scholarly journals Brief communication: Spatial and temporal variations in surface snow chemistry along a traverse from coastal East Antarctica to the ice sheet summit (Dome A)

2021 ◽  
Vol 15 (2) ◽  
pp. 1087-1095
Author(s):  
Guitao Shi ◽  
Hongmei Ma ◽  
Zhengyi Hu ◽  
Zhenlou Chen ◽  
Chunlei An ◽  
...  
Keyword(s):  
Sea Ice ◽  
Ice Sheet ◽  
Temporal Variations ◽  
Sea Salt ◽  
Biogenic Emissions ◽  
Dome A ◽  
Sea Salts ◽  
Snow Chemistry ◽  
Surface Snow ◽  
The Antarctic

Abstract. To better understand snow chemistry in different environments across the Antarctic ice sheet, we investigated snow ions on a traverse from the coast to Dome A. Results show that the non-sea-salt (nss) fractions of K+, Mg2+, and Ca2+ are mainly from terrestrial particle mass and nssCl− is associated with HCl. Spatially, the non-sea-salt fractions of ions to the totals are higher in the interior areas than on the coast, and seasonally, the proportions are higher in summer than in winter. Negative nssSO42- on the coast indicates sea salts from the sea ice, and marine biogenic emissions dominate snow SO42- in interior areas throughout the year.

scholarly journals Spatial and temporal variations in snow chemistry along a traverse from coastal East Antarctica to the ice sheet summit (Dome A)

2020 ◽  
Author(s):  
Guitao Shi ◽  
Hongmei Ma ◽  
Zhengyi Hu ◽  
Zhenlou Chen ◽  
Chunlei An ◽  
...  
Keyword(s):  
Ice Sheet ◽  
Temporal Variations ◽  
East Antarctica ◽  
Spatial And Temporal Variations ◽  
Biogenic Emissions ◽  
Dome A ◽  
Sea Salts ◽  
Snow Chemistry ◽  
Winter Snow ◽  
Surface Snow

Abstract. There is a large variability in environmental conditions across the Antarctic ice sheet, and it is of significance to investigate the snow chemistry at as many locations as possible and over time, given that the ice sheet itself, and precipitation and deposition patterns and trends are changing. The China inland Antarctic traverse from coastal Zhongshan Station to the ice sheet summit (Dome A) covers a variety of environments, allowing for a vast collection of snow chemistry conditions across East Antarctica. Surface snow and snow pit samples were collected on this traverse during five campaigns, to comprehensively investigate the spatial and temporal variations in chemical ions (Cl−, NO3−, SO42−, Na+, NH4+, K+, Mg2+, and Ca2+) and the related controlling factors. Results show that spatial patterns of ions in surface snow are consistent among the five campaigns, with Cl−, Na+, K+, and Mg2+ decreasing rapidly with distance from the coast and NO3− showing an opposite pattern. No clear spatial trends in SO42−, NH4+ and Ca2+ were found. In the interior areas, an enrichment of Cl− versus Na+ with respect to seawater composition is ubiquitous as a result of the deposition of HCl, which can account for up to ~40 % of the total Cl− budget, while enriched K+ and Mg2+ are associated with terrestrial particle mass. Ca2+ and SO42− in surface snow are significantly enriched relative to Na+, related to terrestrial dust inputs and marine biogenic emissions, respectively. Snow NH4+ is mainly associated with marine biological activities, with higher concentrations in summer than in winter. On the coast, parts of the winter snow are characterized with a depletion of SO42− versus Na+, and a significant negative correlation between nssSO42− and Na+ was found, suggesting that sea salts originated from the sea ice. In the interior areas, the negative nssSO42− signal in winter snow resulted from inputs of sea salts being completely swamped by the contribution of marine biogenic emissions. Ternary plots of Cl−, Na+, and SO42− suggest that sea salt modification is generally negligible on the coast, while the degree of modification processes to sea salts is high in the interior areas, especially during the summertime. Ion flux assessment suggests an efficient transport of nssSO42− to at least as far inland as the ~2800 m contour line. The interannual variations in ion concentrations in surface snow on the traverse are likely linked to the changes in the Southern Indian Ocean low (SIOL) from year to year, and the deepening of the SIOL in summer tends to promote the transport of marine aerosols to Princess Elizabeth Land.

scholarly journals The Weddell Sea region: an important precipitation channel to the interior of the Antarctic ice sheet as revealed by glaciochemical investigation of surface snow along the longest trans-Antarctic route

1999 ◽  
Vol 29 ◽  
pp. 55-60 ◽  
Author(s):  
Qin Dahe ◽  
Paul A. Mayewski ◽  
Ren Jiawen ◽  
Xiao Cunde ◽  
Sun Junying
Keyword(s):  
Ice Sheet ◽  
Weddell Sea ◽  
Sea Salt ◽  
East Antarctica ◽  
Antarctic Ice Sheet ◽  
Air Masses ◽  
Antarctic Plateau ◽  
Salt Ions ◽  
Surface Snow ◽  
The Antarctic

AbstractGlaciochemical analysis of surface snow samples, collected along a profile crossing the Antarctic ice sheet from the Larsen Ice Shelf, Antarctic Peninsula, via the Antarctic Plateau through South Pole, Vostok and Komsomolskaya to Mirny station (at the east margin of East Antarctica), shows that the Weddell Sea region is an important channel for air masses to the high plateau of the Antarctic ice sheet (>2000 m a.s.l.). This opinion is supported by the following. (1) The fluxes of sea-salt ions such as Na+, Mg2 + and CF display a decreasing trend from the west to the east of interior Antarctica. In |eneral, as sea-salt aerosols are injected into the atmosphere over the Antarctic ice sheet from the Weddell Sea, large aerosols tend to decrease. For the inland plateau, few large particles of sea-salt aerosol reach the area, and the sea-salt concentration levels are low (2) The high altitude of the East Antarctic plateau, as well as the polar cold high-pressure system, obstruct the intrusive air masses mainly from the South Indian Ocean sector. (3) For the coastal regions of the East Antarctic ice sheet, the elevation rises to 2000 m over a distance from several to several tens of km. High concentrations of sea salt exist in snow in East Antarctica but are limited to a narrow coastal zone. (4) Fluxes of calcium and non-sea-salt sulfate in snow from the interior plateau do not display an eastward-decreasing trend. Since calcium is mainly derived from crustal sources, and nssSO42- is a secondary aerosol, this again confirms that the eastward-declining tendency of sea-salt ions indicates the transfer direction of precipitation vapor.

scholarly journals Spatial and Temporal Variations of Snow Chemistry in Terre Adélie (East Antarctica)

1985 ◽  
Vol 7 ◽  
pp. 20-25 ◽  
Author(s):  
Michel Legrand ◽  
Robert J. Delmas
Keyword(s):  
Ion Chromatography ◽  
Temporal Variations ◽  
Sea Salt ◽  
East Antarctica ◽  
Snow Chemistry ◽  
Antarctic Plateau ◽  
Time Period ◽  
Terre Adélie ◽  
The Mean ◽  
The Antarctic

The chemistry of recently deposited snow sampled in 1982–83 along a 430 km coast-interior traverse in Terre Adelie, East Antarctica, is reported. In addition, three firn samples, covering the same time period (1959 to 1969) and collected on the traverse at D 55, D 80 and Dome C stations, respectively at 200, 430 and 1070 km from the sea, are also studied. Concentrations of major soluble impurities (H+, , Na+, K+, Cl−, and ) were determined by ion chromatography (except H+ which was titrated) on more than 200 samples. Conditions of sampling and analysis were carefully controlled in order to avoid contamination problems. A balanced ionic budget was generally obtained for each of the samples. For stations occupying an intermediary position between the coastal areas and the central Antarctic plateau, our results demonstrate that the two major impurities are H2SO4 and HNO3. HCl is also present, but at a lower level of concentration; the sea-salt contribution is dominant only at the most coastal sites (within 40 km) of the sea. The degree of neutralization of the snow acidity by NH3 is always very low as indicated by the values of content. The mean concentrations of H2SO4 along the traverse are relatively constant whereas an increase of the HNO3 concentrations is observed when going inland. It decreases, however, in most central areas. These results are discussed in relation to the glaciochemical data published for other locations on the Antarctic plateau, in particular the sulphate concentrations which depend strongly on explosive volcanic activity.

scholarly journals Spatial and Temporal Variations of Snow Chemistry in Terre Adélie (East Antarctica)

1985 ◽  
Vol 7 ◽  
pp. 20-25 ◽  
Author(s):  
Michel Legrand ◽  
Robert J. Delmas
Keyword(s):  
Ion Chromatography ◽  
Temporal Variations ◽  
Sea Salt ◽  
East Antarctica ◽  
Snow Chemistry ◽  
Antarctic Plateau ◽  
Time Period ◽  
Terre Adélie ◽  
The Mean ◽  
The Antarctic

The chemistry of recently deposited snow sampled in 1982–83 along a 430 km coast-interior traverse in Terre Adelie, East Antarctica, is reported. In addition, three firn samples, covering the same time period (1959 to 1969) and collected on the traverse at D 55, D 80 and Dome C stations, respectively at 200, 430 and 1070 km from the sea, are also studied. Concentrations of major soluble impurities (H+, , Na+, K+, Cl−, and ) were determined by ion chromatography (except H+ which was titrated) on more than 200 samples. Conditions of sampling and analysis were carefully controlled in order to avoid contamination problems. A balanced ionic budget was generally obtained for each of the samples. For stations occupying an intermediary position between the coastal areas and the central Antarctic plateau, our results demonstrate that the two major impurities are H2SO4 and HNO3. HCl is also present, but at a lower level of concentration; the sea-salt contribution is dominant only at the most coastal sites (within 40 km) of the sea. The degree of neutralization of the snow acidity by NH3 is always very low as indicated by the values of content. The mean concentrations of H2SO4 along the traverse are relatively constant whereas an increase of the HNO3 concentrations is observed when going inland. It decreases, however, in most central areas. These results are discussed in relation to the glaciochemical data published for other locations on the Antarctic plateau, in particular the sulphate concentrations which depend strongly on explosive volcanic activity.

scholarly journals Recent changes in pan-Antarctic surface snowmelt detected by AMSR-E and AMSR2

2019 ◽  
Author(s):  
Lei Zheng ◽  
Chunxia Zhou ◽  
Tingjun Zhang ◽  
Qi Liang ◽  
Kang Wang
Keyword(s):  
Sea Ice ◽  
Ice Sheet ◽  
Remote Sensing Data ◽  
Microwave Remote Sensing ◽  
Southern Annular Mode ◽  
Temporal Variations ◽  
Acquisition Time ◽  
Polar Regions ◽  
Antarctic Sea Ice ◽  
The Antarctic

Abstract. Surface snowmelt in the pan-Antarctic, including the Antarctic sea ice and ice sheet, is crucial to the mass and energy balance in polar regions and can serve as an indicator of climate change. We investigated the spatial and temporal variations of the surface snowmelt over the entire pan-Antarctic as a whole from 2002 to 2017 by using the passive microwave remote sensing data. The stable orbit and appropriate acquisition time of the Advanced Microwave Scanning Radiometer for the Earth Observing System (AMSR-E) and the Advanced Microwave Scanning Radiometer 2 (AMSR2) enable us to take full advantage of the daily brightness temperature (Tb) variations to detect the surface snowmelt events. In this study, diurnal amplitude variations of AMSR-E/2 vertically polarized 36.5 GHz Tb (DAV36V) were utilized to map the pan-Antarctic snowmelt because it is unaffected by the snow metamorphism. We validated the DAV36V method against the ground-based measurements and further improved the method over the marginal sea ice zone by excluding the effect of open water. Snowmelt detected by AMSR-E/2 data agreed well with that derived by ERA-Interim reanalysis, and much more extensive than that detected by the Special Sensor Microwave/Imager (SSM/I) data. On average, pan-Antarctic snowmelt began on 19 September, and experienced 32 melt events. Annual mean melt extent on the Antarctic ice sheet (AIS) was only 9 % of that on the Antarctic sea ice. Overall, the pan-Antarctic surface snowmelt showed a trend (at 95 % confidence level) toward later melt onset (0.70 days yr−1) during the 2002–2017 period. Surface snowmelt was well correlated with atmospheric indices in some regions. Notably, the decreasing surface snowmelt on the AIS was very likely linked with the enhancing summer Southern Annular Mode.

scholarly journals Snow surface height variations on the Antarctic ice sheet in Princess Elizabeth Land, Antarctica: 1 year of data from an automatic weather station

2004 ◽  
Vol 39 ◽  
pp. 181-187 ◽  
Author(s):  
Qin Dahe ◽  
Xiao Cunde ◽  
Ian Allison ◽  
Bian Lingen ◽  
Rod Stephenson ◽  
...  
Keyword(s):  
Ice Sheet ◽  
Cloud Amount ◽  
Snow Accumulation ◽  
Strong Wind ◽  
Weather Station ◽  
Automatic Weather Station ◽  
Antarctic Ice Sheet ◽  
Total Cloud Amount ◽  
Surface Snow ◽  
The Antarctic

AbstractThe net surface snow accumulation on the Antarctic ice sheet is determined by a combination of precipitation, sublimation and wind redistribution. We present a 1 year record of hourly snow-height measurements that shows its seasonal variability. The measurements were made with an ultrasonic sensor mounted on an automatic weather station (AWS) installed at LGB69, Princess Elizabeth Land, Antarctica (70.835˚S, 77.075˚E; 1850 ma.s.l.). The average accumulation at this site is approximately 0.70 m snow a–1. Throughout the winter, between April and September, there was little change in surface snow height. The strongest accumulation occurred during the period October–March, with four episodic increases occurring during 2002. These episodic events coincided with obvious humidity ‘pulses’ and decreases of incoming solar radiation as recorded by the AWS. Observations of the total cloud amount at Davis station, 160 km north-northeast of LGB69, showed good correlation with major accumulation events recorded at LGB69. There was an obvious anticorrelation between the lowest cloud height at Davis and the daily accumulation rate at LGB69. Although there was no correlation over the total year between wind speed and accumulation at LGB69, large individual accumulation events are associated with episodes of strong wind. Strong accumulation events at LGB69 are associated with major storms in the region and inland transport of moist air masses from the coast.

scholarly journals The origin of sea salt in snow on Arctic sea ice and in coastal regions

2004 ◽  
Vol 4 (9/10) ◽  
pp. 2259-2271 ◽  
Author(s):  
F. Domine ◽  
R. Sparapani ◽  
A. Ianniello ◽  
H. J. Beine
Keyword(s):  
Time Series ◽  
Sea Ice ◽  
Ozone Depletion ◽  
Sea Salt ◽  
Sea Spray ◽  
Snow Surface ◽  
Coastal Regions ◽  
Upward Migration ◽  
Surface Snow ◽  
Frost Flowers

Abstract. Snow, through its trace constituents, can have a major impact on lower tropospheric chemistry, as evidenced by ozone depletion events (ODEs) in oceanic polar areas. These ODEs are caused by the chemistry of bromine compounds that originate from sea salt bromide. Bromide may be supplied to the snow surface by upward migration from sea ice, by frost flowers being wind-blown to the snow surface, or by wind-transported aerosol generated by sea spray. We investigate here the relative importance of these processes by analyzing ions in snow near Alert and Ny-Ålesund (Canadian and European high Arctic) in winter and spring. Vertical ionic profiles in the snowpack on sea ice are measured to test upward migration of sea salt ions and to seek evidence for ion fractionation processes. Time series of the ionic composition of surface snow layers are investigated to quantify wind-transported ions. Upward migration of unfractionated sea salt to heights of at least 17cm was observed in winter snow, leading to Cl- concentration of several hundred µM. Upward migration thus has the potential to supply ions to surface snow layers. Time series show that wind can deposit aerosols to the top few cm of the snow, leading also to Cl- concentrations of several hundred µM, so that both diffusion from sea ice and wind transport can significantly contribute ions to snow. At Ny-Ålesund, sea salt transported by wind was unfractionated, implying that it comes from sea spray rather than frost flowers. Estimations based on our results suggest that the marine snowpack contains about 10 times more Na+ than the frost flowers, so that both the marine snowpack and frost flowers need to be considered as sea salt sources. Our data suggest that ozone depletion chemistry can significantly enhance the Br- content of snow. We speculate that this can also take place in coastal regions and contribute to propagate ODEs inland. Finally, we stress the need to measure snow physical parameters such as permeability and specific surface area to understand quantitatively changes in snow chemistry.

scholarly journals Nitrate deposition and preservation in the snowpack along a traverse from coast to the ice sheet summit (Dome A) in East Antarctica

2018 ◽  
Vol 12 (4) ◽  
pp. 1177-1194 ◽  
Author(s):  
Guitao Shi ◽  
Meredith G. Hastings ◽  
Jinhai Yu ◽  
Tianming Ma ◽  
Zhengyi Hu ◽  
...  
Keyword(s):  
Dry Deposition ◽  
Aerosol Particles ◽  
Ice Sheet ◽  
Snow Accumulation ◽  
East Antarctica ◽  
Dome A ◽  
Surface Snow ◽  
The Relationship ◽  
Coexisting Ions ◽  
Snow Samples

Abstract. Antarctic ice core nitrate (NO3-) can provide a unique record of the atmospheric reactive nitrogen cycle. However, the factors influencing the deposition and preservation of NO3- at the ice sheet surface must first be understood. Therefore, an intensive program of snow and atmospheric sampling was made on a traverse from the coast to the ice sheet summit, Dome A, East Antarctica. Snow samples in this observation include 120 surface snow samples (top ∼ 3 cm), 20 snow pits with depths of 150 to 300 cm, and 6 crystal ice samples (the topmost needle-like layer on Dome A plateau). The main purpose of this investigation is to characterize the distribution pattern and preservation of NO3- concentrations in the snow in different environments. Results show that an increasing trend of NO3- concentrations with distance inland is present in surface snow, and NO3- is extremely enriched in the topmost crystal ice (with a maximum of 16.1 µeq L−1). NO3- concentration profiles for snow pits vary between coastal and inland sites. On the coast, the deposited NO3- was largely preserved, and the archived NO3- fluxes are dominated by snow accumulation. The relationship between the archived NO3- and snow accumulation rate can be depicted well by a linear model, suggesting a homogeneity of atmospheric NO3- levels. It is estimated that dry deposition contributes 27–44 % of the archived NO3- fluxes, and the dry deposition velocity and scavenging ratio for NO3- were relatively constant near the coast. Compared to the coast, the inland snow shows a relatively weak correlation between archived NO3- and snow accumulation, and the archived NO3- fluxes were more dependent on concentration. The relationship between NO3- and coexisting ions (nssSO42-, Na+ and Cl−) was also investigated, and the results show a correlation between nssSO42- (fine aerosol particles) and NO3- in surface snow, while the correlation between NO3- and Na+ (mainly associated with coarse aerosol particles) is not significant. In inland snow, there were no significant relationships found between NO3- and the coexisting ions, suggesting a dominant role of NO3- recycling in determining the concentrations.

scholarly journals Using the temporal variability of satellite radar altimetric observations to map surface properties of the Antarctic ice sheet

1998 ◽  
Vol 44 (147) ◽  
pp. 197-206 ◽  
Author(s):  
Benoît Legrésy ◽  
Frédérique Rémy
Keyword(s):  
Ice Sheet ◽  
Temporal Variations ◽  
Radar Altimeter ◽  
Height Measurement ◽  
Radar Echoes ◽  
Measuring Surface ◽  
Antarctic Continent ◽  
Ice Sheet Mass Balance ◽  
Satellite Radar ◽  
The Antarctic

AbstractThe problem of measuring surface height and snowpack characteristics from satellite radar altimeter echoes is investigated. In this paper, we perform an analysis of the ERS1 altimeter dataset acquired during a 3 day repeat orbit. The analysis reveals that there are temporal variations in shapes of the radar altimeter echo and that these variations are linked to meteorological phenomena. The time- and space-scales over which these variations apply are a few to tens of days and a few hundred kilometres, respectively. This phenomenon, if not accounted for, can create error in the height measurement. A numerical echo model is used to recover snowpack characteristics by taking advantage of the temporal variations of the radar echoes. A map of penetration depth of the radar waves in the Ku band over the Antarctic continent is obtained and suggests that grain-size produces the dominant effect on radar extinction in the snowpack at this frequency. Finally, a procedure is proposed to correct the height measurement within the context of ice-sheet mass-balance survey.

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