scholarly journals Aerosol mass closure and reconstruction of the light scattering coefficient over the Eastern Mediterranean Sea during the MINOS campaign

2005 ◽  
Vol 5 (2) ◽  
pp. 2427-2461 ◽  
Author(s):  
J. Sciare ◽  
K. Oikonomou ◽  
H. Cachier ◽  
N. Mihalopoulos ◽  
M. O. Andreae ◽  
...  
Keyword(s):  
Light Scattering ◽  
Ammonium Sulfate ◽  
Conversion Factor ◽  
Eastern Mediterranean ◽  
Scattering Coefficient ◽  
Carbonaceous Aerosols ◽  
Mass Closure ◽  
Dust Aerosols ◽  
Remote Sites ◽  
Particulate Mass

Abstract. As part of the Mediterranean Intensive Oxidant Study (MINOS) performed during August 2001 in the Eastern Mediterranean Region, intensive measurements of chemical and radiative properties of atmospheric aerosols were performed at two remote sites on Crete Island, located in the marine boundary layer (MBL), and in the lower free troposphere (FT), respectively. Gravimetric particulate mass, as well as chemically-derived masses of water soluble ions, organic and elemental carbon, and tracer elements for dust aerosols were measured for fine (<1.2 µm) and coarse (>1.2 µm) particles at the two sampling sites. Although strongly bound water, mainly associated with inorganic species, could have slightly altered our results (10% of the reconstructed mass), chemical mass closure was achieved most of the time for the fine and coarse size fractions and at both sites. Our conversion factor of 2.1 for organic carbon (OC) to particulate organic matter (POM) is at the upper end of those reported in the literature, but fits with the aged smoke particles collected during the campaign. The results indicate that this conversion factor changed during the campaign along with the BC/TC ratio. The particulate mass (PM) concentration for fine aerosols at the MBL and FT sites averaged 17.4±4.7 µg/m3 and 11.2±3.2 µg/m3, respectively, and is among the highest reported in the literature for remote sites; more than 90% of this PM was composed equally of ammonium sulfate and carbonaceous aerosols. Comparison between the MBL and FT sites showed a slight vertical gradient for PM that was not observed for dust aerosols, which averaged 10.5±4.8 and 11.7±5.0 µg/m3 for the MBL and FT sites, respectively. The results were used to reconstruct the ambient light scattering coefficient (σsp) that was measured at ambient Relative Humidity (RH) for fine particles at the MBL site. Reconstruction of σsp was achieved using ratios of wet to dry scattering, f(RH), that depend on RH for ammonium sulfate, but are kept equal to 1 for POM. This results in a low water adsorption for our organic-rich carbonaceous aerosols, although these aged biomass smoke aerosols are supposed to be highly oxidized. Mass scattering efficiencies of the main aerosol components were obtained by multivariate regression analysis, and were 2.66 and 4.19 m2/g (at the 95% confidence level) for dry ammonium sulfate and POM, respectively. The calculations indicate that one third of the reconstructed σsp was due to water uptake by ammonium sulfate aerosols, demonstrating their major role in the radiative aerosol properties in the eastern Mediterranean.

scholarly journals Aerosol mass closure and reconstruction of the light scattering coefficient over the Eastern Mediterranean Sea during the MINOS campaign

2005 ◽  
Vol 5 (8) ◽  
pp. 2253-2265 ◽  
Author(s):  
J. Sciare ◽  
K. Oikonomou ◽  
H. Cachier ◽  
N. Mihalopoulos ◽  
M. O. Andreae ◽  
...  
Keyword(s):  
Light Scattering ◽  
Ammonium Sulfate ◽  
Conversion Factor ◽  
Eastern Mediterranean ◽  
Scattering Coefficient ◽  
Carbonaceous Aerosols ◽  
Mass Closure ◽  
Dust Aerosols ◽  
Remote Sites ◽  
Particulate Mass

Abstract. As part of the Mediterranean Intensive Oxidant Study (MINOS) performed during August 2001 in the Eastern Mediterranean Region, intensive measurements of chemical and radiative properties of atmospheric aerosols were performed at two remote sites on Crete Island, located in the marine boundary layer (MBL), and in the lower free troposphere (FT), respectively. Gravimetric particulate mass, as well as chemically-derived masses of water soluble ions, organic and elemental carbon, and tracer elements for dust aerosols were measured for fine (<1.2 µm) and coarse (>1.2 µm) particles at the two sampling sites. Although strongly bound water, mainly associated with inorganic species, could have slightly altered our results (10% of the reconstructed mass), chemical mass closure was achieved most of the time for the fine and coarse size fractions and at both sites. Our conversion factor of 2.1 for organic carbon (OC) to particulate organic matter (POM) is at the upper end of those reported in the literature, but fits with the aged smoke particles collected during the campaign. The results indicate that this conversion factor changed during the campaign along with the BC/TC ratio. The particulate mass (PM) concentration for fine aerosols at the MBL and FT sites averaged 17.4±4.7 µg/m3 and 11.2±3.2 µg/m3, respectively, and is among the highest reported in the literature for remote sites; more than 90% of this PM was composed equally of ammonium sulfate and carbonaceous aerosols. Comparison between the MBL and FT sites showed a slight vertical gradient for PM that was not observed for dust aerosols, which averaged 10.5±4.8 and 11.7±5.0 µg/m3 for the MBL and FT sites, respectively. The results were used to reconstruct the ambient light scattering coefficient (σsp) that was measured at ambient Relative Humidity (RH) for fine particles at the MBL site. Reconstruction of σsp was achieved using ratios of wet to dry scattering, f(RH), that depend on RH for ammonium sulfate, but are kept equal to 1 for POM. This results in a low water adsorption for our organic-rich carbonaceous aerosols, although these aged biomass smoke aerosols are supposed to be highly oxidized. Mass scattering efficiencies of the main aerosol components were obtained by multivariate regression analysis, and were 2.66 and 4.19 m2/g (at the 95% confidence level) for dry ammonium sulfate and POM, respectively. The calculations indicate that one third of the reconstructed σsp was due to water uptake by ammonium sulfate aerosols, demonstrating their major role in the radiative aerosol properties in the eastern Mediterranean.

scholarly journals A comparative evaluation of Aura-OMI and SKYNET near-UV single-scattering albedo products

2019 ◽  
Vol 12 (12) ◽  
pp. 6489-6503
Author(s):  
Hiren Jethva ◽  
Omar Torres
Keyword(s):  
Surface Albedo ◽  
Single Scattering ◽  
Single Scattering Albedo ◽  
Absolute Difference ◽  
Urban Site ◽  
Ultraviolet Region ◽  
Carbonaceous Aerosols ◽  
Inversion Algorithm ◽  
Ozone Monitoring Instrument ◽  
Dust Aerosols

Abstract. The aerosol single-scattering albedo (SSA) retrieved by the near-UV algorithm applied to the Aura Ozone Monitoring Instrument (OMI) measurements (OMAERUV) is compared with an independent inversion product derived from the sky radiometer network SKYNET – a ground-based radiation observation network with sites in Asia and Europe. The present work continues previous efforts to evaluate the consistency between the retrieved SSA from satellite and ground sensors. The automated spectral measurements of direct downwelling solar flux and sky radiances made by the SKYNET Sun-sky radiometer are used as input to an inversion algorithm that derives spectral aerosol optical depth (AOD) and single-scattering albedo (SSA) in the near-UV to near-IR spectral range. The availability of SKYNET SSA measurements in the ultraviolet region of the spectrum allows, for the first time, a direct comparison with OMI SSA retrievals eliminating the need of extrapolating the satellite retrievals to the visible wavelengths as is the case in the evaluation against the Aerosol Robotic Network (AERONET). An analysis of the collocated retrievals from over 25 SKYNET sites reveals that about 61 % (84 %) of OMI–SKYNET matchups agree within the absolute difference of ±0.03 (±0.05) for carbonaceous aerosols, 50 % (72 %) for dust aerosols, and 45 % (75 %) for urban–industrial aerosol types. Regionally, the agreement between the two inversion products is robust over several sites in Japan influenced by carbonaceous and urban–industrial aerosols; at the biomass burning site Phimai in Thailand; and the polluted urban site in New Delhi, India. The collocated dataset yields fewer matchups identified as dust aerosols mostly over the site Dunhuang with more than half of the matchup points confined to within ±0.03 limits. Altogether, the OMI–SKYNET retrievals agree within ±0.03 when SKYNET AOD (388 or 400 nm) is larger than 0.5 and the OMI UV Aerosol Index is larger than 0.2. The remaining uncertainties in both inversion products can be attributed to specific assumptions made in the retrieval algorithms, i.e., the uncertain calibration constant, assumption of spectral surface albedo and particle shape, and subpixel cloud contamination. The assumption of fixed and spectrally neutral surface albedo (0.1) in the SKYNET inversion appears to be unrealistic, leading to underestimated SSA, especially under lower aerosol load conditions. At higher AOD values for carbonaceous and dust aerosols, however, retrieved SSA values by the two independent inversion methods are generally consistent in spite of the differences in retrieval approaches.

scholarly journals Online mass spectrometric aerosol measurements during the MINOS campaign (Crete, August 2001)

2004 ◽  
Vol 4 (1) ◽  
pp. 65-80 ◽  
Author(s):  
J. Schneider ◽  
S. Borrmann ◽  
A. G. Wollny ◽  
M. Bläsner ◽  
N. Mihalopoulos ◽  
...  
Keyword(s):  
Ammonium Sulfate ◽  
Mass Spectrometer ◽  
Biomass Burning ◽  
Eastern Mediterranean ◽  
Mass Spectrometric ◽  
Particle Analysis ◽  
Spectrometric Analysis ◽  
Aerosol Mass Spectrometer ◽  
Aerosol Mass ◽  
Fine Mode

Abstract. Mass spectrometric analysis of volatile and semi-volatile (=non-refractory) aerosol particles have been performed during a field study in the summer Eastern Mediterranean. A size-resolved, quantitative mass spectrometric technique (the Aerodyne Aerosol Mass Spectrometer, AMS) has been used, and the results are compared to filter sampling methods and particle sizing techniques. The different techniques agree with the finding that the fine particle mode (D<1.2 mm) consisted mostly of ammonium sulfate and of organic material. The aerosol sulfate ranged between 2 and 12 mg/m3. On most days, ammonium was closely correlated with sulfate, suggesting ammonium sulfate as the major aerosol component, but on days with high sulfate mass concentrations, the sulfate was not fully neutralized by ammonium. Trajectories indicate that the aerosol and/or its precursors originate from South-Eastern Europe. The source of the ammonium sulfate aerosol is most likely fossil fuel burning, whereas the organic aerosol may also originate from biomass burning. Ion series analysis of the organics fraction in the mass spectrometer indicated that the major component of the organics were oxygenated organics which are a marker for aged, photochemically processed aerosol or biomass burning aerosol. The non-refractory aerosol compounds, measured with the Aerosol Mass Spectrometer, contributed between 37 and 50% to the total aerosol mass in the fine mode. A second mass spectrometer for single particle analysis by laser ablation has been used for the first time in the field during this study and yielded results, which agree with filter samples of the coarse particle mode. This mode consisted of sea salt particles and dust aerosol.

scholarly journals Optical Properties of the Urban Aerosol Particles Obtained from Ground Based Measurements and Satellite-Based Modelling Studies

2015 ◽  
Vol 2015 ◽  
pp. 1-12 ◽  
Author(s):  
Genrik Mordas ◽  
Nina Prokopciuk ◽  
Steigvilė Byčenkienė ◽  
Jelena Andriejauskienė ◽  
Vidmantas Ulevicius
Keyword(s):  
Optical Properties ◽  
Light Scattering ◽  
Urban Environment ◽  
Size Distribution ◽  
Number Concentration ◽  
Scattering Coefficient ◽  
Dust Particles ◽  
Aerosol Size Distribution ◽  
Air Masses ◽  
The Impact

Applications of satellite remote sensing data combined with ground measurements and model simulation were applied to study aerosol optical properties as well as aerosol long-range transport under the impact of large scale circulation in the urban environment in Lithuania (Vilnius). Measurements included the light scattering coefficients at 3 wavelengths (450, 550, and 700 nm) measured with an integrating nephelometer and aerosol particle size distribution (0.5–12 μm) and number concentration (Dpa> 0.5 μm) registered by aerodynamic particle sizer. Particle number concentration and mean light scattering coefficient varied from relatively low values of 6.0 cm−3and 12.8 Mm−1associated with air masses passed over Atlantic Ocean to relatively high value of 119 cm−3and 276 Mm−1associated with South-Western air masses. Analysis shows such increase in the aerosol light scattering coefficient (276 Mm−1) during the 3rd of July 2012 was attributed to a major Sahara dust storm. Aerosol size distribution with pronounced coarse particles dominance was attributed to the presence of dust particles, while resuspended dust within the urban environment was not observed.

scholarly journals Effect of hygroscopic growth on the aerosol light-scattering coefficient: A review of measurements, techniques and error sources

2016 ◽  
Vol 141 ◽  
pp. 494-507 ◽  
Author(s):  
G. Titos ◽  
A. Cazorla ◽  
P. Zieger ◽  
E. Andrews ◽  
H. Lyamani ◽  
...  
Keyword(s):  
Light Scattering ◽  
Scattering Coefficient ◽  
Hygroscopic Growth ◽  
Error Sources

scholarly journals Geochemical perspectives from a new aerosol chemical mass closure

2007 ◽  
Vol 7 (6) ◽  
pp. 1657-1670 ◽  
Author(s):  
B. Guinot ◽  
H. Cachier ◽  
K. Oikonomou
Keyword(s):  
Urban Areas ◽  
Conversion Factor ◽  
Major Ions ◽  
Fine Fraction ◽  
Coarse Fraction ◽  
Urban Environments ◽  
Data Set ◽  
K Value ◽  
Mass Closure ◽  
Chemical Mass Closure

Abstract. The aerosol chemical mass closure is revisited and a simple and inexpensive methodology is proposed. This methodology relies on data obtained for aerosol mass, and concentration of the major ions and the two main carbon components, the organic carbon (OC) and the black carbon (BC). Atmospheric particles are separated into coarse (AD>2 μm) and fine (AD<2 μm) fractions and are treated separately. For the coarse fraction the carbonaceous component is minor and assumption is made for the conversion factor k of OC-to-POM (Particulate Organic Matter) which is fixed to the value of 1.8 accounting for secondary species. The coarse soluble calcium is shown to display a correlation (regression coefficient f, y axis intercept b) with the missing mass. Conversely, the fine fraction is dominated by organic species and assumption is made for dust which is assumed to have the same f factor as the coarse mode dust. The fine mode mass obtained from chemical analyses is then adjusted to the actual weighed mass by tuning the k conversion factor. The k coefficient is kept different in the two modes due to the expected different origins of the organic particles. Using the f and k coefficient obtained from the data set, the mass closure is reached for each individual sample with an undetermined fraction less than 10%. The procedure has been applied to different urban and peri-urban environments in Europe and in Beijing and its efficiency and uncertainties on f and k values are discussed. The f and k coefficients are shown to offer consistent geochemical indications on aerosol origin and transformations. f allows to retrieve dust mass and its value accounting for Ca abundance in dust at the site of investigation may serve as an indicator of dust origin and aerosol interactions with anthropogenic acids. f values were found to vary in the 0.08–0.12 range in European urban areas, and a broader range in Beijing (0.01–0.16). As expected, k appears to be a relevant proxy for particle origin and ageing and varies in the 1.4–1.8 range. For Beijing, k exhibits high values of about 1.7 in winter and summer. Winter values suggest that fresh coal aerosol might be responsible for such a high k value, which was not taken into account in previous works.

Spectral dependency of light scattering/absorption and hygroscopicity of pollution and dust aerosols in Northeast Asia

2012 ◽  
Vol 50 ◽  
pp. 246-254 ◽  
Author(s):  
Sihye Lee ◽  
Soon-Chang Yoon ◽  
Sang-Woo Kim ◽  
Yong Pyo Kim ◽  
Young Sung Ghim ◽  
...  
Keyword(s):  
Light Scattering ◽  
Northeast Asia ◽  
Dust Aerosols

scholarly journals Variability of carbonaceous aerosols in remote, rural, urban and industrial environments in Spain: implications for air quality policy

2013 ◽  
Vol 13 (3) ◽  
pp. 6971-7019
Author(s):  
X. Querol ◽  
A. Alastuey ◽  
M. Viana ◽  
T. Moreno ◽  
C. Reche ◽  
...  
Keyword(s):  
Air Quality ◽  
Road Traffic ◽  
Mixing Layer ◽  
Gaseous Emissions ◽  
Carbonaceous Aerosols ◽  
Health Related ◽  
Remote Sites ◽  
Rural Sites ◽  
The Impact ◽  
Urban Sites

Abstract. We interpret here the variability of levels of carbonaceous aerosols based on a 12-yr database from 78 monitoring stations across Spain especially compiled for this article. Data did not evidence any spatial trends of carbonaceous aerosols across the country. Conversely, results show marked differences in average concentrations from the cleanest, most remote sites (around 1 μg m−3 of non-mineral carbon (nmC), mostly made of organic carbon (OC), with very little elemental carbon (EC) 0.1 μg m−3; OC/EC = 12–15), to the highly polluted major cities (8–10 μg m−3 of nmC; 3–4 μg m−3 of EC; 4–5 μg m−3 of OC; OC/EC = 1–2). Thus, urban (and very specific industrial) pollution was found to markedly increase levels of carbonaceous aerosols in Spain, with much lower impact of biomass burning. Correlations between yearly averaged OC/EC and EC concentrations adjust very well to a potential equation (OC/EC = 3.37 EC−0.67 R2 = 0.94). A similar equation is obtained when including average concentrations obtained at other European sites (y = 3.61x−0.5, R2 = 0.78). A clear seasonal variability in OC and EC concentrations was detected. Both OC and EC concentrations were higher during winter at the traffic and urban sites, but OC increased during the warmer months at the rural sites. Hourly equivalent black carbon (EBC) concentrations at urban sites accurately depict road traffic contributions, varying with distance to road, traffic volume and density, mixing layer height and wind speed. Weekday urban rush-hour EBC peaks are mimicked by concentrations of primary gaseous emissions from road traffic, whereas a single midday peak is characteristic of remote and rural sites. Decreasing annual trends for carbonaceous aerosols were observed between 1999 and 2011 at a large number of stations, probably reflecting the impact of the EURO4 and EURO5 standards in reducing the diesel PM emissions. This has resulted in some cases in an increasing trend of NO2/OC+EC ratios, because these standards have been much less effective for the abatement of NOx exhaust emissions in passenger diesel cars. This study concludes that EC, EBC, and especially nmC and OC+EC are very good candidates for new air quality standards since they cover both emission impact and health related issues.

scholarly journals Оптическое просветление кожи человека in vivo рядом моносахаридов

2019 ◽  
Vol 127 (8) ◽  
pp. 329
Author(s):  
К.В. Березин ◽  
К.Н. Дворецкий ◽  
М.Л. Чернавина ◽  
В.В. Нечаев ◽  
А.М. Лихтер ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Optical Coherence Tomography ◽  
Light Scattering ◽  
Rate Of Change ◽  
Scattering Coefficient ◽  
Optical Clearing ◽  
Collagen Peptide ◽  
Cleaning Agents ◽  
Optical Immersion

AbstractWe present the results of in vivo optical immersion clearing of human skin by aqueous solutions of some immersion agents (ribose, glucose, and fructose monosaccharides and glycerol), obtained using optical coherence tomography (OCT). To assess the efficiency of optical clearing, we determined the values of the rate of change of the light scattering coefficient, obtained using the averaged A-scan of the OCT signal in the derma section at a depth of 350–700 μm. A good correlation was observed between the rate of change of the light scattering coefficient and the potential of the optical clearing. Using complex molecular simulation of the interaction of a number of immersion clearing agents with collagen mimetic peptide (GPH)_3 using classical molecular dynamics and quantum chemistry, we found correlations between the efficiency of optical clearing and the energy of intermolecular interaction of cleaning agents with a fragment of collagen peptide.

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