Supplementary material to "Cloud-scale modelling of the impact of deep convection on the fate of oceanic bromoform in the troposphere: a case study over the west coast of Borneo"

Abstract. Coastal oceans emit bromoform (CHBr3) that can be transported rapidly to the upper troposphere by deep convection. In the troposphere, the spatial and vertical distribution of CHBr3 and its product gases (PGs) depend on emissions, chemical processing, transport by large scale flow, convection, and associated washout. This paper presents a modelling study on the fate of CHBr3 and its PGs in the troposphere. A case study at cloud scale was conducted along the west coast of Borneo, when several deep convective systems triggered in the afternoon and early evening of November 19th 2011. These systems were sampled by the Falcon aircraft during the field campaign of the SHIVA project. We analyse these systems using a simulation with the cloud-resolving meteorological model C-CATT-BRAMS at 2 × 2 km resolution that describes transport, photochemistry, and washout of CHBr3. We find that simulated CHBr3 mixing ratios and the observed values in the boundary layer and the outflow of the convective systems agree. However, the model underestimates the background CHBr3 mixing ratios in the upper troposphere, which suggests a missing source. An analysis of the simulated chemical speciation of bromine within and around each simulated convective system during the mature convective stage reveals that > 85 % of the bromine derived from CHBr3 and its PGs is transported vertically to the point of convective detrainment in the form of CHBr3 and that the remaining small fraction is in the form of organic PGs, principally insoluble brominated carbonyls produced from the photo-oxidation of CHBr3. The model simulates that within the boundary layer and free troposphere, the inorganic PGs are only present in soluble forms, i.e., HBr, HOBr, and BrONO2, and consequently, within the convective clouds, the inorganic PGs are almost entirely removed by wet scavenging. For the conditions of the simulated case study Br2 plays no significant role in the vertical transport of bromine. This likely results from the small simulated quantities of inorganic bromine involved, the presence of HBr in large excess compared to HOBr and the less soluble BrO, and the relatively quick removal of soluble compounds within the convective column. This prevalence of HBr is a result of the wider simulated regional atmospheric composition whereby background tropospheric ozone levels are exceptionally low.

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Cloud-scale modelling of the impact of deep convection on the fate of oceanic bromoform in the troposphere: a case study over the west coast of Borneo

Atmospheric Chemistry and Physics ◽

10.5194/acp-21-16955-2021 ◽

2021 ◽

Vol 21 (22) ◽

pp. 16955-16984

Author(s):

Paul D. Hamer ◽

Virginie Marécal ◽

Ryan Hossaini ◽

Michel Pirre ◽

Gisèle Krysztofiak ◽

...

Keyword(s):

Boundary Layer ◽

West Coast ◽

Deep Convection ◽

Regional Scale ◽

Convective System ◽

The West ◽

Convective Systems ◽

Mixing Ratios ◽

The Impact

Abstract. This paper presents a modelling study on the fate of CHBr3 and its product gases in the troposphere within the context of tropical deep convection. A cloud-scale case study was conducted along the west coast of Borneo, where several deep convective systems were triggered on the afternoon and early evening of 19 November 2011. These systems were sampled by the Falcon aircraft during the field campaign of the SHIVA project and analysed using a simulation with the cloud-resolving meteorological model C-CATT-BRAMS at 2×2 km resolution that represents the emissions, transport by large-scale flow, convection, photochemistry, and washout of CHBr3 and its product gases (PGs). We find that simulated CHBr3 mixing ratios and the observed values in the boundary layer and the outflow of the convective systems agree. However, the model underestimates the background CHBr3 mixing ratios in the upper troposphere, which suggests a missing source at the regional scale. An analysis of the simulated chemical speciation of bromine within and around each simulated convective system during the mature convective stage reveals that >85 % of the bromine derived from CHBr3 and its PGs is transported vertically to the point of convective detrainment in the form of CHBr3 and that the remaining small fraction is in the form of organic PGs, principally insoluble brominated carbonyls produced from the photo-oxidation of CHBr3. The model simulates that within the boundary layer and free troposphere, the inorganic PGs are only present in soluble forms, i.e. HBr, HOBr, and BrONO2, and, consequently, within the convective clouds, the inorganic PGs are almost entirely removed by wet scavenging. We find that HBr is the most abundant PG in background lower-tropospheric air and that this prevalence of HBr is a result of the relatively low background tropospheric ozone levels at the regional scale. Contrary to a previous study in a different environment, for the conditions in the simulation, the insoluble Br2 species is hardly formed within the convective systems and therefore plays no significant role in the vertical transport of bromine. This likely results from the relatively small quantities of simulated inorganic bromine involved, the presence of HBr in large excess compared to HOBr and BrO, and the relatively efficient removal of soluble compounds within the convective column.

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The impact of seaweed cultivation on ecosystem services - a case study from the west coast of Sweden

Marine Pollution Bulletin ◽

10.1016/j.marpolbul.2018.05.005 ◽

2018 ◽

Vol 133 ◽

pp. 53-64 ◽

Cited By ~ 21

Author(s):

Linus Hasselström ◽

Wouter Visch ◽

Fredrik Gröndahl ◽

Göran M. Nylund ◽

Henrik Pavia

Keyword(s):

Ecosystem Services ◽

West Coast ◽

Seaweed Cultivation ◽

The West ◽

The Impact

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The application of environmental isotopes to conceptualize groundwater recharge in a coastal aquifer system: Case study of the West Coast Aquifer System, South Africa

Physics and Chemistry of the Earth Parts A/B/C ◽

10.1016/j.pce.2021.102995 ◽

2021 ◽

pp. 102995

Author(s):

C.W. Andries ◽

T. Kanyerere ◽

S. Israel ◽

M. Butler

Keyword(s):

South Africa ◽

Groundwater Recharge ◽

West Coast ◽

Coastal Aquifer ◽

Environmental Isotopes ◽

The West ◽

Aquifer System

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ENSO and Wintertime Extreme Precipitation Events over the Contiguous United States

Journal of Climate ◽

10.1175/2007jcli1705.1 ◽

2008 ◽

Vol 21 (1) ◽

pp. 22-39 ◽

Cited By ~ 48

Author(s):

Siegfried D. Schubert ◽

Yehui Chang ◽

Max J. Suarez ◽

Philip J. Pegion

Keyword(s):

United States ◽

West Coast ◽

Extreme Precipitation ◽

East Coast ◽

Daily Precipitation ◽

Precipitation Variability ◽

The West ◽

Extreme Precipitation Events ◽

The Impact ◽

Precipitation Events

Abstract In this study the authors examine the impact of El Niño–Southern Oscillation (ENSO) on precipitation events over the continental United States using 49 winters (1949/50–1997/98) of daily precipitation observations and NCEP–NCAR reanalyses. The results are compared with those from an ensemble of nine atmospheric general circulation model (AGCM) simulations forced with observed SST for the same time period. Empirical orthogonal functions (EOFs) of the daily precipitation fields together with compositing techniques are used to identify and characterize the weather systems that dominate the winter precipitation variability. The time series of the principal components (PCs) associated with the leading EOFs are analyzed using generalized extreme value (GEV) distributions to quantify the impact of ENSO on the intensity of extreme precipitation events. The six leading EOFs of the observations are associated with major winter storm systems and account for more than 50% of the daily precipitation variability along the West Coast and over much of the eastern part of the country. Two of the leading EOFs (designated GC for Gulf Coast and EC for East Coast) together represent cyclones that develop in the Gulf of Mexico and occasionally move and/or redevelop along the East Coast producing large amounts of precipitation over much of the southern and eastern United States. Three of the leading EOFs represent storms that hit different sections of the West Coast (designated SW for Southwest coast, WC for the central West Coast, and NW for northwest coast), while another represents storms that affect the Midwest (designated by MW). The winter maxima of several of the leading PCs are significantly impacted by ENSO such that extreme GC, EC, and SW storms that occur on average only once every 20 years (20-yr storms) would occur on average in half that time under sustained El Niño conditions. In contrast, under La Niña conditions, 20-yr GC and EC storms would occur on average about once in 30 years, while there is little impact of La Niña on the intensity of the SW storms. The leading EOFs from the model simulations and their connections to ENSO are for the most part quite realistic. The model, in particular, does very well in simulating the impact of ENSO on the intensity of EC and GC storms. The main model discrepancies are the lack of SW storms and an overall underestimate of the daily precipitation variance.

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