. Lee ◽  
Felipe D. Lopez-Hilfiker ◽  
Emma L. D'Ambro ◽  
Putian Zhou ◽  
Michael Boy ◽  
...  
2003 ◽  
Vol 79 (1) ◽  
pp. 132-146 ◽  
Author(s):  
Dennis Yemshanov ◽  
Ajith H Perera

We reviewed the published knowledge on forest succession in the North American boreal biome for its applicability in modelling forest cover change over large extents. At broader scales, forest succession can be viewed as forest cover change over time. Quantitative case studies of forest succession in peer-reviewed literature are reliable sources of information about changes in forest canopy composition. We reviewed the following aspects of forest succession in literature: disturbances; pathways of post-disturbance forest cover change; timing of successional steps; probabilities of post-disturbance forest cover change, and effects of geographic location and ecological site conditions on forest cover change. The results from studies in the literature, which were mostly based on sample plot observations, appeared to be sufficient to describe boreal forest cover change as a generalized discrete-state transition process, with the discrete states denoted by tree species dominance. In this paper, we outline an approach for incorporating published knowledge on forest succession into stochastic simulation models of boreal forest cover change in a standardized manner. We found that the lack of details in the literature on long-term forest succession, particularly on the influence of pre-disturbance forest cover composition, may be limiting factors in parameterizing simulation models. We suggest that the simulation models based on published information can provide a good foundation as null models, which can be further calibrated as detailed quantitative information on forest cover change becomes available. Key words: probabilistic model, transition matrix, boreal biome, landscape ecology


2021 ◽  
Author(s):  
Luis M. F. Barreira ◽  
Arttu Ylisirniö ◽  
Iida Pullinen ◽  
Angela Buchholz ◽  
Zijun Li ◽  
...  

Abstract. Secondary organic aerosols (SOA) formed from biogenic volatile organic compounds (BVOCs) constitute a significant fraction of atmospheric particulate matter and have been recognized to affect significantly the climate and air quality. Many laboratory and field experiments have studied SOA particle formation and growth in the recent years. Most of them have focused on a few monoterpenes and isoprene. However, atmospheric SOA particulate mass yields and chemical composition result from a much more complex mixture of oxidation products originating from many BVOCs, including terpenes other than isoprene and monoterpenes. Thus, a large uncertainty still remains regarding the contribution of BVOCs to SOA. In particular, organic compounds formed from sesquiterpenes have not been thoroughly investigated, and their contribution to SOA remains poorly characterized. In this study, a Filter Inlet for Gases and Aerosols (FIGAERO) combined with a high-resolution time-of-flight chemical ionization mass spectrometer (CIMS), with iodide ionization, was used for the simultaneous measurement of gas and particle phase atmospheric SOA. The aim of the study was to evaluate the relative contribution of sesquiterpene oxidation products to SOA in a spring-time hemi-boreal forest environment. Our results revealed that monoterpene and sesquiterpene oxidation products were the main contributors to SOA particles. The chemical composition of SOA particles was compared for times when either monoterpene or sesquiterpene oxidation products were dominant and possible key oxidation products for SOA particle formation were identified. Surprisingly, sesquiterpene oxidation products were the predominant fraction in the particle phase at some periods, while their gas phase concentrations remained much lower than those of monoterpene products. This can be explained by quick and effective partitioning of sesquiterpene products into the particle phase or their efficient removal by dry deposition. The SOA particle volatility determined from measured thermograms increased when the concentration of sesquiterpene oxidation products in SOA particles was higher than that of monoterpenes. Overall, this study demonstrates the important role of sesquiterpenes in atmospheric chemistry and suggests that the contribution of their products to SOA particles is being underestimated in comparison to the most studied terpenes.


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