CO2 Capture and Storage from Flue Gas Using Novel Gas Hydrate-Based Technologies and Their Associated Impacts

2020 ◽  
Author(s):  
Aliakbar Hassanpouryouzband ◽  
Katriona Edlmann ◽  
Jinhai Yang ◽  
Bahman Tohidi ◽  
Evgeny Chuvilin
Keyword(s):  
Gas Hydrate ◽  
Flue Gas ◽  
Power Plants ◽  
Carbon Capture And Storage ◽  
Hydrate Formation ◽  
Gas Hydrate Formation ◽  
Experimental Apparatus ◽  
The Impact ◽  
And Storage ◽  
Hydrate Reservoirs

<p>Power plants emit large amounts of carbon dioxide into the atmosphere primarily through the combustion of fossil fuels, leading to accumulation of increased greenhouse gases in the earth’s atmosphere. Global climate changing has led to increasing global mean temperatures, particularly over the poles, which threatens to melt gas hydrate reservoirs, releasing previously trapped methane and exacerbating the situation.  Here we used gas hydrate-based technologies to develop techniques for capturing and storing CO<sub>2</sub> present in power plant flue gas as stable hydrates, where CO<sub>2</sub> replaces methane within the hydrate structure. First, we experimentally measured the thermodynamic properties of various flue gases, followed by modelling and tuning the equations of state. Second, we undertook proof of concept investigations of the injection of CO2 flue gas into methane gas hydrate reservoirs as an option for economically sustainable production of natural gas as well as carbon capture and storage. The optimum injection conditions were found and reaction kinetics was investigated experimentally under realistic conditions. Third, the kinetics of flue gas hydrate formation for both the geological storage of CO<sub>2</sub> and the secondary sealing of CH<sub>4</sub>/CO<sub>2</sub> release in one simple process was investigated, followed by a comprehensive investigation of hydrate formation kinetics using a highly accurate in house developed experimental apparatus, which included an assessment of the gas leakage risks associated with above processes.  Finally, the impact of the proposed methods on permeability and mechanical strength of the geological formations was investigated.</p>

scholarly journals Rapid Gas Hydrate Formation—Evaluation of Three Reactor Concepts and Feasibility Study

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3615
Author(s):  
Florian Filarsky ◽  
Julian Wieser ◽  
Heyko Juergen Schultz
Keyword(s):  
Gas Hydrates ◽  
Gas Hydrate ◽  
Hydrate Formation ◽  
Synthetic Natural Gas ◽  
Operation Conditions ◽  
Gas Hydrate Formation ◽  
Gas Conditioning ◽  
And Storage ◽  
Economic Considerations ◽  
High Storage

Gas hydrates show great potential with regard to various technical applications, such as gas conditioning, separation and storage. Hence, there has been an increased interest in applied gas hydrate research worldwide in recent years. This paper describes the development of an energetically promising, highly attractive rapid gas hydrate production process that enables the instantaneous conditioning and storage of gases in the form of solid hydrates, as an alternative to costly established processes, such as, for example, cryogenic demethanization. In the first step of the investigations, three different reactor concepts for rapid hydrate formation were evaluated. It could be shown that coupled spraying with stirring provided the fastest hydrate formation and highest gas uptakes in the hydrate phase. In the second step, extensive experimental series were executed, using various different gas compositions on the example of synthetic natural gas mixtures containing methane, ethane and propane. Methane is eliminated from the gas phase and stored in gas hydrates. The experiments were conducted under moderate conditions (8 bar(g), 9–14 °C), using tetrahydrofuran as a thermodynamic promoter in a stoichiometric concentration of 5.56 mole%. High storage capacities, formation rates and separation efficiencies were achieved at moderate operation conditions supported by rough economic considerations, successfully showing the feasibility of this innovative concept. An adapted McCabe-Thiele diagram was created to approximately determine the necessary theoretical separation stage numbers for high purity gas separation requirements.

scholarly journals Screening of Amino Acids and Surfactant as Hydrate Promoter for CO2 Capture from Flue Gas

Processes ◽  
2020 ◽  
Vol 8 (1) ◽  
pp. 124 ◽  
Author(s):  
Pandey ◽  
Daas ◽  
Solms
Keyword(s):  
Amino Acids ◽  
Gas Hydrate ◽  
Flue Gas ◽  
Sodium Dodecyl ◽  
Hydrate Formation ◽  
Bulk Water ◽  
Gas Hydrate Formation ◽  
Hydropathy Index ◽  
Hydrophobic Amino Acids ◽  
Kinetics Of

In this study, the kinetics of flue gas hydrate formation in bulk water in the presence of selected amino acids and surfactants are investigated. Four amino acids (3000 ppm) are selected based on different hydropathy index. Constant-ramping and isothermal experiments at 120 bar pressure and 1 °C temperature are carried out to compare their hydrate promotion capabilities with surfactant sodium dodecyl sulfate (SDS) (500–3000 ppm) and water. Based on experimental results, we report the correlation between hydrate promotion capability of amino acids and their hydrophobicity. Hydrophobic amino acids show stronger flue gas hydrate promotion capability than water and hydrophilic amino acids. We discuss the controlling mechanisms to differentiate between promoters and inhibitors’ roles among the amino acids. Between 2000–3000 ppm concentrations, hydrophobic amino acids have near similar promotion capabilities as SDS. This research highlights the potential use of amino acids as promoters or inhibitors for various applications.

Insights into CO2 Capture by Flue Gas Hydrate Formation: Gas Composition Evolution in Systems Containing Gas Hydrates and Gas Mixtures at Stable Pressures

2018 ◽  
Vol 6 (5) ◽  
pp. 5732-5736 ◽  
Author(s):  
Aliakbar Hassanpouryouzband ◽  
Jinhai Yang ◽  
Bahman Tohidi ◽  
Evgeny Chuvilin ◽  
Vladimir Istomin ◽  
...  
Keyword(s):  
Co2 Capture ◽  
Gas Hydrates ◽  
Gas Hydrate ◽  
Flue Gas ◽  
Hydrate Formation ◽  
Gas Mixtures ◽  
Gas Composition ◽  
Gas Hydrate Formation

scholarly journals Effect of Propane and NaCl-SDS Solution on Nucleation Process of Mine Gas Hydrate

2017 ◽  
Vol 2017 ◽  
pp. 1-12 ◽  
Author(s):  
Qiang Zhang ◽  
Qiang Wu ◽  
Hui Zhang
Keyword(s):  
Gas Hydrate ◽  
Induction Time ◽  
Equilibrium Points ◽  
Sodium Dodecyl ◽  
Hydrate Formation ◽  
Nucleation Process ◽  
Nucleation Kinetics ◽  
Gas Hydrate Formation ◽  
Experimental Apparatus ◽  
Mine Gas

In order to explore the method of accelerating hydration separation process to recover methane from mine gas, propane hydrate phase equilibrium was used to measure the equilibrium points of three kinds of mine gas in NaCl solution. Driving force was set as 1 MPa on this basis and high-pressure experimental apparatus of mine gas hydrate was used to carry out the nucleation kinetics experiments of mine gas hydrate for three gas samples in different concentrations of sodium chloride (NaCl) and sodium dodecyl sulfate (SDS) compound systems, which was to study the effect of propane and NaCl-SDS solution on nucleation process of mine gas hydrate. The results showed that induction time of multicomponent mine gas hydrate formation was shortened with the decrease of methane concentration and increase of propane concentration. The induction time of mine gas hydrate formation was shortened with the reduction of NaCl concentration and the increase of SDS concentration. It was found that methane and propane in multicomponent mine gas nucleated collaboratively, which simplified its nucleation process compared with the single component. NaCl has two kinds of functions.

Formation Kinetics and Self-Preservation of CO2 Hydrates in the Presence of Carboxylated Multiwall Carbon Nanotubes

2021 ◽  
Author(s):  
Khalik Mohamad Sabil ◽  
Omar Nashed ◽  
Bhajan Lal ◽  
Khor Siak Foo
Keyword(s):  
Gas Hydrate ◽  
Induction Time ◽  
Completion Time ◽  
Formation Rate ◽  
Sodium Dodecyl ◽  
Hydrate Formation ◽  
Significant Finding ◽  
Formation Kinetic ◽  
Gas Hydrate Formation ◽  
The Impact

Abstract Nanofluids are known of having the capability to increase heat and mass transfer and their suitability to be used as kinetic gas hydrate promoters have been recently investigated. They have favorable properties such as high thermal conductivity, large surface area, recyclable, ecofriendly, and relatively cheap that are favorable for kinetic gas hydrate promoters. However, the nanomaterials face challenges related to their stability in the base fluid. Therefore, it is crucial to investigate the impact of surfactant free nanofluid on hydrate formation and dissociation kinetics. In this work, COOH-MWCNT suspended in water is used to study the effect of surfactant free nanofluid on CO2 hydrates formation kinetic and stability. Kinetic study on CO2 hydrates formation as well as self-preservation are conducted in a stirred tank reactor. The kinetic experiments are carried out at 2.7 MPa and 274.15 K. The induction time, initial gas consumption rate, half-completion time t50, semi completion time t95 are measured to evaluate the effect of COOH-MWCNT. Furthermore, the dissociation rate was calculated to assess the impact of COOH-MWCNT on self-preservation at 271.15 K and atmospheric pressure. The results are compared with that of sodium dodecyl sulphate (SDS). The study of CO2 hydrates formation kinetic shows that the induction time is not affected by COOH-MWCNT. The impact of nanofluid is more pronounced during the hydrate growth. The initial formation rate is the highest at 0.01 wt% of COOH-MWCNT whereas 0.01 and 0.03 wt% shows the same and shortest t50. However, t95 found to be decreased with increasing the concentration. The effect of COOH-MWCNT is attributed to the strong functional group. Self-preservation results shows CO2 hydrates are less stable in the presence of COOH-MWCNT. The result of this work may provide significant finding that can be used to developed kinetic gas hydrate promoter based on nanofluid that work better than SDS to eliminate gas hydrate formation in oil and gas pipeline.

Transporting the Next Generation of CO2 for Carbon, Capture and Storage: The Impact of Impurities on Supercritical CO2 Pipelines

2008 ◽  
Author(s):  
Patricia N. Seevam ◽  
Julia M. Race ◽  
Martin J. Downie ◽  
Phil Hopkins
Keyword(s):  
Carbon Dioxide ◽  
Carbon Capture ◽  
Power Plants ◽  
Fossil Fuel ◽  
Carbon Capture And Storage ◽  
Transport Infrastructure ◽  
New Generation ◽  
The Impact ◽  
And Storage ◽  
Fossil Fuel Power Plants

Climate change has been attributed to greenhouse gases with carbon dioxide (CO2) being the major contributor. Most of these CO2 emissions originate from the burning of fossil fuels (e.g. power plants). Governments and industry worldwide are now proposing to capture CO2 from their power plants and either store it in depleted reservoirs or saline aquifers (‘Carbon Capture and Storage’, CCS), or use it for ‘Enhanced Oil Recovery’ (EOR) in depleting oil and gas fields. The capture of this anthropogenic (man made sources of CO2) CO2 will mitigate global warming, and possibly reduce the impact of climate change. The United States has over 30 years experience with the transportation of carbon dioxide by pipeline, mainly from naturally occurring, relatively pure CO2 sources for onshore EOR. CCS projects differ significantly from this past experience as they will be focusing on anthropogenic sources from major polluters such as fossil fuel power plants, and the necessary CO2 transport infrastructure will involve both long distance onshore and offshore pipelines. Also, the fossil fuel power plants will produce CO2 with varying combinations of impurities depending on the capture technology used. CO2 pipelines have never been designed for these differing conditions; therefore, CCS will introduce a new generation of CO2 for transport. Application of current design procedures to the new generation pipelines is likely to yield an over-designed pipeline facility, with excessive investment and operating cost. In particular, the presence of impurities has a significant impact on the physical properties of the transported CO2 which affects: pipeline design; compressor/pump power; repressurisation distance; pipeline capacity. These impurities could also have implications in the fracture control of the pipeline. All these effects have direct implications for both the technical and economic feasibility of developing a carbon dioxide transport infrastructure onshore and offshore. This paper compares and contrasts the current experience of transporting CO2 onshore with the proposed transport onshore and offshore for CCS. It covers studies on the effect of physical and transport properties (hydraulics) on key technical aspects of pipeline transportation, and the implications for designing and operating a pipeline for CO2 containing impurities. The studies reported in the paper have significant implications for future CO2 transportation, and highlight a number of knowledge gaps that will have to be filled to allow for the efficient and economic design of pipelines for this ‘next’ generation of anthropogenic CO2.

Effect of surfactants and liquid hydrocarbons on gas hydrate formation rate and storage capacity

2003 ◽  
Vol 27 (8) ◽  
pp. 747-756 ◽  
Author(s):  
Zhigao Sun ◽  
Ruzhu Wang ◽  
Rongsheng Ma ◽  
Kaihua Guo ◽  
Shuanshi Fan
Keyword(s):  
Gas Hydrate ◽  
Storage Capacity ◽  
Formation Rate ◽  
Hydrate Formation ◽  
Liquid Hydrocarbons ◽  
Gas Hydrate Formation ◽  
And Storage

Review the impact of nanoparticles on the thermodynamics and kinetics of gas hydrate formation

2018 ◽  
Vol 55 ◽  
pp. 452-465 ◽  
Author(s):  
Omar Nashed ◽  
Behzad Partoon ◽  
Bhajan Lal ◽  
Khalik M. Sabil ◽  
Azmi Mohd Shariff
Keyword(s):  
Gas Hydrate ◽  
Hydrate Formation ◽  
Thermodynamics And Kinetics ◽  
Gas Hydrate Formation ◽  
The Impact ◽  
Kinetics Of
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