Key controls of water vapour isotopes during oceanic evaporation and their global impact

2020 ◽  
Author(s):  
Martin Werner ◽  
Jean-Louis Bonne ◽  
Alexandre Cauquoin ◽  
Hans Christian Steen-Larsen
Keyword(s):  
Boundary Layer ◽  
Sea Ice ◽  
Isotopic Composition ◽  
Water Vapour ◽  
Marine Boundary Layer ◽  
Atmospheric Model ◽  
Global Scale ◽  
Data Sets ◽  
Stable Water Isotopes ◽  
New Findings

<p>Stable water isotopes are employed as hydrological tracers to quantify the diverse implications of atmospheric moisture for climate. In a recent study based on several years of in-situ isotope measurements in water vapour of the marine boundary layer it was shown that the isotope signal during evaporation is not modulated by wind speed, contrary to the commonly used theory, but controlled by relative humidity and sea surface temperature, only (Bonne et al., 2019). In sea ice covered regions, the sublimation of deposited snow on sea ice was found as another key process controlling the local water vapour isotopic composition. Here, we evaluate how these new findings will impact the stable water isotope signal both in vapour and precipitation on a global scale. For this purpose, the newly suggested parametrisations are included in two versions of the isotope-enabled atmospheric model ECHAM-wiso (Werner et al., 2016; Cauquoin et al., 2019) and a set of simulations is performed to disentangle the effects of the various controlling factors. Model results are evaluated against a compilation of short-term measurements of the isotopic composition in the marine boundary layer (Benetti et al., 2017), as well as data sets from several coastal stations (Steen-Larsen et al., 2014; 2015; 2017). In addition, the implications of the suggested parameterization changes for the interpretation of various isotope records in paleo-records will be discussed.</p>

scholarly journals A satellite and reanalysis view of cloud organization, thermodynamic, and dynamic variability within the subtropical marine boundary layer

2017 ◽  
Author(s):  
Brian H. Kahn ◽  
Georgios Matheou ◽  
Qing Yue ◽  
Thomas Fauchez ◽  
Eric J. Fetzer ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Spatial Organization ◽  
Marine Boundary Layer ◽  
Global Scale ◽  
Data Sets ◽  
Wind Speeds ◽  
Novel Approach ◽  
Process Understanding ◽  
Static Energy ◽  
Visible Reflectance

Abstract. The global-scale patterns and covariances of subtropical marine boundary layer (MBL) cloud fraction and spatial organization with atmospheric thermodynamic and dynamic fields remain poorly understood. We describe a novel approach that leverages coincident NASA A-train and the Modern Era Retrospective-Analysis for Research and Applications (MERRA) data to quantify the relationships in the subtropical MBL derived at the native pixel and grid resolution. Four subtropical oceanic regions that capture transitions from closed-cell stratocumulus to open-cell trade cumulus are investigated. We define stratocumulus and cumulus regimes based exclusively from infrared-based thermodynamic phase. Visible reflectances are normally distributed within stratocumulus and are increasingly skewed away from the coast where disorganized cumulus dominates. Increases in MBL depth, wind speed and effective radius (re), and reductions in 700–1000 hPa moist static energy differences and 700 and 850 hPa vertical velocity, correspond with increases in reflectance skewness. We posit that a more robust representation of the cloudy MBL is obtained using visible reflectance rather than retrievals of optical thickness that are limited to a smaller subset of cumulus. An increase in re within shallow cumulus is strongly related to higher MBL wind speeds that further correspond to increased precipitation occurrence according to CloudSat. Our results are consistent with surface-based observations and suggest that the combination of A-train and MERRA data sets have potential to add global context to our process understanding of the subtropical cumulus-dominated MBL.

scholarly journals An A-train and MERRA view of cloud, thermodynamic, and dynamic variability within the subtropical marine boundary layer

2017 ◽  
Vol 17 (15) ◽  
pp. 9451-9468 ◽  
Author(s):  
Brian H. Kahn ◽  
Georgios Matheou ◽  
Qing Yue ◽  
Thomas Fauchez ◽  
Eric J. Fetzer ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Marine Boundary Layer ◽  
Global Scale ◽  
Data Sets ◽  
Data Set ◽  
Global Context ◽  
Wind Speeds ◽  
Static Energy ◽  
Thermodynamic Phase ◽  
Modern Era

Abstract. The global-scale patterns and covariances of subtropical marine boundary layer (MBL) cloud fraction and spatial variability with atmospheric thermodynamic and dynamic fields remain poorly understood. We describe an approach that leverages coincident NASA A-train and the Modern Era Retrospective-Analysis for Research and Applications (MERRA) data to quantify the relationships in the subtropical MBL derived at the native pixel and grid resolution. A new method for observing four subtropical oceanic regions that capture transitions from stratocumulus to trade cumulus is demonstrated, where stratocumulus and cumulus regimes are determined from infrared-based thermodynamic phase. Visible radiances are normally distributed within stratocumulus and are increasingly skewed away from the coast, where trade cumulus dominates. Increases in MBL depth, wind speed, and effective radius (re), and reductions in 700–1000 hPa moist static energy differences and 700 and 850 hPa vertical velocity correspond with increases in visible radiance skewness. We posit that a more robust representation of the cloudy MBL is obtained using visible radiance rather than retrievals of optical thickness that are limited to a smaller subset of cumulus. The method using the combined A-train and MERRA data set has demonstrated that an increase in re within shallow cumulus is strongly related to higher MBL wind speeds that further correspond to increased precipitation occurrence according to CloudSat, previously demonstrated with surface observations. Hence, the combined data sets have the potential of adding global context to process-level understanding of the MBL.

Disentangling the impact of air-sea interaction and boundary layer cloud formation on stable water isotope signals in the warm sector of a Southern Ocean cyclone 

2021 ◽  
Author(s):  
Iris Thurnherr ◽  
Heini Wernli ◽  
Franziska Aemisegger
Keyword(s):  
Boundary Layer ◽  
Water Vapour ◽  
Marine Boundary Layer ◽  
Cloud Formation ◽  
Stable Water Isotopes ◽  
Near Surface ◽  
Warm Sector ◽  
Moisture Fluxes ◽  
Boundary Layer Cloud ◽  
Dew Deposition

<p>Stable water isotopes in marine boundary layer water vapour are strongly influenced by the strength of air-sea moisture fluxes and are thus tracers of air-sea interaction. Air-sea moisture fluxes in the extratropics are modulated by large-scale air advection, for instance the advection of warm and moist air masses in the warm sector of extratropical cyclones. A distinct isotopic composition of water vapour in the latter environment has been observed in near-surface water vapour over the Southern Ocean during the 2016/17 Antarctic Circumnavigation coordinated by the Swiss Polar Institute. Most prominently, the second-order isotope variable d-excess shows negative values in the cyclones’ warm sector. Here, we present three single-process air parcel models, which simulate the evolution of d-excess and specific humidity in an air parcel induced by dew deposition, decreasing ocean evaporation or upstream cloud formation, respectively. The air-parcel models are combined with simulations with the isotope-enabled numerical weather prediction model COSMO<sub>iso</sub> (i) to validate the air parcel models, (ii) to study the extent of non-linear interactions between the different processes, and (iii) to quantify the relevance of the three processes for stable water isotopes in the warm sector of the investigated extratropical cyclone. This analysis reveals that dew deposition and decreasing ocean evaporation lead to the strongest d-excess decrease in near-surface water vapour in the warm sector. Furthermore, COSMO<sub>iso</sub> air parcel trajectories show that the persistent low d-excess observed in the warm sector of extratropical cyclones is not a result of material conservation of low d-excess. Instead the latter feature is sustained by the continuous production of low d-excess values in new air parcels entering the warm sector. We show that with the mechanistic approach of using single-process air parcel models we are able to simulate the evolution of d-excess during the air parcel’s transport. This improves our understanding of the effect of air-sea interaction and boundary layer cloud formation on the stable water isotope variability of marine boundary layer water vapour.</p>

scholarly journals A broadband cavity ringdown spectrometer for in-situ measurements of atmospheric trace gases

2005 ◽  
Vol 5 (3) ◽  
pp. 3491-3532 ◽  
Author(s):  
M. Bitter ◽  
S. M. Ball ◽  
I. M. Povey ◽  
R. L. Jones
Keyword(s):  
Boundary Layer ◽  
Water Vapour ◽  
Marine Boundary Layer ◽  
Thermal Dissociation ◽  
Optical Absorption Spectroscopy ◽  
Integration Time ◽  
Research Station ◽  
Absorption Bands ◽  
Optical Extinction ◽  
Cavity Ringdown

Abstract. This paper describes a broadband cavity ringdown spectrometer and its deployment during the 2002 North Atlantic Marine Boundary Layer Experiment (NAMBLEX) to measure ambient concentrations of NO3, N2O5, I2 and OIO at the Mace Head Atmospheric Research Station, Co. Galway, Ireland. The effective absorption path lengths accessible with the spectrometer generally exceeded 10 km, enabling sensitive localised ''point'' measurements of atmospheric absorbers to be made adjacent to the other instruments monitoring chemically related species at the same site. For the majority of observations, the spectrometer was used in an open path configuration thereby avoiding surface losses of reactive species. A subset of observations targeted the N2O5 molecule by detecting the additional NO3 formed by the thermal dissociation of N2O5. In all cases the concentrations of the atmospheric absorbers were retrieved by fitting the differential structure in the broadband cavity ringdown spectra using a methodology adapted from long path differential optical absorption spectroscopy. The uncertainty of the retrieval depends crucially on the correct treatment and fitting of the absorption bands due to water vapour, a topic that is discussed in the context of analysing broadband cavity ringdown spectra. The quality of the measurements and the retrieval method are illustrated with representative spectra acquired during NAMBLEX in spectral regions around 660 nm (NO3 and N2O5) and 570 nm (I2 and OIO). Typical detection limits were 1 pptv for NO3 in an integration time of 100 s, 4 pptv for OIO and 20 pptv for I2 in an integration time of 10 min. Additionally, the concentrations of atmospheric water vapour and the aerosol optical extinction were retrieved in both spectral regions. A companion paper in this issue presents the time series of the measurements and discusses their significance for understanding the variability of short lived nitrogen and iodine compounds in the marine boundary layer.

scholarly journals The stable isotope composition of water vapour above Corsica during the HyMeX SOP1: insight into vertical mixing processes from lower-tropospheric survey flights

2016 ◽  
Author(s):  
Harald Sodemann ◽  
Franziska Aemisegger ◽  
Stephan Pfahl ◽  
Mark Bitter ◽  
Ulrich Corsmeier ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Stable Isotope ◽  
Water Vapour ◽  
Isotope Composition ◽  
Water Isotopes ◽  
High Temporal Resolution ◽  
Stable Isotope Composition ◽  
Stable Water Isotopes ◽  
Mixing Processes ◽  
Strong Inversion

Abstract. Stable water isotopes are powerful indicators of meteorological processes on a broad range of scales, reflecting evaporation, condensation, and airmass mixing processes. With the recent advent of fast laser-based spectroscopic methods it has become possible to measure the stable isotopic composition of atmospheric water vapour in situ at high temporal resolution, enabling to tremendously extend the measurement data base in space and time. Here we present the first set of airborne spectroscopic stable water isotopes measurements over the western Mediterranean. Measurements have been acquired by a customised Picarro L2130-i cavity-ring down spectrometer deployed onboard of the Dornier 128 D-IBUF aircraft together with a meteorological flux measurement package during the HyMeX SOP1 field campaign in Corsica, France during September and October 2012. Taking into account memory effects of the air inlet pipe, the typical time resolution of the measurements was about 15–30 s, resulting in an average horizontal resolution of about 1–2 km. Cross-calibration of the water vapour measurements from all humidity sensors showed good agreement in most flight conditions but the most turbulent ones. In total 21 successful stable isotope flights with 59 flight hours have been performed. Our data provide quasi-climatological autumn average conditions of the stable isotope parameters δD, δ18O and d-excess during the study period. A time-averaged perspective of the vertical stable isotope composition reveals for the first time the mean vertical structure of stable water isotopes over the Mediterranean at high resolution. A d-excess minimum in the overall average profile is reached in the region of the boundary layer top due to precipitation evaporation, bracketed by higher d-excess values near the surface due to non-equilibrium fractionation and above the boundary layer due to the non-linearity of the d-excess definition. Repeated flights along the same pattern reveals pronounced day-to-day variability due to changes in the large-scale circulation. During a period marked by a strong inversion at the top of the marine boundary layer, vertical gradients in stable isotopes reached up to 25.4 ‰ 100 m−1 for δD.

scholarly journals The importance of alkyl nitrates and sea ice emissions to atmospheric NO<sub>x</sub> sources and cycling in the summertime Southern Ocean marine boundary layer

2021 ◽  
Author(s):  
Jessica Mary Burger ◽  
Julie Granger ◽  
Emily Joyce ◽  
Meredith Galanter Hastings ◽  
Kurt Angus McDonald Spence ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Southern Ocean ◽  
Sea Ice ◽  
Marine Boundary Layer ◽  
Weddell Sea ◽  
Alkyl Nitrates ◽  
Air Mass ◽  
Surface Ocean ◽  
Alkyl Nitrate ◽  
Atmospheric Nitrate

Abstract. Atmospheric nitrate originates from the oxidation of nitrogen oxides (NOx = NO + NO2) and impacts both tropospheric chemistry and climate. NOx sources, cycling, and NOx to nitrate formation pathways are poorly constrained in remote marine regions, especially the Southern Ocean where pristine conditions serve as a useful proxy for the preindustrial atmosphere. Here, we measured the isotopic composition (δ15N and δ18O) of atmospheric nitrate in coarse-mode (> 1 μm) aerosols collected in the summertime marine boundary layer of the Atlantic Southern Ocean from 34.5° S to 70° S, and across the northern edge of the Weddell Sea. The δ15N-NO3− decreased with latitude from −2.7 ‰ to −43.1 ‰. The decline in δ15N with latitude is attributed to changes in the dominant NOx sources: lightning at the low latitudes, oceanic alkyl nitrates at the mid latitudes, and photolysis of nitrate in snow at the high latitudes. There is no evidence of any influence from anthropogenic NOx sources or equilibrium isotopic fractionation. Using air mass back trajectories and an isotope mixing model, we calculate that oceanic alkyl nitrate emissions have a δ15N signature of −22.0 ‰ ± 7.5 ‰. Given that measurements of alkyl nitrate contributions to remote nitrogen budgets are scarce, this may be a useful tracer for detecting their contribution in other oceanic regions. The δ18O-NO3− was always less than 70 ‰, indicating that daytime processes involving OH are the dominant NOx oxidation pathway during summer. Unusually low δ18O-NO3− values (less than 31 ‰) were observed at the western edge of the Weddell Sea. The air mass history of these samples indicates extensive interaction with sea ice covered ocean, which is known to enhance peroxy radical production. The observed low δ18O-NO3− is therefore attributed to increased exchange of NO with peroxy radicals, which have a low δ18O, relative to ozone, which has a high δ18O. This study reveals that the mid- and high-latitude surface ocean may serve as a more important NOx source than previously thought, and that the ice-covered surface ocean impacts the reactive nitrogen budget as well as the oxidative capacity of the marine boundary layer.

scholarly journals Meridional and vertical variations of the water vapour isotopic composition in the marine boundary layer over the Atlantic and Southern Ocean

2020 ◽  
Vol 20 (9) ◽  
pp. 5811-5835 ◽  
Author(s):  
Iris Thurnherr ◽  
Anna Kozachek ◽  
Pascal Graf ◽  
Yongbiao Weng ◽  
Dimitri Bolshiyanov ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Time Series ◽  
Wind Speed ◽  
Southern Ocean ◽  
Water Vapour ◽  
Turbulent Mixing ◽  
Large Scale ◽  
Marine Boundary Layer ◽  
Sea Spray ◽  
Moisture Source

Abstract. Stable water isotopologues (SWIs) are useful tracers of moist diabatic processes in the atmospheric water cycle. They provide a framework to analyse moist processes on a range of timescales from large-scale moisture transport to cloud formation, precipitation and small-scale turbulent mixing. Laser spectrometric measurements on research vessels produce high-resolution time series of the variability of the water vapour isotopic composition in the marine boundary layer. In this study, we present a 5-month continuous time series of such ship-based measurements of δ2H and δ18O from the Antarctic Circumnavigation Expedition (ACE) in the Atlantic and the Southern Ocean in the time period from November 2016 to April 2017. We analyse the drivers of meridional SWI variations in the marine boundary layer across diverse climate zones in the Atlantic and Southern Ocean using Lagrangian moisture source diagnostics and relate vertical SWI differences to near-surface wind speed and ocean surface state. The median values of δ18O, δ2H and deuterium excess during ACE decrease continuously from low to high latitudes. These meridional SWI distributions reflect climatic conditions at the measurement and moisture source locations, such as air temperature, specific humidity and relative humidity with respect to sea surface temperature. The SWI variability at a given latitude is highest in the extratropics and polar regions with decreasing values equatorwards. This meridional distribution of SWI variability is explained by the variability in moisture source locations and its associated environmental conditions as well as transport processes. The westward-located moisture sources of water vapour in the extratropics are highly variable in extent and latitude due to the frequent passage of cyclones and thus widen the range of encountered SWI values in the marine boundary layer. Moisture loss during transport further contributes to the high SWI variability in the extratropics. In the subtropics and tropics, persistent anticyclones lead to well-confined narrow easterly moisture source regions, which is reflected in the weak SWI variability in these regions. Thus, the expected range of SWI signals at a given latitude strongly depends on the large-scale circulation. Furthermore, the ACE SWI time series recorded at 8.0 and 13.5 m above the ocean surface provide estimates of vertical SWI gradients in the lowermost marine boundary layer. On average, the vertical gradients with height found during ACE are -0.1‰m-1 for δ18O, -0.5‰m-1 for δ2H and 0.3 ‰ m−1 for deuterium excess. Careful calibration and post-processing of the SWI data and a detailed uncertainty analysis provide a solid basis for the presented gradients. Using sea spray concentrations and sea state conditions, we show that the vertical SWI gradients are particularly large during high wind speed conditions with increased contribution of sea spray evaporation or during low wind speed conditions due to weak vertical turbulent mixing. Although further SWI measurements at a higher vertical resolution are required to validate these findings, the simultaneous SWI measurements at several heights during ACE show the potential of SWIs as tracers for vertical mixing and sea spray evaporation in the lowermost marine boundary layer.

scholarly journals Isotopic composition of rainwater nitrate at Bermuda: The influence of air mass source and chemistry in the marine boundary layer

2013 ◽  
Vol 118 (19) ◽  
pp. 11,304-11,316 ◽  
Author(s):  
K. E. Altieri ◽  
M. G. Hastings ◽  
A. R. Gobel ◽  
A. J. Peters ◽  
D. M. Sigman
Keyword(s):  
Boundary Layer ◽  
Isotopic Composition ◽  
Marine Boundary Layer ◽  
Mass Source ◽  
Air Mass
Sign in / Sign up

Export Citation Format

Share Document