scholarly journals Mercury distribution and transport in the North Atlantic Ocean along the GEOTRACES-GA01 transect

2018 ◽  
Vol 15 (8) ◽  
pp. 2309-2323 ◽  
Author(s):  
Daniel Cossa ◽  
Lars-Eric Heimbürger ◽  
Fiz F. Pérez ◽  
Maribel I. García-Ibáñez ◽  
Jeroen E. Sonke ◽  
...  

Abstract. We report here the results of total mercury (HgT) determinations along the 2014 Geotraces Geovide cruise (GA01 transect) in the North Atlantic Ocean (NA) from Lisbon (Portugal) to the coast of Labrador (Canada). HgT concentrations in unfiltered samples (HgTUNF) were log-normally distributed and ranged between 0.16 and 1.54 pmol L−1, with a geometric mean of 0.51 pmol L−1 for the 535 samples analysed. The dissolved fraction (< 0.45 µm) of HgT (HgTF), determined on 141 samples, averaged 78 % of the HgTUNF for the entire data set, 84 % for open seawaters (below 100 m) and 91 % if the Labrador Sea data are excluded, where the primary production was high (with a winter convection down to 1400 m). HgTUNF concentrations increased eastwards and with depth from Greenland to Europe and from subsurface to bottom waters. The HgTUNF concentrations were similarly low in the subpolar gyre waters ( ∼  0.45 pmol L−1), whereas they exceeded 0.60 pmol L−1 in the subtropical gyre waters. The HgTUNF distribution mirrored that of dissolved oxygen concentration, with highest concentration levels associated with oxygen-depleted zones. The relationship between HgTF and the apparent oxygen utilization confirms the nutrient-like behaviour of Hg in the NA. An extended optimum multiparameter analysis allowed us to characterize HgTUNF concentrations in the different source water types (SWTs) present along the transect. The distribution pattern of HgTUNF, modelled by the mixing of SWTs, show Hg enrichment in Mediterranean waters and North East Atlantic Deep Water and low concentrations in young waters formed in the subpolar gyre and Nordic seas. The change in anthropogenic Hg concentrations in the Labrador Sea Water during its eastward journey suggests a continuous decrease in Hg content in this water mass over the last decades. Calculation of the water transport driven by the Atlantic Meridional Overturning Circulation across the Portugal–Greenland transect indicates northward Hg transport within the upper limb and southward Hg transport within the lower limb, with resulting net northward transport of about 97.2 kmol yr−1.

2014 ◽  
Vol 27 (21) ◽  
pp. 8229-8243 ◽  
Author(s):  
Daniel L. R. Hodson ◽  
Jon I. Robson ◽  
Rowan T. Sutton

Abstract In the 1960s and early 1970s, sea surface temperatures in the North Atlantic Ocean cooled rapidly. There is still considerable uncertainty about the causes of this event, although various mechanisms have been proposed. In this observational study, it is demonstrated that the cooling proceeded in several distinct stages. Cool anomalies initially appeared in the mid-1960s in the Nordic Seas and Gulf Stream extension, before spreading to cover most of the subpolar gyre. Subsequently, cool anomalies spread into the tropical North Atlantic before retreating, in the late 1970s, back to the subpolar gyre. There is strong evidence that changes in atmospheric circulation, linked to a southward shift of the Atlantic ITCZ, played an important role in the event, particularly in the period 1972–76. Theories for the cooling event must account for its distinctive space–time evolution. The authors’ analysis suggests that the most likely drivers were 1) the “Great Salinity Anomaly” of the late 1960s; 2) an earlier warming of the subpolar North Atlantic, which may have led to a slowdown in the Atlantic meridional overturning circulation; and 3) an increase in anthropogenic sulfur dioxide emissions. Determining the relative importance of these factors is a key area for future work.


2018 ◽  
Author(s):  
Manon Tonnard ◽  
Hélène Planquette ◽  
Andrew R. Bowie ◽  
Pier van der Merwe ◽  
Morgane Gallinari ◽  
...  

Abstract. Dissolved Fe (DFe) samples from the GEOVIDE voyage (GEOTRACES GA01, May–June 2014) in the North Atlantic Ocean were analysed using a SeaFAST-picoTM coupled to an Element XR HR-ICP-MS and provided interesting insights on the Fe sources in this area. Overall, DFe concentrations ranged from 0.09 ± 0.01 nmol L−1 to 7.8 ± 0.5 nmol L−1. Elevated DFe concentrations were observed above the Iberian, Greenland and Newfoundland Margins likely due to riverine inputs from the Tagus River, meteoric water inputs and sedimentary inputs. Air-sea interactions were suspected to be responsible for the increase in DFe concentrations within subsurface waters of the Irminger Sea due to deep convection occurring the previous winter, that provided iron-to-nitrate ratios sufficient to sustain phytoplankton growth. Increasing DFe concentrations along the flow path of the Labrador Sea Water were attributed to sedimentary inputs from the Newfoundland Margin. Bottom waters from the Irminger Sea displayed high DFe concentrations likely due to the dissolution of Fe-rich particles from the Denmark Strait Overflow Water and the Polar Intermediate Water. Finally, the nepheloid layers were found to act as either a source or a sink of DFe depending on the nature of particles.


2009 ◽  
Vol 5 (3) ◽  
pp. 471-480 ◽  
Author(s):  
Y.-X. Li ◽  
H. Renssen ◽  
A. P. Wiersma ◽  
T. E. Törnqvist

Abstract. The 8.2 ka event is the most prominent abrupt climate change in the Holocene and is often believed to result from catastrophic drainage of proglacial lakes Agassiz and Ojibway (LAO) that routed through the Hudson Bay and the Labrador Sea into the North Atlantic Ocean, and perturbed Atlantic meridional overturning circulation (MOC). One key assumption of this triggering mechanism is that the LAO freshwater drainage was dispersed over the Labrador Sea. Recent data, however, show no evidence of lowered δ18O values, indicative of low salinity, from the open Labrador Sea around 8.2 ka. Instead, negative δ18O anomalies are found close to the east coast of North America, extending as far south as Cape Hatteras, North Carolina, suggesting that the freshwater drainage may have been confined to a long stretch of continental shelf before fully mixing with North Atlantic Ocean water. Here we conduct a sensitivity study that examines the effects of a southerly drainage route on the 8.2 ka event with the ECBilt-CLIO-VECODE model. Hosing experiments of four routing scenarios, where freshwater was introduced to the Labrador Sea in the northerly route and to three different locations along the southerly route, were performed to investigate the routing effects on model responses. The modeling results show that a southerly drainage route is possible but generally yields reduced climatic consequences in comparison to those of a northerly route. This finding implies that more freshwater would be required for a southerly route than for a northerly route to produce the same climate anomaly. The implicated large amount of LAO drainage for a southerly routing scenario is in line with a recent geophysical modelling study of gravitational effects on sea-level change associated with the 8.2 ka event, which suggests that the volume of drainage might be larger than previously estimated.


2017 ◽  
Vol 30 (2) ◽  
pp. 477-498 ◽  
Author(s):  
Florian Sévellec ◽  
Alexey V. Fedorov

This study investigates the excitation of decadal variability and predictability of the ocean climate state in the North Atlantic. Specifically, initial linear optimal perturbations (LOPs) in temperature and salinity that vary with depth, longitude, and latitude are computed, and the maximum impact on the ocean of these perturbations is evaluated in a realistic ocean general circulation model. The computations of the LOPs involve a maximization procedure based on Lagrange multipliers in a nonautonomous context. To assess the impact of these perturbations four different measures of the North Atlantic Ocean state are used: meridional volume and heat transports (MVT and MHT) and spatially averaged sea surface temperature (SST) and ocean heat content (OHC). It is shown that these metrics are dramatically different with regard to predictability. Whereas OHC and SST can be efficiently modified only by basin-scale anomalies, MVT and MHT are also strongly affected by smaller-scale perturbations. This suggests that instantaneous or even annual-mean values of MVT and MHT are less predictable than SST and OHC. Only when averaged over several decades do the former two metrics have predictability comparable to the latter two, which highlights the need for long-term observations of the Atlantic meridional overturning circulation in order to accumulate climatically relevant data. This study also suggests that initial errors in ocean temperature of a few millikelvins, encompassing both the upper and deep ocean, can lead to ~0.1-K errors in the predictions of North Atlantic sea surface temperature on interannual time scales. This transient error growth peaks for SST and OHC after about 6 and 10 years, respectively, implying a potential predictability barrier.


2018 ◽  
Vol 15 (18) ◽  
pp. 5663-5676 ◽  
Author(s):  
Jill N. Sutton ◽  
Gregory F. de Souza ◽  
Maribel I. García-Ibáñez ◽  
Christina L. De La Rocha

Abstract. The stable isotope composition of dissolved silicon in seawater (δ30SiDSi) was examined at 10 stations along the GEOVIDE section (GEOTRACES GA-01), spanning the North Atlantic Ocean (40–60∘ N) and Labrador Sea. Variations in δ30SiDSi below 500 m were closely tied to the distribution of water masses. Higher δ30SiDSi values are associated with intermediate and deep water masses of northern Atlantic or Arctic Ocean origin, whilst lower δ30SiDSi values are associated with DSi-rich waters sourced ultimately from the Southern Ocean. Correspondingly, the lowest δ30SiDSi values were observed in the deep and abyssal eastern North Atlantic, where dense southern-sourced waters dominate. The extent to which the spreading of water masses influences the δ30SiDSi distribution is marked clearly by Labrador Sea Water (LSW), whose high δ30SiDSi signature is visible not only within its region of formation within the Labrador and Irminger seas, but also throughout the mid-depth western and eastern North Atlantic Ocean. Both δ30SiDSi and hydrographic parameters document the circulation of LSW into the eastern North Atlantic, where it overlies southern-sourced Lower Deep Water. The GEOVIDE δ30SiDSi distribution thus provides a clear view of the direct interaction between subpolar/polar water masses of northern and southern origin, and allow examination of the extent to which these far-field signals influence the local δ30SiDSi distribution.


2017 ◽  
Author(s):  
Daniel Cossa ◽  
Lars-Eric Heimbürger ◽  
Fiz F. Pérez ◽  
Maribel I. García-Ibáñez ◽  
Jeroen E. Sonke ◽  
...  

Abstract. We report here the results of total mercury (HgT) determinations along the 2014 GEOTRACES GEOVIDE cruise (GA01 transect) in the North Atlantic Ocean (NA) from Lisbon (Portugal) to the Labrador coast (Canada). Ninety-seven percent of the HgT concentrations of unfiltered samples (HgTUNF) ranged between 0.16 and 1.00 pmol L−1. The geometric mean was 0.51 pmol L−1 for the 535 samples analysed. The dissolved fraction (


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