Mineralogy, textural characteristics and mineral chemistry of remobilised sulphides and sulphosalts in the Rävliden Norra VMS deposit, Skellefte district, northern Sweden

2020 ◽  
Author(s):  
Jonathan Rincon ◽  
Simon Johansson ◽  
Nils Jansson ◽  
Helen Thomas ◽  
Majka Christiane Kaiser ◽  
...  
Keyword(s):  
Boundary Migration ◽  
Hanging Wall ◽  
Volcanic Rocks ◽  
Mineral Chemistry ◽  
Massive Sulphide ◽  
Ductile Deformation ◽  
Sulphide Mineralization ◽  
Micro Scale ◽  
Metasedimentary Rocks ◽  
Skellefte District

<p>Remobilisation of sulphides in metamorphosed volcanic-hosted massive sulphide deposits has been investigated in many VMS districts with regards to scale, mineral assemblages, texture and relative competence of minerals under certain p-t conditions (Gilligan & Marshall, 1987; Marshall & Gilligan, 1987). Examples of syn-tectonic remobilisation can be found at the Rävliden Norra (RVN) volcanic-hosted massive sulphide in the Skellefte district. At Rävliden, polymetallic sulphide mineralization occurs at the transition from meta-volcanic rocks of the Skellefte group rocks to the overlying Vargfors group, comprising volcaniclastic metasedimentary rocks and graphitic shales. This contribution details features of mesoscale (0.1-50 cm) remobilisation of sulphides, such as sulphide-rich veins, tension gashes, ball-ore, massive sulphides with cataclastic texture, and micro-scale features such as infilling of pressure shadows, displaying evidences of brittle and ductile deformation. Sulphide-rich veins containing sphalerite, galena, and a relative high content of Ag-sulphosalts (e.g. freibergite, pyrargyrite, pyrostilpnite) are hosted in the hanging wall (HW) of the RVN mineralization. Brittle deformation is shown in accessory quartz and calcite as bulging recrystallization, grain boundary migration and deformation lamellae or twinning. Ductile expressions include ball-ore (i.e. “durchbewegung”) textures, typically made up of two components, one composed of clasts of graphite shale or tremolite-, actinolite-, talc-altered meta-volcanic rocks and the other comprising a matrix of massive sulphide mineralization. In the massive sulphide matrix of sphalerite, chalcopyrite or pyrrhotite, micro-scale tension gashes and/or pressure shadows occur around clasts infilled by pyrrhotite, chalcopyrite, galena, freibergite, boulangerite, or gudmundite. A similar mineralogy is observed in ore lenses in the ore zone, comprising sphalerite, galena and Ag-Sb-As sulphosalts, hosted structurally above chalcopyrite + pyrrhotite stringer zones in the footwall (FW). Sulphosalts and galena present a high silver content relative to other VMS deposits in the district. This is evidenced by SEM and EMPA analysis in both HW and FW ore lenses. Argentopyrite, sternbergite and stephanite are also locally present in the HW as minor silver species hosted in veins. Inclusions of freibergite in galena contain Ag with average values of 18.4 wt. % in the HW (n=5), 18 wt. % in the massive sphalerite and ball-ore (n= 15), and 20.2 wt. % in the chalcopyrite + pyrrhotite stringer zone (n= 5). Similarly, Pb is 0.2 wt. %, 0.3 wt. %, and 0.4 wt. %, respectively. For sphalerite, Fe is on average 8.0 wt. % (n=3), 7.4 wt. % (n = 11), and 8.3 wt. % (n=3), respectively. Our preliminary results suggest that mineralization in the HW is remobilized from the main ore and textural relationships support a hypothesis that remobilisation involved a relative silver-enrichment in paragenetically later assemblages. At least two stages of deformation in the deposit can be recognized. In the first stage, sphalerite- and chalcopyrite-rich mineralization was deformed along with tremolite and talc to form a S1 foliation. The second stage involved folding of S1, and remobilisation of galena, chalcopyrite and Ag-Sb-As sulphosalts as veins or breccia infill in the HW or filling tension gaps or ball-ore, in the FW. These are often parallel to S2 crenulation or axial planes.</p>

Geological setting, U–Pb geochronology, and radiogenic isotopic characteristics of the Permo-Triassic Kutcho Assemblage, north-central British Columbia

1997 ◽  
Vol 34 (10) ◽  
pp. 1310-1324 ◽  
Author(s):  
Fiona C. Childe ◽  
John F.H. Thompson
Keyword(s):  
Hanging Wall ◽  
Volcanic Rocks ◽  
Isotopic Signature ◽  
Massive Sulphide ◽  
Pyroclastic Flows ◽  
Sulphide Mineralization ◽  
Isotopic Signatures ◽  
Arc Magmas ◽  
Volcanogenic Massive Sulphide ◽  
Mass Flows

The Kutcho Assemblage is a latest Permian to Early Triassic volcano-sedimentary sequence within the fault-bounded King Salmon Allochthon. Volcanic and volcaniclastic rocks consist of massive to pillowed flows and tuffs of basaltic to basaltic andesitic composition, as well as flows, mass flows, and pyroclastic flows of rhyodacitic to rhyolitic composition. The volcanic sequence is intruded by gabbro, diorite, trondhjemite, and quartz–plagioclase porphyry. Volcanic and intrusive rocks have tholeiitic magmatic affinities, with die exception of the gabbro sills and dykes, which are chemically similar to alkaline arc magmas. Cu–Zn volcanogenic massive sulphide mineralization at die Kutcho Creek deposit is hosted by rhyolite mass flows near me top of the Kutcho Assemblage. Rhyolite mass flows from the hanging wall and footwall to mineralization have U–Pb ages of 242 ± 1 and [Formula: see text], respectively, whereas a quartz–plagioclase porphyritic intrusion to the south of the mineralization has a U–Pb age of 244 ± 6 Ma. The dates determined in this study constrain a previously unknown age for massive sulphide mineralization in the Canadian Cordillera. Furthermore, the age of the Kutcho Assemblage and the primitive Pb isotopic signature of its contained syngenetic mineralization (207Pb/206Pb = 0.83988–0.84112 and 208Pb/206Pb = 2.0517–2.0556) are inconsistent with formation as part of the adjacent Stikine or Quesnel terranes. Primitive Nd isotopic signatures (εNd(initial) = +7.5 to +9.1) and trace and rare earth element chemistry indicate that volcanic rocks of the Kutcho Assemblage, related intrusions, and volcanogenic massive sulphide mineralization formed in an intraoceanic island arc environment, probably directly on oceanic crustal basement. Gabbro sills and dykes, which are interpreted to be slightly younger than volcanic rocks of the Kutcho Assemblage, appear to have formed in response to a change in the tectonic regime, perhaps as a result of a collisional event.

Polyphase tectonothermal events recorded in metamorphic basement rocks from the northern Altyn Tagh, southeastern Tarim Craton

2020 ◽  
Author(s):  
Zhongmei Wang ◽  
Chunming Han ◽  
Wenjiao Xiao ◽  
Patrick Asamoah Sakyi
Keyword(s):  
Tectonic Setting ◽  
Volcanic Rocks ◽  
Mineral Chemistry ◽  
Metasedimentary Rocks ◽  
Exposed Rock ◽  
Altyn Tagh ◽  
Argillaceous Rocks ◽  
Southeastern Margin ◽  
Minimum Age ◽  
Tarim Craton

<p>  Paleoproterozoic is a pivotal time for understanding the geochronological framework of the Tarim Craton. Located on the southeastern margin of the Tarim Craton, the northern Altyn Tagh is the main exposed region for Paleoproterozoic magmatic-metamorphic rocks. These rocks are diverse, diachronous and modified by multiple magmatic and/or metamorphic events. In this study, we performed systematic analyses on the amphibolite, felsic gneisses, and metasedimentary rocks in the Aketashitage area, southeastern Tarim Craton, including petrography, mineral chemistry, and whole-rock geochemistry, as well as in-situ zircon U-Pb ages and Hf isotopes, to examine the Paleoproterozoic magmatic-metamorphic events in the northern Altyn Tagh. Geochemically, the amphibolite and felsic gneisses in the Aketashitage area seemingly represent the typical bimodal associations of mafic and acidic volcanic rocks. In addition, the felsic gneisses are characterized by high Sr and low Y contents, with high Sr/Y and La<sub>N</sub>/Yb<sub>N</sub> ratios, and indistinctive Eu anomalies, closely resembling high-SiO<sub>2</sub> adakites derived from subducted basaltic slab-melt. The palimpsest textures and geochemical features of the Aketashitage metasedimentary rocks suggest that their protoliths are argillaceous rocks. The amphibolite has a metamorphic age of 1.96 Ga, and the felsic gneisses yield crystallization ages of 2.54-2.52 Ga. For the metasedimentary rocks, the major age peaks of 2.72 Ga, 2.05 Ga and 1.97 Ga are consistent with the magmatic and/or metamorphic events in the study area. The minimum age peak suggests that the depositional age is no earlier than 1.97 Ga. The geochemical and geochronological evidences documented by the exposed rock associations in the Aketashitage area suggest a subduction-related tectonic setting in the Paleoproterozoic. Our new data combined with the previous studies indicate that the Paleoproterozoic magmatism and metamorphism in the northern Altyn Tagh area are nearly synchronous, and both are likely related to oceanic subduction.</p>

Petrogenesis of the 1.9 Ga mafic hanging wall sequence to the Flin Flon, Callinan, and Triple 7 massive sulphide deposits, Flin Flon, Manitoba, CanadaThis is a companion paper to DeWolfe, Y.M., Gibson, H.L., Lafrance , B., and Bailes, A.H. 2009. Volcanic reconstruction of Paleoproterozoic arc volcanoes: the Hidden and Louis formations, Flin Flon, Manitoba, Canada. Canadian Journal of Earth Sciences, 46: this issue.

2009 ◽  
Vol 46 (7) ◽  
pp. 509-527 ◽  
Author(s):  
Y. M. DeWolfe ◽  
H. L. Gibson ◽  
S. J. Piercey
Keyword(s):  
Oceanic Crust ◽  
Basaltic Andesite ◽  
Hanging Wall ◽  
Volcanic Rocks ◽  
Companion Paper ◽  
Massive Sulphide ◽  
Massive Sulphide Deposits ◽  
Volcanogenic Massive Sulphide ◽  
Flin Flon ◽  
Sulphide Deposits

A detailed study of the geochemical and isotopic characteristics of the volcanic rocks of the Hidden and Louis formations, which make up the hanging wall to the volcanogenic massive sulphide deposits at Flin Flon, Manitoba, was carried out on a stratigraphically controlled set of samples. The stratigraphy consists of the lowermost, dominantly basaltic, Hidden formation, and the overlying, dominantly basaltic, Louis formation. Of importance petrogenetically, is the 1920 unit a basaltic andesite with Nb/Thmn = 0.54–0.62, εNd(1.9Ga) = +3.6–+5.9, εHf(1.9Ga) = +8.5–+9.6, and 204Pb/206Pb = 23.9. The basaltic flows that dominate the Hidden formation have Nb/Thmn = 0.16–0.29, εNd(1.9Ga) = +1.7–+4.4, εHf(1.9Ga) = +7.0–+11.8 and 204Pb/206Pb = 16.9–18.6). The Carlisle Lake basaltic–andesite (top of Hidden formation) is characterized by Nb/Thmn = 0.16–0.14, and 204Pb/206Pb = 21.4. The rhyodacitic Tower member (bottom of Louis formation) has Nb/Thmn = 0.23, εNd1.9Ga = +4.6, εHf1.9Ga = +9.3, and 204Pb/206Pb = 22.2. The basaltic flows that dominate the Louis formation have Nb/Thmn = 0.18–0.25, εNd(1.9Ga) = +3.6–+4.2, εHf(1.9Ga) = +8.4–+11.3 and 204Pb/206Pb = 17.9. The Hidden and Louis formations show dominantly transitional arc tholeiite signatures, with the 1920 unit having arc tholeiite characteristics. It is interpreted to have formed through extensive fractional crystallization of differentiated magmas at shallow levels in oceanic crust. Given the geological, geochemical, and isotopic characteristics of the Hidden and Louis formations, they are interpreted to represent subducted slab metasomatism with minor contamination from subducted sediments.

scholarly journals New zircon data supporting models of short-lived igneous activity at 1.89 Ga in the western Skellefte District, central Fennoscandian Shield

Solid Earth ◽  
2011 ◽  
Vol 2 (2) ◽  
pp. 205-217 ◽  
Author(s):  
P. Skyttä ◽  
T. Hermansson ◽  
J. Andersson ◽  
M. Whitehouse ◽  
P. Weihed
Keyword(s):  
Hanging Wall ◽  
Volcanic Rocks ◽  
New Age ◽  
Fennoscandian Shield ◽  
Time Interval ◽  
Zircon Age ◽  
Skellefte District ◽  
Field Evidence ◽  
Igneous Activity ◽  
Minimum Age

Abstract. New U-Th-Pb zircon data (SIMS) from three intrusive phases of the Palaeoproterozoic Viterliden intrusion in the western Skellefte District, central Fennoscandian Shield, dates igneous emplacement in a narrow time interval at about 1.89 Ga. A locally occurring quartz-plagioclase porphyritic tonalite, here dated at 1889 ± 3 Ma, is considered the youngest of the intrusive units, based on the new age data and field evidence. This supports an existing interpretation of its fault-controlled emplacement after intrusion of the dominating hornblende-tonalite units, in this study dated at 1892 ± 3 Ma. The Viterliden magmatism was synchronous with the oldest units of the Jörn type early-orogenic intrusions in the eastern part of the district (1.89–1.88 Ga; cf. Gonzàles Roldán, 2010). A U-Pb zircon age for a felsic metavolcanic rock from the hanging-wall to the Kristineberg VMS deposit, immediately south of the Viterliden intrusion, is constrained at 1883 ± 6 Ma in this study. It provides a minimum age for the Kristineberg ore deposit and suggests contemporaneous igneous/volcanic activity throughout the Skellefte District. Furthermore, it supports the view that the Skellefte Group defines a laterally continuous belt throughout this "ore district". Tentative correlation of the 1889 ± 3 Ma quartz-plagioclase porphyritic tonalite with the Kristineberg "mine porphyry" suggests that these units are coeval at about 1.89 Ga. Based on the new age determinations, the Viterliden intrusion may equally well have intruded into or locally acted as a basement for the ore-hosting Skellefte Group volcanic rocks.

scholarly journals New zircon data supporting models of short-lived igneous activity at 1.89 Ga in the western Skellefte District, central Fennoscandian Shield

2011 ◽  
Vol 3 (1) ◽  
pp. 355-383 ◽  
Author(s):  
P. Skyttä ◽  
T. Hermansson ◽  
J. Andersson ◽  
P. Weihed
Keyword(s):  
Hanging Wall ◽  
Volcanic Rocks ◽  
New Age ◽  
Fennoscandian Shield ◽  
Time Interval ◽  
Skellefte District ◽  
Field Evidence ◽  
Metavolcanic Rocks ◽  
Igneous Activity ◽  
Minimum Age

Abstract. New U-Th-Pb zircon data (SIMS) from three intrusive phases of the Palaeoproterozoic Viterliden intrusion in the western Skellefte District, central Fennoscandian Shield, dates igneous emplacement in a narrow time interval at about 1.89 Ga. A locally occurring quartz-plagioclase porphyritic tonalite, here dated at 1889 ± 3 Ma, is, based on the new age data and field evidence, considered the youngest of the intrusive units. This supports an existing interpretation of its fault-controlled emplacement after intrusion of the dominating hornblende-tonalite units, in this study dated at 1892 ± 3 Ma. The Viterliden magmatism was synchronous with the oldest units of the Jörn type early-orogenic intrusions in the eastern part of the district (1.89–1.88 Ga; cf. Gonzàles Roldán, 2010). A U-Pb zircon age for a felsic metavolcanic rock from the hanging-wall to the Kristineberg VMS deposit, immediately south of the Viterliden intrusion, is in this study constrained in the 1.89–1.88 Ga time interval. It provides a minimum age for the Kristineberg ore deposit and suggests contemporaneous igneous/volcanic activity throughout the Skellefte District. Furthermore, it supports the view that the Skellefte Group defines a laterally continuous belt throughout this "ore district". Tentative correlation of the 1889 ± 3 Ma quartz-plagioclase porphyritic tonalite with the Kristineberg "mine porphyry", which cuts the altered ore-hosting metavolcanic rocks, further constrain the minimum age for ore deposition at 1889 ± 3 Ma. Based on the new age determinations, the Viterliden intrusion may equally well have intruded into, or locally acted as a basement for the ore-hosting Skellefte Group volcanic rocks.

scholarly journals Geochemistry of Sphalerite from the Permian Volcanic-Hosted Massive Sulphide (VHMS) Deposits in the Tasik Chini Area, Peninsular Malaysia: Constraints for Ore Genesis

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 728
Author(s):  
Mohd Basril Iswadi Basori ◽  
Sarah E. Gilbert ◽  
Khin Zaw ◽  
Ross R. Large
Keyword(s):  
Variable Temperature ◽  
Mineral Chemistry ◽  
Peninsular Malaysia ◽  
Massive Sulphide ◽  
Compositional Variation ◽  
Volcanic Origin ◽  
Sedimentary Deposits ◽  
Depositional Processes ◽  
Tasik Chini ◽  
Vhms Deposits

The Bukit Botol and Bukit Ketaya deposits are two examples of volcanic-hosted massive sulphide (VHMS) deposits that occur in the Tasik Chini area, Central Belt of Peninsular Malaysia. The mineralisation is divided into subzones distinguished by spatial, mineralogical, and textural characteristics. The primary sulphide minerals include pyrite, chalcopyrite, sphalerite, and galena, with lesser amounts of Sn- and Ag-bearing minerals, with Au. However, pyrrhotite is absent from both deposits. This study presents the results of sphalerite chemistry analysed by using an electron microprobe. Two types of sphalerite are recognised: sphalerite from the Bukit Botol deposit reveals a range of <DL to 24.0 mole% FeS, whereas sphalerite from the Bukit Ketaya deposit shows a range of <DL to 3 mole% FeS. Significant variations are shown in Zn, Cu, Cd, and Ag levels. Although the sphalerite has a wide variation in composition, a discernible decreasing Fe trend is exhibited from the stringer zone towards massive sulphide. This compositional variation in sphalerites may in part reflect variable temperature and activity of sulphur in the hydrothermal fluids during ore formation. Alternatively, the bimodal composition variations suggest that mineral chemistry relates to contrasting depositional processes. The Zn/Cd ratios for sphalerite from both these deposits are similar to those exhibited by volcano−sedimentary deposits with a volcanic origin. Therefore, the consistently low Cd concentrations and moderate to high Zn/Cd ratios suggest mixing of seawater and minor magmatic fluids controlling the chemistry of sphalerite at both deposits during their formation.

scholarly journals Geochemical signatures of mineralizing events in the Juomasuo Au–Co deposit, Kuusamo belt, northeastern Finland

2021 ◽  
Author(s):  
Mikael Vasilopoulos ◽  
Ferenc Molnár ◽  
Hugh O’Brien ◽  
Yann Lahaye ◽  
Marie Lefèbvre ◽  
...  
Keyword(s):  
Trace Element ◽  
Sulfur Isotope ◽  
Mineral Chemistry ◽  
Chemical Compositions ◽  
Metasedimentary Rocks ◽  
Metavolcanic Rocks ◽  
Icp Ms ◽  
Stage 1 ◽  
Host Rocks ◽  
Relationship Of

AbstractThe Juomasuo Au–Co deposit, currently classified as an orogenic gold deposit with atypical metal association, is located in the Paleoproterozoic Kuusamo belt in northeastern Finland. The volcano-sedimentary sequence that hosts the deposit was intensely altered, deformed, and metamorphosed to greenschist facies during the 1.93–1.76 Ga Svecofennian orogeny. In this study, we investigate the temporal relationship between Co and Au deposition and the relationship of metal enrichment with protolith composition and alteration mineralogy by utilizing lithogeochemical data and petrographic observations. We also investigate the nature of fluids involved in deposit formation based on sulfide trace element and sulfur isotope LA-ICP-MS data together with tourmaline mineral chemistry and boron isotopes. Classification of original protoliths was made on the basis of geochemically immobile elements; recognized lithologies are metasedimentary rocks, mafic, intermediate-composition, and felsic metavolcanic rocks, and an ultramafic sill. The composition of the host rocks does not control the type or intensity of mineralization. Sulfur isotope values (δ34S − 2.6 to + 7.1‰) and trace element data obtained for pyrite, chalcopyrite, and pyrrhotite indicate that the two geochemically distinct Au–Co and Co ore types formed from fluids of different compositions and origins. A reduced, metamorphic fluid was responsible for deposition of the pyrrhotite-dominant, Co-rich ore, whereas a relatively oxidized fluid deposited the pyrite-dominant Au–Co ore. The main alteration and mineralization stages at Juomasuo are as follows: (1) widespread albitization that predates both types of mineralization; (2) stage 1, Co-rich mineralization associated with chlorite (± biotite ± amphibole) alteration; (3) stage 2, Au–Co mineralization related to sericitization. Crystal-chemical compositions for tourmaline suggest the involvement of evaporite-related fluids in formation of the deposit; boron isotope data also allow for this conclusion. Results of our research indicate that the metal association in the Juomasuo Au–Co deposit was formed by spatially coincident and multiple hydrothermal processes.

The Peninsular Ranges Batholith: an insight into the evolution of the Cordilleran batholiths of southwestern North America

1988 ◽  
Vol 79 (2-3) ◽  
pp. 105-121 ◽  
Author(s):  
L. T. Silver ◽  
B. W. Chappell
Keyword(s):  
Baja California ◽  
Volcanic Rocks ◽  
Oceanic Lithosphere ◽  
Radiometric Dating ◽  
Island Arcs ◽  
Magmatic Arc ◽  
Metasedimentary Rocks ◽  
Basaltic Composition ◽  
Peninsular Ranges ◽  
General Aspects

ABSTRACTThe Peninsular Ranges Batholith of southern and Baja California is the largest segment of a Cretaceous magmatic arc that was once continuous from northern California to southern Baja California. In this batholith, the emplacement of igneous rocks took place during a single sequence of magmatic activity, unlike many of the other components of the Cordilleran batholiths which formed during successive separate magmatic episodes. Detailed radiometric dating has shown that it is a composite of two batholiths. A western batholith, which was more heterogeneous in composition, formed as a static magmatic arc between 140 and 105 Ma and was intrusive in part into related volcanic rocks. The eastern batholith formed as a laterally transgressing arc which moved away from those older rocks between 105 and 80 Ma, intruding metasedimentary rocks. Rocks of the batholith range from undersaturated gabbros through to felsic granites, but tonalite is the most abundant rock throughout. Perhaps better than elsewhere in the Cordillera, the batholith shows beautifully developed asymmetries in chemical and isotopic properties. The main gradients in chemical composition from W to E are found among the trace elements, with Ba, Sr, Nb and the light rare earth elements increasing by more than a factor of two, and P, Rb, Pb, Th, Zn and Ga showing smaller increases. Mg and the transition metals decrease strongly towards the E, with Sc, V and Cu falling to less than half of their value in the most westerly rocks. Oxygen becomes very systematically more enriched in18O from W to E and the Sr, Nd and Pb isotopic systems change progressively from mantle values in the W to a more evolved character on the eastern side of the batholith. In detail the petrogenesis of the Peninsular Ranges Batholith is not completely understood, but many general aspects of the origin are clear. The exposed rocks, particularly in the western batholith, closely resemble those of present day island arcs, although the most typical and average tonalitic composition is distinctly more felsic than the mean quartz diorite or mafic andesite composition of arcs. Chemical and isotopic properties of the western part of the batholith indicate that it formed as the root of a primitive island arc on oceanic lithosphere at a convergent plate margin. Further E, the plutonic rocks appear to have been derived by partial melting from deeper sources of broadly basaltic composition at subcrustal levels. The compositional systematics of the batholith do not reflect a simple mixing of various end-members but are a reflection of the differing character of the source regions laterally and vertically away from the pre-Cretaceous continental margin.

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