scholarly journals Supplementary material to "Mercury in arctic tundra snowpack: temporal and spatial concentration patterns and trace–gas exchanges"

Author(s):  
Yannick Agnan ◽  
Thomas A. Douglas ◽  
Detlev Helmig ◽  
Jacques Hueber ◽  
Daniel Obrist
2017 ◽  
Author(s):  
Yannick Agnan ◽  
Thomas A. Douglas ◽  
Detlev Helmig ◽  
Jacques Hueber ◽  
Daniel Obrist

Abstract. In the Arctic, the snowpack forms the major interface between atmospheric and terrestrial mercury (Hg) cycling, a global pollutant. In this study, we investigated Hg dynamics in an interior arctic tundra snowpack in northern Alaska during two snow seasons. Using a snow tower system and soil wells to monitor trace gas exchange of Hg, we observed consistent concentration declines of gaseous elemental Hg (Hg0gas), the volatile form of Hg, from the atmosphere to the snowpack to soils. This indicates a sink of Hg0gas in tundra soils. There was no evidence of photochemical reduction of HgII to Hg0gas in the tundra snowpack, unlike in temperate snowpacks, with the exception of short periods during late winter. We consistently measured low concentrations of both total (Hgtot) and dissolved (Hgdiss) Hg in the tundra snowpack throughout two years (generally


2014 ◽  
pp. 1001-1004
Author(s):  
Jürgen Kreuzwieser ◽  
Heinz Rennenberg
Keyword(s):  

2005 ◽  
Vol 5 (2) ◽  
pp. 1647-1678 ◽  
Author(s):  
P. Peylin ◽  
P. J. Rayner ◽  
P. Bousquet ◽  
C. Carouge ◽  
F. Hourdin ◽  
...  

Abstract. This paper presents a method for inferring trace gas fluxes at high temporal and spatial resolution from atmospheric concentration measurements. The method is designed for regional applications and for use in intensive campaigns. We apply the method to a one month inversion 5 of fluxes over Europe. We show that the information added by the measurements depends critically on the smoothness constraint assumed among the source components. We show that the initial condition affects the inversion for 20 days, provided one has enough observing sites to constrain regional fluxes. We show that the impact of the far-field fluxes grows throughout the inversion and hence a 10 reasonable global flux field is a prerequisite for a regional inversion.


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