scholarly journals Increased inorganic aerosol fraction contributes to air pollution and haze in China

2018 ◽  
Author(s):  
Yonghong Wang ◽  
Yuesi Wang ◽  
Lili Wang ◽  
Tuukka Petäjä ◽  
Qiaozhi Zha ◽  
...  
Keyword(s):  
Aerosol Particles ◽  
Satellite Observation ◽  
Pollution Level ◽  
Mass Fractions ◽  
Particle Pollution ◽  
Aerosol Fraction ◽  
Inorganic Aerosol ◽  
Haze Days ◽  
Reduced Surface

Abstract. The detailed formation mechanism of increased number of haze events in China is still not very clear. Here, we found that reduced surface visibility and an increase in satellite derived columnar concentration of inorganic precursor concentrations are connected with each other. Typically higher inorganic mass fractions lead to increased aerosol water uptake and light scattering ability in elevated relative humidity. Satellite observation of aerosol precursors of NO2 and SO2 showed increased concentrations during study period. Our in-situ measurement of aerosol chemical composition in Beijing also confirmed increased contribution of inorganic aerosol fraction as a function of increased particle pollution level. Our investigations demonstrate that the increased inorganic fraction in the aerosol particles is a key component in the frequently occurring haze days during studying period, and particularly the reduction of nitrate, sulfate and their precursor gases would contribute towards better air quality in China.

scholarly journals Increased inorganic aerosol fraction contributes to air pollution and haze in China

2019 ◽  
Vol 19 (9) ◽  
pp. 5881-5888 ◽  
Author(s):  
Yonghong Wang ◽  
Yuesi Wang ◽  
Lili Wang ◽  
Tuukka Petäjä ◽  
Qiaozhi Zha ◽  
...  
Keyword(s):  
Satellite Observation ◽  
Pollution Level ◽  
Mass Fractions ◽  
Particle Pollution ◽  
Aerosol Fraction ◽  
Inorganic Aerosol ◽  
Haze Days ◽  
Inorganic Precursors ◽  
Reduced Surface

Abstract. The detailed formation mechanism of an increased number of haze events in China is still not very clear. Here, we found that reduced surface visibility from 1980 to 2010 and an increase in satellite-derived columnar concentrations of inorganic precursors from 2002 to 2012 are connected with each other. Typically, higher inorganic mass fractions lead to increased aerosol water uptake and light-scattering ability in elevated relative humidity. Satellite observation of aerosol precursors of NO2 and SO2 showed increased concentrations during the study period. Our in situ measurement of aerosol chemical composition in Beijing also confirmed increased contribution of inorganic aerosol fraction as a function of the increased particle pollution level. Our investigations demonstrate that the increased inorganic fraction in the aerosol particles is a key component in the frequently occurring haze days during the study period, and particularly the reduction of nitrate, sulfate and their precursor gases would contribute towards better visibility in China.

scholarly journals In situ observations of aerosol particles remaining from evaporated cirrus crystals: Comparing clean and polluted air masses

2002 ◽  
Vol 2 (5) ◽  
pp. 1599-1633 ◽  
Author(s):  
M. Seifert ◽  
J. Ström ◽  
R. Krejci ◽  
A. Minikin ◽  
A. Petzold ◽  
...  
Keyword(s):  
Southern Hemisphere ◽  
Northern Hemisphere ◽  
Aerosol Particles ◽  
Pollution Level ◽  
Size Distributions ◽  
Number Density ◽  
Particle Volume ◽  
The North ◽  
In Situ Observations

Abstract. In situ observations of aerosol particles contained in cirrus crystals are presented and compared to interstitial aerosol size distributions (non-activated particles in between the cirrus crystals). The observations were conducted in cirrus clouds in the Southern and Northern Hemisphere mid-latitudes during the INCA project. The first campaign in March and April 2000 was performed from Punta Arenas, Chile (54° S) in pristine air. The second campaign in September and October 2000 was performed from Prestwick, Scotland (53° N) in the vicinity of the North Atlantic flight corridor. Size distribution measurements of crystal residuals (particles remaining after evaporation of the crystals) show that small aerosol particles (Dp < 0.1µm) dominate the number density of residuals. The crystal residual size distributions were significantly different in the two campaigns. On average the residual size distributions were shifted towards larger sizes in the Southern Hemisphere. For a given integral residual number density, the calculated particle volume was on average three times larger in the Southern Hemisphere. This may be of significance to the vertical redistribution of aerosol mass by clouds in the tropopause region. In both campaigns the mean residual size increased with increasing crystal number density. The observations of ambient aerosol particles were consistent with the expected higher pollution level in the Northern Hemisphere. The fraction of residual particles only contributes to approximately a percent or less of the total number of particles, which is the sum of the residual and interstitial particles.

scholarly journals In-situ observations of aerosol particles remaining from evaporated cirrus crystals: Comparing clean and polluted air masses

2003 ◽  
Vol 3 (4) ◽  
pp. 1037-1049 ◽  
Author(s):  
M. Seifert ◽  
J. Ström ◽  
R. Krejci ◽  
A. Minikin ◽  
A. Petzold ◽  
...  
Keyword(s):  
Size Distribution ◽  
Southern Hemisphere ◽  
Northern Hemisphere ◽  
Aerosol Particles ◽  
Pollution Level ◽  
Size Distributions ◽  
Number Density ◽  
Particle Volume ◽  
In Situ Observations

Abstract. In-situ observations of aerosol particles contained in cirrus crystals are presented and compared to interstitial aerosol size distributions (non-activated particles in between the cirrus crystals). The observations were conducted in cirrus clouds in the Southern and Northern Hemisphere mid-latitudes during the INCA project. The first campaign in March and April 2000 was performed from Punta Arenas, Chile (54°S) in pristine air. The second campaign in September and October 2000 was performed from Prestwick, Scotland (53°N) in the vicinity of the North Atlantic flight corridor. Size distribution measurements of crystal residuals (particles remaining after evaporation of the crystals) show that small aerosol particles (Dp< 0.1 mm) dominate the number density of residuals. The crystal residual size distributions were significantly different in the two campaigns. On average the residual size distributions were shifted towards larger sizes in the Southern Hemisphere. For a given integral residual number density, the calculated particle volume was on average three times larger in the Southern Hemisphere. This may be of significance to the vertical redistribution of aerosol mass by clouds in the tropopause region. In both campaigns the mean residual size increased slightly with increasing crystal number density. The form of the residual size distribution did not depend on temperature as one might have expected considering different modes of nucleation. The observations of ambient aerosol particles were consistent with the expected higher pollution level in the Northern Hemisphere. The fraction of residual particles only contributes to approximately a percent or less of the total number of particles, which is the sum of the residual and interstitial particles. Excellent agreement between the CVI and FSSP-300 probes was found supporting the assumption that each crystal is associated with only one residual particle.

scholarly journals Hygroscopic and phase separation properties of ammonium sulfate/organics/water ternary solutions

2015 ◽  
Vol 15 (15) ◽  
pp. 8975-8986 ◽  
Author(s):  
M. A. Zawadowicz ◽  
S. R. Proud ◽  
S. S. Seppalainen ◽  
D. J. Cziczo
Keyword(s):  
Phase Separation ◽  
Ammonium Sulfate ◽  
Atmospheric Aerosols ◽  
Aerosol Particles ◽  
Field Measurements ◽  
Inorganic Salts ◽  
Ample Evidence ◽  
Hygroscopic Properties ◽  
Inorganic Aerosol

Abstract. Atmospheric aerosol particles are often partially or completely composed of inorganic salts, such as ammonium sulfate and sodium chloride, and therefore exhibit hygroscopic properties. Many inorganic salts have well-defined deliquescence and efflorescence points at which they take up and lose water, respectively. Field measurements have shown that atmospheric aerosols are not typically pure inorganic salt, instead, they often also contain organic species. There is ample evidence from laboratory studies that suggests that mixed particles exist in a phase-separated state, with an aqueous inorganic core and organic shell. Although phase separation has not been measured in situ, there is no reason it would not also take place in the atmosphere. Here, we investigate the deliquescence and efflorescence points, phase separation and ability to exchange gas-phase components of mixed organic and inorganic aerosol using a flow tube coupled with FTIR (Fourier transform infrared) spectroscopy. Ammonium sulfate aerosol mixed with organic polyols with different O : C ratios, including 1,4-butanediol, glycerol, 1,2,6-hexanetriol, 1,2-hexanediol, and 1,5-pentanediol have been investigated. Those constituents correspond to materials found in the atmosphere in great abundance and, therefore, particles prepared in this study should mimic atmospheric mixed-phase aerosol particles. Some results of this study tend to be in agreement with previous microscopy experiments, but others, such as phase separation properties of 1,2,6-hexanetriol, do not agree with previous work. Because the particles studied in this experiment are of a smaller size than those used in microscopy studies, the discrepancies found could be a size-related effect.

scholarly journals Microwave Sensors for In Situ Monitoring of Trace Metals in Polluted Water

Sensors ◽  
2021 ◽  
Vol 21 (9) ◽  
pp. 3147
Author(s):  
Ilaria Frau ◽  
Stephen Wylie ◽  
Patrick Byrne ◽  
Patrizia Onnis ◽  
Jeff Cullen ◽  
...  
Keyword(s):  
Trace Metals ◽  
In Situ Monitoring ◽  
Polluted Water ◽  
Pollution Level ◽  
Mining Areas ◽  
Low Concentrations ◽  
The Uk ◽  
Microwave Sensors ◽  
Immediate Response

Thousands of pollutants are threatening our water supply, putting at risk human and environmental health. Between them, trace metals are of significant concern, due to their high toxicity at low concentrations. Abandoned mining areas are globally one of the major sources of toxic metals. Nowadays, no method can guarantee an immediate response for quantifying these pollutants. In this work, a novel technique based on microwave spectroscopy and planar sensors for in situ real-time monitoring of water quality is described. The sensors were developed to directly probe water samples, and in situ trial measurements were performed in freshwater in four polluted mining areas in the UK. Planar microwave sensors were able detect the water pollution level with an immediate response specifically depicted at three resonant peaks in the GHz range. To the authors’ best knowledge, this is the first time that planar microwave sensors were tested in situ, demonstrating the ability to use this method for classifying more and less polluted water using a multiple-peak approach.

Influence of Collecting Substrates on the Characterization of Hygroscopic Properties of Inorganic Aerosol Particles

2014 ◽  
Vol 86 (5) ◽  
pp. 2648-2656 ◽  
Author(s):  
Hyo-Jin Eom ◽  
Dhrubajyoti Gupta ◽  
Xue Li ◽  
Hae-Jin Jung ◽  
HyeKyeong Kim ◽  
...  
Keyword(s):  
Aerosol Particles ◽  
Hygroscopic Properties ◽  
Inorganic Aerosol

scholarly journals The variation characteristics and possible sources of atmospheric water-soluble ions in Beijing

2016 ◽  
Author(s):  
Pengfei Liu ◽  
Chenglong Zhang ◽  
Yujing Mu ◽  
Chengtang Liu ◽  
Chaoyang Xue ◽  
...  
Keyword(s):  
Mineral Dust ◽  
Water Soluble ◽  
Effective Control ◽  
Pollution Level ◽  
Summer Maize ◽  
Soluble Ions ◽  
Water Soluble Ions ◽  
Variation Characteristics ◽  
Oxidation Ratio ◽  
Haze Days

Abstract. The North China plain (NCP) including Beijing is currently suffering from severe haze events due to high pollution level of atmospheric fine particles called PM2.5. To mitigate the serious pollution status, identification of the sources of PM2.5 is urgently needed for the effective control measures. A total of 235 daily samples of PM2.5 were collected in Beijing through the year of 2014, and the variation characteristics of water-soluble ions (WSIs) in the PM2.5 were comprehensively analyzed for recognizing their possible sources. The results indicated that the periodic emissions from farmers' activities made evident contribution to the atmospheric WSIs in Beijing. The unusually high ratio of Cl− to Na+ in summer could be rationally explained by the prevailing fertilization of NH4Cl for planting summer maize in the vast area of NCP. The remarkable elevation of Cl− in winter was ascribed to coal combustion for heating by farmers. The most serious pollution episodes in autumn were coincident with significant elevation of Ca2+ which was ascribed to be from harvest of the summer maize and tillage for planting the winter wheat. The mineral dust emission from the harvest and tillage not only increased the atmospheric concentrations of the primary pollutants, but also greatly accelerated formation of sulfate and nitrate through heterogeneous reactions of NO2 and SO2 on the mineral dust. The relatively high concentration of K+ in winter and autumn further confirmed that crop straw burning made evident contribution to atmospheric PM2.5 in Beijing. The backward trajectories also indicated that the highest concentrations of WSIs usually occurred in the air parcel from southwest/south regions with high density of farmers. In addition, the values of nitrogen oxidation ratio (NOR) and the sulfur oxidation ratio (SOR) were found to be much higher under haze days than under non-haze days, implying that formation of sulfate and nitrate was greatly accelerated through heterogeneous or multiphase reactions of NO2 and SO2 on PM2.5.

scholarly journals Aerosol particle characteristics measured in the United Arab Emirates and their response to mixing in the boundary layer

2021 ◽  
Author(s):  
Jutta Kesti ◽  
John Backman ◽  
Ewan James O'Connor ◽  
Anne Hirsikko ◽  
Eija Asmi ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Aerosol Particle ◽  
United Arab Emirates ◽  
Wind Direction ◽  
Aerosol Particles ◽  
Surface Wind ◽  
Number Concentration ◽  
Particle Properties ◽  
Boundary Layer Height

Abstract. Aerosol particles play an important in role in the microphysics of clouds and hence on their likelihood to precipitate. In the changing climate already dry areas such as the United Arab Emirates (UAE) are predicted to become even drier. Comprehensive observations of the daily and seasonal variation in aerosol particle properties in such locations are required reducing the uncertainty in such predictions. We analyse observations from a one-year measurement campaign at a background location in the United Arab Emirates to investigate the properties of aerosol particles in this region, study the impact of boundary layer mixing on background aerosol particle properties measured at the surface and study the temporal evolution of the aerosol particle cloud formation potential in the region. We used in-situ aerosol particle measurements to characterise the aerosol particle composition, size, number and cloud condensation nuclei (CCN) properties, in-situ SO2 measurements as an anthropogenic signature and a long-range scanning Doppler lidar to provide vertical profiles of the horizontal wind and turbulent properties to monitor the evolution of the boundary layer. Anthropogenic sulphate dominated the aerosol particle mass composition in this location. There was a clear diurnal cycle in the surface wind direction, which had a strong impact on aerosol particle total number concentration, SO2 concentration and black carbon mass concentration. Local sources were the predominant source of black carbon, as concentrations clearly depended on the presence of turbulent mixing, with much higher values during calm nights. The measured concentrations of SO2, instead, were highly dependent on the surface wind direction as well as on the depth of the boundary layer when entrainment from the advected elevated layers occurred. The wind direction at the surface or of the elevated layer suggests that the cities of Dubai, Abu Dhabi and other coastal conurbations were the remote sources of SO2. We observed new aerosol particle formation events almost every day (on four days out of five on average). Calm nights had the highest CCN number concentrations and lowest κ values and activation fractions. We did not observe any clear dependence of CCN number concentration and κ parameter on the height of the daytime boundary layer, whereas the activation fraction did show a slight increase with increasing boundary layer height, due to the change in the shape of the aerosol particle size distribution where the relative portion of larger aerosol particles increased with increasing boundary layer height. We believe that this indicates that size is more important than chemistry for aerosol particle CCN activation at this site. The combination of instrumentation used in this campaign enabled us to identify periods when anthropogenic pollution from remote sources that had been transported in elevated layers was present, and had been mixed down to the surface in the growing boundary layer.

MARINE-EO project: Monitoring and forecast of eutrophication around fish farms, a Maliakos Gulf case (Eastern Mediterranean).

2021 ◽  
Author(s):  
Amandine Declerck ◽  
Matthias Delpey ◽  
Thibaut Voirand ◽  
Ioanna Varkitzi
Keyword(s):  
Water Quality ◽  
High Resolution ◽  
Real Time ◽  
Chlorophyll A ◽  
Satellite Observation ◽  
Risk Level ◽  
Fish Farms ◽  
Ocean Modelling ◽  
Monitoring And Forecasting

&lt;p&gt;Keywords: eutrophication; high resolution ocean modeling ; Chla satellite data ; biogeochemistry&lt;/p&gt;&lt;p&gt;Maliakos Gulf corresponds to mesotrophic waters that can reach eutrophic conditions and are occasionally subject to Harmful Algal Blooms (HAB) (Varkitzi et al. 2018). At the same time, it is an important fish farming and aquaculture production area. A large issue is thus related to the monitoring and forecasting of the risk of occurrence of algae blooms in the Gulf. For this purpose, the present study couples predictions from a high-resolution numerical ocean model with satellite observation to improve the monitoring and anticipation of threats for the local fish farms induced by occasional eutrophication.&lt;/p&gt;&lt;p&gt;This solution is developed in the frame of the MARINE-EO project (https://marine-eo.eu/). It combines satellite observation with high-resolution ocean modelling to provide detailed information as a support to fish farms management and operations. It is implemented in an operational platform, which provides continuous information in real time as well as short term predictions. The deployed solution uses CMEMS physical products as an input data and offers to refine this solution in order to provide a local information on site using a downscaling strategy. High resolution satellite products and ocean modelling allow to include the impact of local coastal processes on currents and water quality parameters to provide a proper monitoring and forecasting solution at the scale of a specific fish farm.&lt;/p&gt;&lt;p&gt;To model specific eutrophication processes, a NPZD (Nutrients-Phytoplankton-Zooplankton-Detritus) biogeochemical model is used. Included in the MOHID Water modelling system, the water quality module (Mateus, 2006) considering 18 properties: nutrients and organic matter (nitrogen, phosphorus and silica biogeochemical cycles), oxygen and organisms (phytoplankton and zooplankton) was deployed in the western Aegean Sea. The simulated chlorophyll a concentrations are used to compute a risk level for the eutrophication occurrence. To complete this indicator, another risk level was based on the eutrophication variation following Primpas et al. (2010) formulation. In addition to model forecasts, ocean color observations from the Sentinel-2 MSI and Landsat-8 OLI sensors are used to provide high resolution chlorophyll a concentrations maps in case of bloom events. The processing chain uses the sixth version of the Quasi-Analytical Algorithm initially developed by Lee et al. (2002) and an empirical relation based on a database built using the HydroLight software to compute chlorophyll a concentration.&lt;/p&gt;&lt;p&gt;Two past eutrophication events monitored in situ (Varkitzi et al. 2018) were studied to assess the accuracy of the developed tool. Although few in situ data were available on environmental input (as rivers flow and nutrient concentrations), it was possible using statistics to reproduce qualitatively these blooms. Finally, an operational demonstration was conducted during 2 months of the 2020 autumn season, to showcase real time monitoring and predictive perspectives.&lt;/p&gt;

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