scholarly journals Supplementary material to "Long-term fluxes of carbonyl sulfide and their seasonality and interannual variability in a boreal forest"

Author(s):  
Timo Vesala ◽  
Kukka-Maaria Kohonen ◽  
Arnaud P. Praplan ◽  
Linda M. J. Kooijmans ◽  
Lenka Foltýnová ◽  
...  
2017 ◽  
Author(s):  
Linda M. J. Kooijmans ◽  
Kadmiel Maseyk ◽  
Ulli Seibt ◽  
Wu Sun ◽  
Timo Vesala ◽  
...  

2021 ◽  
Author(s):  
Timo Vesala ◽  
Kukka-Maaria Kohonen ◽  
Arnaud P. Praplan ◽  
Linda M. J. Kooijmans ◽  
Lenka Foltýnová ◽  
...  

Abstract. The seasonality and interannual variability of terrestrial carbonyl sulfide (COS) flux are poorly constrained. We present the first easy-to-use parameterization for net COS forest sink based on the longest eddy covariance record from a boreal pine forest, covering 32 months over 5 years. Fluxes from hourly to yearly scales are reported, with the aim of revealing controlling factors and the level of interannual variability. The parameterization is based on the photosynthetically active radiation, vapor pressure deficit, air temperature, and leaf area index. The spring recovery of the flux after the winter dormancy period was mostly governed by air temperature, and the onset of the uptake varied by 2 weeks. For the first time, we report a significant reduction of ecosystem-scale COS flux under large water vapor pressure deficit in summer. The maximum monthly and weekly median COS uptake varied 26 and 20 % between years, respectively. The timing of the latter varied by 6 weeks. The fraction of the nocturnal uptake remained below 21 % of the total COS uptake. We observed the growing season (April–August) average net uptake of COS totaling −58.0 gS ha−1 with 37 % interannual variability. The long-term flux observations were scaled up to evergreen needleleaf forests (ENFs) in the whole boreal region by the Simple Biosphere Model Version 4 (SiB4). The observations were reparameterized by using SiB4 meteorological drivers and phenology. The total COS uptake by boreal ENF was in line with a missing COS sink at high latitudes pointed out in earlier studies.


2021 ◽  
Author(s):  
Michael P. Cartwright ◽  
Jeremy J. Harrison ◽  
David P. Moore

<p>Carbonyl sulfide (OCS) is the most abundant sulfur containing gas in the atmosphere and is an important source of stratospheric aerosol. Furthermore, it has been shown that OCS can be used as a proxy for photosynthesis, which is a powerful tool in quantifying global gross primary production. While considerable improvements have been made in our understanding of the location and magnitude of OCS fluxes over the past few decades, recent studies highlight the need for a new satellite dataset to help reduce the uncertainties in current estimations. The Infrared Atmospheric Sounding Interferometer (IASI) instruments on-board the MetOp satellites offer over 14 years of nadir viewing radiance measurements with excellent spatial coverage. Given that there are currently three IASI instruments in operation, there is the potential for a significantly larger OCS dataset than is currently available elsewhere. Retrievals of OCS from these IASI radiances have been made using an adapted version of the University of Leicester IASI Retrieval Scheme (ULIRS). OCS total column amounts are calculated from profiles retrieved on a 31-layer equidistant pressure grid, using an optimal estimation approach for microwindows in the range 2000 – 2100 cm<sup>-1</sup> wavenumbers. Sensitivity of the measurements peak in the mid-troposphere, between 5 – 10 km.</p><p>The outlook of this work is to produce a long-term OCS satellite observational data set that provides fresh insight to the spatial distribution and trend of atmospheric OCS. Here, we present subsets of data in the form of case studies for different geographic regions and time periods.</p>


2017 ◽  
Vol 117 (03) ◽  
pp. 508-518 ◽  
Author(s):  
K.John Pasi ◽  
Kathelijn Fischer ◽  
Margaret Ragni ◽  
Beatrice Nolan ◽  
David J. Perry ◽  
...  

SummaryThe safety, efficacy, and prolonged half-life of recombinant factor IX Fc fusion protein (rFIXFc) were demonstrated in the Phase 3 B-LONG (adults/adolescents ≥12 years) and Kids B-LONG (children <12 years) studies of subjects with haemophilia B (≤2 IU/dl). Here, we report interim, long-term safety and efficacy data from B-YOND, the rFIXFc extension study. Eligible subjects who completed B-LONG or Kids B-LONG could enrol in B-YOND. There were four treatment groups: weekly prophylaxis (20–100 IU/kg every 7 days), individualised prophylaxis (100 IU/kg every 8–16 days), modified prophylaxis (further dosing personalisation to optimise prophylaxis), and episodic (ondemand) treatment. Subjects could change treatment groups at any point. Primary endpoint was inhibitor development. One hundred sixteen subjects enrolled in B-YOND. From the start of the parent studies to the B-YOND interim data cut, median duration of rFIXFc treatment was 39.5 months and 21.9 months among adults/adolescents and children, respectively; 68/93 (73.1 %) adults/adolescents and 9/23 (39.1 %) children had ≥100 cumulative rFIXFc exposure days. No inhibitors were observed. Median annualised bleeding rates (ABRs) were low in all prophylaxis regimens: weekly (≥12 years: 2.3; <6 years: 0.0; 6 to <12 years: 2.7), individualised (≥12 years: 2.3; 6 to <12 years: 2.4), and modified (≥12 years: 2.4). One or two infusions were sufficient to control 97 % (adults/adolescents) and 95 % (children) of bleeding episodes. Interim data from B-YOND are consistent with data from B-LONG and Kids B-LONG, and confirm the longterm safety of rFIXFc, absence of inhibitors, and maintenance of low ABRs with prophylactic dosing every 1 to 2 weeks.Supplementary Material to this article is available online at www.thrombosis-online.com.


2016 ◽  
Vol 115 (02) ◽  
pp. 361-367 ◽  
Author(s):  
Kristin Kornelia Utne ◽  
Waleed Ghanima ◽  
Siv Foyn ◽  
Susan Kahn ◽  
Per Morten Sandset ◽  
...  

SummaryPost-thrombotic syndrome (PTS) is a long-term complication of deepvein thrombosis (DVT). The Villalta scale is the recommended tool for diagnosing PTS, but requires a clinician’s assessment in addition to patient self-assessment. In the present study, we validated a self-administered tool for patient reporting of leg symptoms and signs as a mean to assess PTS. We first validated a form for patient self-reported Villalta (PRV1), then developed and validated a visually assisted form (PRV2). The validity of PRV1 and PRV2 was assessed in patients diagnosed with DVT between 2004 and 2012. Median time from DVT to inclusion was 5.1 and 3.5 years for PRV1 (n=162) and PRV2 (n=94), respectively. Patients were requested to complete the PRV form before a scheduled visit. PTS diagnosed by the original Villalta scale during the visit served as the reference method. PRV1 showed only moderate agreement for diagnosing PTS compared with the original Villalta scale (kappa agreement 0.60, 95 % CI 0.48–0.72), whereas PRV2 showed very good agreement (0.82, 95 % CI 0.71–0.94). In the validation of PRV2, PTS was diagnosed in 54 (57 %) patients according to the original Villalta scale and in 60 (64 %) by PRV2. The sensitivity of PRV2 to detect PTS was 98 % and the specificity was 83 %. We conclude that the visually assisted form for PRV is a valid and sensitive tool for diagnosing PTS. Such a tool could be applied in further clinical studies of PTS, making studies less resource demanding by reducing the need for in-person clinic visits.Supplementary Material to this article is available online at www.thrombosis-online.com.


2013 ◽  
Vol 13 (8) ◽  
pp. 21703-21763 ◽  
Author(s):  
A. Virkkula ◽  
J. Levula ◽  
T. Pohja ◽  
P. P. Aalto ◽  
P. Keronen ◽  
...  

Abstract. A prescribed burning of a boreal forest was conducted on 26 June 2009 in Hyytiälä, Finland, to study aerosol and trace gas emissions from wildfires and the effects of fire on soil properties in a controlled environment. A 0.8 ha forest near the SMEAR II was cut clear; some tree trunks, all tree tops and branches were left on the ground and burned. The amount of burned organic material was ~46.8 t (i.e., ~60 t ha−1). The flaming phase lasted 2 h 15 min, the smoldering phase 3 h. Measurements were conducted on the ground with both fixed and mobile instrumentation, and from a research aircraft. In the middle of the burning area, CO2 concentration peaks were around 2000–3000 ppm above the baseline and peak vertical flow velocities were 6 ± 3 m s−1, as measured a 10-Hz 3-D sonic anemometer placed within the burn area. Peak particle number concentrations were approximately 1–2 × 106 cm−3 in the plume at a distance of 100–200 m from the burn area. The geometric mean diameter of the mode with the highest concentration was at 80 ± 1 nm during the flaming phase and in the middle of the smoldering phase but at the end of the smoldering phase the largest mode was at 122 nm. In the volume size distributions geometric mean diameter of the largest volume mode was at 153 nm during the flaming phase and at 300 nm during the smoldering phase. The lowest single-scattering albedo of the ground-level measurents was 0.7 in the flaming-phase plume and ~0.9 in the smoldering phase. The radiative forcing efficiency was negative above dark surfaces, in other words, the particles cool the atmosphere. Elevated concentrations of several VOCs (including acetonitrile which is a biomass burning marker) were observed in the smoke plume at ground level. The forest floor (i.e., richly organic layer of soil and debris, characteristic of forested land) measurements showed that VOC fluxes were generally low and consisted mainly of monoterpenes, but a clear peak of VOC flux was observed after the burning. After one year, the fluxes were nearly stabilised close to the level before the burning. The clearcutting and burning of slash increased the total long-term CO2 release from the soil, altered the soil's physical, chemical and biological properties such as increased the available nitrogen contents of the soil, which in turn, affected the level of the long-term fluxes of greenhouse gases.


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