Recently Discovered Thick Bentonite Bed Hosted by the Lithothamnium Limestones (Badenian) in the Polish Part of the Carpathian Foredeep: The Evidence for Volcanic Origin

In this paper, we discuss the hypothesis on the volcanic origin of the precursor sediments for a thick (0.6 m) clay bed, hosted by the sequence of lithothamnium limestones of the Pińczów Formation. Combined X-ray powder diffraction, imaging methods (optical and electron microscopy), and chemical analysis were used to document the volcanic markers, which were preserved in the rock studied. The results obtained show that the clay bed discussed is bentonite in origin. This bentonite, which can be called Drugnia Rządowa bentonite, is composed almost entirely of montmorillonite with little admixtures of quartz and biotite. A small amount of calcite is present, but only in the top of the bed. Despite that, the bentonite contains nothing but clay material—it is a model example of entirely altered pyroclastic rock, which retains texture originally developed in volcanic glass fragments and reveals the preserved original features of the precursor fallout pyroclastic deposits (rhyolitic in character). The thick bentonite beds, discovered for the first time within the Badenian lithothamnium limestones of the Pińczów Formation, can be considered as a record of a violent, explosive volcanic event related to the closure of the Outer Carpathian basin and the development of the Carpathian Foredeep.

Experimental Investigation on the Influence of Oven-Drying on the Geotechnical Properties of Volcanic Ash-Derived Residual Soils

For thousands of years, the volcanic activity present along the Andes Mountain range has generated a large amount of pyroclastic material. As a result, around 60 percent of the soils present in Chile have a volcanic origin, of which, we can find soils derived from volcanic ash. These correspond to soils whose origin is the weathering of volcanic ash, which generates minerals such as allophane, imogolite, and halloysite. The presence of these minerals gives these soils unique geotechnical properties, such as high plasticity, low dry unit weight, and a unique internal structure. Subjecting these soils to extreme temperatures like those needed to perform standard laboratory tests produces changes in their structures, and thus in their geotechnical behavior. These changes are important to be aware of with respect to slope stability problems, embankment conformation, surface foundations, etc. In the present study, a type of soil found in Chile originating from the weathering of volcanic ash and locally named Trumao was studied. Due to its age and formation processes, the main minerals found in the soil are allophane and imogolite, and hence it belongs to the allophanic soil type. The material was studied in its natural state (undisturbed) and, after being oven-dried using common geotechnical tests, the behaviors of both samples were compared. The study shows that some properties are affected significantly by the oven-drying process, and thus it is not recommended to expose the material to high temperatures during geotechnical laboratory testing to avoid misleading results.

Elemental composition, rare earths and minority elements in organic and conventional wines from volcanic areas: The Canary Islands (Spain)

The organic wine market is rapidly growing worldwide, both in terms of production and consumption. However, the scientific literature is not conclusive regarding differences in the elemental composition of wines according to their production method, including both major and trace elements. Minerals can be present in wine as a result of both anthropogenic and environmental factors. To date, this has not been evaluated in volcanic contexts, neither has the emergent issue of rare earths and other minority elements as potential sources of food contamination. This study using inductively coupled plasma mass spectrometry (ICP-MS) analyses organic and conventional wines produced in the Canary Islands (Spain), an archipelago of volcanic origin, to compare their content of 49 elements, including rare earths and minority elements. Our results showed that organic wines presented lower potential toxic element content on average than their conventional counterparts, but differences were not significant. Geographical origin of the wine samples (island) was the only significant variable differentiating wine samples by their composition profiles. By comparing our data with the literature, no agreement was found in terms of differences between organic and conventionally-produced wines. This confirms that other factors prevail over elemental composition when considering differences between wine production methods. Regarding the toxicological profile of the wines, five samples (three organic and two conventional) exceeded the maximum limits established by international legislation. This highlights the need for stricter analytical monitoring in the Canary Islands, with a particular focus on Cu and Ni concentration, and potentially in other volcanic areas.

Volcanic origin of the mercury anomalies at the Cretaceous-Paleogene transition of Bidart, France

The timing and mechanisms of the climatic and environmental perturbations induced by the emplacement of the Deccan Traps large igneous province (India) and their contribution to the Cretaceous-Paleogene (K-Pg) mass extinction are still debated. In many marine sediment archives, mercury (Hg) enrichments straddling the K-Pg boundary have been interpreted as the signature of Deccan Traps volcanism, but Hg may also have been derived from the Chicxulub (Mexico) impact. We investigated the Hg isotope composition, as well as the behavior of iridium (Ir) and other trace elements, in K-Pg sediments from the Bidart section in southwest France. Above the K-Pg boundary, Ir content gradually decreases to background values in the Danian carbonates, which is interpreted to indicate the erosion and redistribution of Ir-rich fallouts. No significant enrichment in Ir and W, or Zn and Cu, is observed just below the K-Pg boundary, excluding the hypothesis of downward remobilization of Hg from the boundary clay layer. Positive Δ199Hg and slightly negative values in the upper Maastrichtian and lower part of the early Danian are consistent with the signature of sediments supplied by atmospheric Hg2+ deposition and volcanic emissions. Up section, large shifts to strongly negative mass-dependent fractionation values (δ202Hg) result from the remobilization of Hg formerly sourced by the impactor or by a mixture of different sources including biomass burning, volcanic eruption, and asteroid impact, requiring further investigation. Our results provide additional support for the interpretation that the largest eruptions of the Deccan Traps began just before, and encompassed, the K-Pg boundary and therefore may have contributed to the K-Pg mass extinction.

Supplemental Material: Volcanic origin of the mercury anomalies at the Cretaceous-Paleogene transition of Bidart, France

Detailed analytical methods, Table S1 (Hg concentration, total organic carbon, and Ir concentration of the Bidart samples), Table S2 (Hg isotope composition of the Bidart samples), and methods.<br>

Supplemental Material: Volcanic origin of the mercury anomalies at the Cretaceous-Paleogene transition of Bidart, France

Detailed analytical methods, Table S1 (Hg concentration, total organic carbon, and Ir concentration of the Bidart samples), Table S2 (Hg isotope composition of the Bidart samples), and methods.<br>

Provenance controls on volcaniclastic beach sand: example from the Aeolian Archipelago, Mediterranean Sea

Sand and sandstone composition of volcanic origin may be clues to the provenance of the sediments and sedimentary rocks. Volcaniclastic provenance studies contribute significantly to unravel the sediment generation and provenance under investigation that in the Aeolian archipelago comprise preserved units of outcrops dominated by lava flows intercalated with air fall tephras as source rocks. The aim of this paper is the study of the petrographic composition and the textures of beach sands that may be used as a guide for the interpretation of provenance and origin of beach sand(stone)s rich in volcanic debris transported into deeper water. The composition of Aeolian beach deposits defines a single immature petrofacies with a high amount of unweathered glass and mafic minerals. Panarea island is dominated by dacites and new grain categories have been proposed to discriminate this provenance. Surface processes such as mechanical erosion (mass wasting and surface runoff) produce an overestimation of mafic components, with respect to the felsic ones in the beach sand fraction.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5608950

Internal Wave Dynamics Over Isolated Seamount and Its Influence on Coral Larvae Dispersion

The internal wave dynamics over Rosemary Bank Seamount (RBS), North Atlantic, were investigated using the Massachusetts Institute of Technology general circulation model. The model was forced by M2-tidal body force. The model results are validated against the in-situ data collected during the 136th cruise of the RRS “James Cook” in June 2016. The observations and the modeling experiments have shown two-wave processes developed independently in the subsurface and bottom layers. Being super-critical topography for the semi-diurnal internal tides, RBS does not reveal any evidence of tidal beams. It was found that below 800-m depth, the tidal flow generates bottom trapped sub-inertial internal waves propagated around RBS. The tidal flow interacting with a cluster of volcanic origin tall bottom cones generates short-scale internal waves located in 100 m thick seasonal pycnocline. A weakly stratified layer separates the internal waves generated in two waveguides. Parameters of short-scale sub-surface internal waves are sensitive to the season stratification. It is unlikely they can be observed in the winter season from November to March when seasonal pycnocline is not formed. The deep-water coral larvae dispersion is mainly controlled by bottom trapped tidally generated internal waves in the winter season. A Lagrangian-type passive particle tracking model is used to reproduce the transport of generic deep-sea water invertebrate species.

Distinguishing volcanic from impact glasses—The case of the Cali glass (Colombia)

Natural glass occurs on Earth in different geological contexts, mainly as volcanic glass, fulgurites, and impact glass. All these different types of glasses are predominantly composed of silica with variable amounts of impurities, especially the alkalis, and differ in their water content due to their mode of formation. Distinguishing between different types of glasses, on Earth and also on the Moon and on other planetary bodies, can be challenging. This is particularly true for glasses of impact and volcanic origin. Because glass is often used for the determination of the age of geological events, even if out of geological context, as well as to derive pressure and temperature constraints, or to evaluate the volatile contents of magmas and their source regions, we rely on methods that can unambiguously distinguish between the different types of glasses. We used the case of the Cali glass, found in an extended area close to the city of Cali in western Colombia, which was previously suggested to be of impact or volcanic origin, to show that, using a multimethod approach (i.e., combining macroscopic observations, chemical and isotopic data, and H2O content), it is possible to distinguish between different formation modes. A suite of Cali glass samples was analyzed using electron microprobe, instrumental neutron activation analysis, thermal ionization mass spectrometry, and Fourier-transform infrared spectroscopy, allowing us to definitively exclude an impact origin and instead classify these glasses as a rhyolitic volcanic glass (obsidian). Our results suggest that other “unusual glass occurrences” that are claimed, but not convincingly proven, to be of impact origin should be reexamined using the same methodology as that applied here.