scholarly journals The stable isotope composition of water vapour above Corsica during the HyMeX SOP1: insight into vertical mixing processes from lower-tropospheric survey flights

2016 ◽  
Author(s):  
Harald Sodemann ◽  
Franziska Aemisegger ◽  
Stephan Pfahl ◽  
Mark Bitter ◽  
Ulrich Corsmeier ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Stable Isotope ◽  
Water Vapour ◽  
Isotope Composition ◽  
Water Isotopes ◽  
High Temporal Resolution ◽  
Stable Isotope Composition ◽  
Stable Water Isotopes ◽  
Mixing Processes ◽  
Strong Inversion

Abstract. Stable water isotopes are powerful indicators of meteorological processes on a broad range of scales, reflecting evaporation, condensation, and airmass mixing processes. With the recent advent of fast laser-based spectroscopic methods it has become possible to measure the stable isotopic composition of atmospheric water vapour in situ at high temporal resolution, enabling to tremendously extend the measurement data base in space and time. Here we present the first set of airborne spectroscopic stable water isotopes measurements over the western Mediterranean. Measurements have been acquired by a customised Picarro L2130-i cavity-ring down spectrometer deployed onboard of the Dornier 128 D-IBUF aircraft together with a meteorological flux measurement package during the HyMeX SOP1 field campaign in Corsica, France during September and October 2012. Taking into account memory effects of the air inlet pipe, the typical time resolution of the measurements was about 15–30 s, resulting in an average horizontal resolution of about 1–2 km. Cross-calibration of the water vapour measurements from all humidity sensors showed good agreement in most flight conditions but the most turbulent ones. In total 21 successful stable isotope flights with 59 flight hours have been performed. Our data provide quasi-climatological autumn average conditions of the stable isotope parameters δD, δ18O and d-excess during the study period. A time-averaged perspective of the vertical stable isotope composition reveals for the first time the mean vertical structure of stable water isotopes over the Mediterranean at high resolution. A d-excess minimum in the overall average profile is reached in the region of the boundary layer top due to precipitation evaporation, bracketed by higher d-excess values near the surface due to non-equilibrium fractionation and above the boundary layer due to the non-linearity of the d-excess definition. Repeated flights along the same pattern reveals pronounced day-to-day variability due to changes in the large-scale circulation. During a period marked by a strong inversion at the top of the marine boundary layer, vertical gradients in stable isotopes reached up to 25.4 ‰ 100 m−1 for δD.

scholarly journals The stable isotopic composition of water vapour above Corsica during the HyMeX SOP1 campaign: insight into vertical mixing processes from lower-tropospheric survey flights

2017 ◽  
Vol 17 (9) ◽  
pp. 6125-6151 ◽  
Author(s):  
Harald Sodemann ◽  
Franziska Aemisegger ◽  
Stephan Pfahl ◽  
Mark Bitter ◽  
Ulrich Corsmeier ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Stable Isotopes ◽  
Stable Isotope ◽  
Isotopic Composition ◽  
Water Vapour ◽  
Temporal Resolution ◽  
Mixing Processes ◽  
Stable Isotopic Composition ◽  
Strong Inversion ◽  
Stable Isotopic

Abstract. Stable isotopes of water vapour are powerful indicators of meteorological processes on a broad range of scales, reflecting evaporation, condensation, and air mass mixing processes. With the recent advent of fast laser-based spectroscopic methods, it has become possible to measure the stable isotopic composition of atmospheric water vapour in situ at a high temporal resolution. Here we present results from such comprehensive airborne spectroscopic isotope measurements in water vapour over the western Mediterranean at a high spatial and temporal resolution. Measurements have been acquired by a customized Picarro L2130-i cavity-ring down spectrometer deployed onboard the Dornier 128 D-IBUF aircraft together with a meteorological flux measurement package during the HyMeX SOP1 (Hydrological cycle in Mediterranean Experiment special observation period 1) field campaign in Corsica, France, during September and October 2012. Taking into account memory effects of the air inlet pipe, the typical time resolution of the measurements was about 15–30 s, resulting in an average horizontal resolution of about 1–2 km. Cross-calibration of the water vapour measurements from all humidity sensors showed good agreement under most flight conditions but the most turbulent ones. In total 21 successful stable isotope flights with 59 flight hours have been performed. Our data provide quasi-climatological autumn average conditions and vertical profiles of the stable isotope parameters δD, δ18O, and d-excess during the study period. A d-excess minimum in the overall average profile is reached in the region of the boundary-layer top, possibly caused by precipitation evaporation. This minimum is bracketed by higher d-excess values near the surface caused by non-equilibrium fractionation, and a maximum above the boundary layer related to the increasing d-excess in very depleted and dry high-altitude air masses. Repeated flights along the same pattern reveal pronounced day-to-day variability due to changes in the large-scale circulation. During a period marked by a strong inversion at the top of the marine boundary layer, vertical gradients in stable isotopes reached up to 25.4 ‰ 100 m−1 for δD and 24.0 ‰ 100 m−1 for the d-excess.

Water vapour and precipitation isotope measurements from different platforms during the IGP campaign, Iceland, in 2018 connect evaporation sources to precipitation sinks

2020 ◽  
Author(s):  
Harald Sodemann ◽  
Alexandra Touzeau ◽  
Chris Barrell ◽  
John F. Burkhart ◽  
Andrew Elvidge ◽  
...  
Keyword(s):  
Stable Isotope ◽  
Data Quality ◽  
Water Vapour ◽  
Isotope Composition ◽  
Cloud Microphysics ◽  
Heat Fluxes ◽  
The Arctic ◽  
Stable Water Isotopes ◽  
Coupled Models ◽  
Isotope Measurements

<p>The water cycle in atmospheric and coupled models is a major contributor to model uncertainty, in particular at high-latitudes, where contrasts between ice-covered regions and the open ocean fuel intense heat fluxes. However, observed atmospheric vapour concentrations do not allow us to disentangle the contributions of different processes, such as evaporation, mixing, and cloud microphysics, to the overall moisture budget. As a natural tracer, stable water isotopes provide access to the moisture sources and phase change history of atmospheric water vapour and precipitation.</p><p>Here we present a unique dataset of stable isotope measurements in water vapour and precipitation from the IGP (Iceland Greenland Seas Project) field campaign that took place during February and March 2018. The dataset includes simultaneous measurements from three platforms (a land-station at Husavik, Iceland, the R/V Alliance, and a Twin Otter aircraft) during winter conditions in the Arctic region. Precipitation was collected on an event basis on the research ship, and along two north-south transects in Northern Iceland, and analysed at two stable isotope laboratories. Airborne vapour isotope data was obtained from 10 flights covering a large geographic range (64 °N to 72 °N). Careful data treatment was applied to all stable isotope measurements to ensure sufficient data quality in a challenging measurement environment with predominantly cold and dry conditions, and characterised by strong isotope and humidity gradients. Data quality was confirmed by inter-comparison of the vapour isotope measurements both between ship and aircraft, and between the aircraft and Husavik station.</p><p>We exemplify the value of the observations from the analysis of several flights dedicated to the study of the atmosphere-ocean interactions, from low-levels legs and vertical sections across the boundary layer during Cold Air Outbreak (CAO) conditions. The precipitation in Northern Iceland collected at the precipitation sampling network shows clear co-variation with the upstream water vapour measurements at Husavik station, indicative of the wider spatial representativeness of the isotope signals. The land-based snow and vapour measurements are furthermore consistent with the isotope composition in upstream ocean regions sampled by the research vessel, and as linked from aircraft measurements.</p>

Airborne water vapor isotope measurements over the Iceland Sea in winter conditions

2021 ◽  
Author(s):  
Alexandra Touzeau ◽  
Hans-Christian Steen-Larsen ◽  
Ian Renfrew ◽  
Þorsteinn Jónsson ◽  
Andrew Elvidge ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Stable Isotope ◽  
Sea Ice ◽  
Water Vapour ◽  
Cloud Cover ◽  
Isotope Composition ◽  
Specific Humidity ◽  
Free Troposphere ◽  
Cold Air ◽  
Isotope Measurements

<p>Improved understanding of evaporation and condensation processes is critical to improve the representation of the water cycle in atmospheric models. Thereby, in-situ measurements along the entire moisture transport pathway, covering evaporation, mixing between different air masses in the atmospheric boundary layer and the free troposphere, and resulting precipitation are highly valuable to obtain new insight. In particular, coherent measurements of the stable isotope composition in atmospheric vapour can provide additional constraints on phase change processes of water vapour from source to sink, enabling direct comparison within isotope-enabled models.</p><p>Here we present stable isotope measurements from the Iceland Greenland Seas Project field campaign that took place in February-March 2018. This unique dataset includes simultaneous measurements from a land-station in Husavik, Iceland, a ship and an air plane in the subpolar region. Alternation between cold-air outbreaks and mid-latitude airmasses characterized the measurement period. Here we focus on the stable water isotope composition in water vapour obtained from 10 research flights, covering a large geographic range (64 °N to 72 °N). Careful data treatment was applied to ensure the quality of isotope measurements in the predominant cold, dry conditions with large gradients in isotope composition and humidity.</p><p>From an intercomparison flight over the Husavik station, we find good agreement between ground and airborne measurements. Out of 7 flights dedicated to the study of atmosphere-ocean-ice interactions, with both low-levels legs and vertical sections in predominant Cold Air Outbreak (CAO) conditions, we focus on the marginal ice zone and regions covered by shallow cumulus clouds. For open water flights, we find the horizontal and vertical distribution of δ<sup>18</sup>O in the marine boundary layer to covary with cloud cover. Thereby, downdrafts bring dry and <sup>18</sup>O-depleted air from the free troposphere towards the surface, corresponding to openings in cloud cover. For flights passing over sea ice edge, both δ<sup>18</sup>O and specific humidity show a clear east-west gradient, with increasing values towards the open sea reflecting ocean moisture availability. Additionally, open leads in the sea ice also have a visible impact on isotope values. Lastly, relatively low d-excess values are observed over the sea-ice, which could either be caused by local processes or advection.</p>

scholarly journals Chemical and stable isotope composition of surface and groundwater in the surroundings of the Los Humeros Caldera, Puebla, Mexico

2019 ◽  
Vol 98 ◽  
pp. 07013
Author(s):  
Thomas Kretzschmar ◽  
Matteo Lelli ◽  
Ruth Alfaro ◽  
Juan Ignacio Sanchez ◽  
Yann Rene Ramos
Keyword(s):  
Stable Isotope ◽  
Isotope Composition ◽  
Regression Line ◽  
Sustainable Use ◽  
Geothermal Reservoir ◽  
Maximum Temperature ◽  
Stable Isotope Composition ◽  
Local Fracture ◽  
Hydrogeological Model ◽  
Fracture Systems

It is important to develop a regional hydrogeological model to identify possible recharge and discharge areas for a sustainable use of a geothermal reservoir. The Los Humeros geothermal area is situated within five surficial watersheds and coveres an area of more than 15.000 km2. A total of 208 well and spring samples were collected between June 2017 and November 2018. The stable isotope data for this region define a regression line of δDH2O = 8.032·δ18O + 12 and indicate that groundwater is recharged by regional precipitation. At least 39 groundwater wells, with a maximum temperature of 35 °C, show temperatures above the reported mean average surface temperature of 15 °C. Characteristic elements for geothermal reservoir fluids (B, Li, As) are also present in these groundwaters, indicating a possible connection between the reservoir fluid and the local groundwater through local fracture systems. Concentration of B in these hot wells is between 150 and 35000 ppb.

scholarly journals Trophic Relationships and Habitat Preferences of Delphinids from the Southeastern Brazilian Coast Determined by Carbon and Nitrogen Stable Isotope Composition

PLoS ONE ◽  
2013 ◽  
Vol 8 (12) ◽  
pp. e82205 ◽  
Author(s):  
Tatiana Lemos Bisi ◽  
Paulo Renato Dorneles ◽  
José Lailson-Brito ◽  
Gilles Lepoint ◽  
Alexandre de Freitas Azevedo ◽  
...  
Keyword(s):  
Stable Isotope ◽  
Isotope Composition ◽  
Habitat Preferences ◽  
Trophic Relationships ◽  
Brazilian Coast ◽  
Stable Isotope Composition ◽  
Nitrogen Stable Isotope ◽  
Carbon And Nitrogen
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